定容高压气体的压缩因子

１前言压缩因子是比较实际气体与理想气体之差异的重要物理量，从某状态的压缩因子Ｚ可求出该状态下实际气体的Ｐ或Ｖ来。现在高压气体的Ｚ大多是在高压ＰＶＴ实验台上用定容测试方法（绝对法）测试出来。但测试过程耗时费资，在新型气态工质不断涌现的今天，一些特殊高压高温条件很难在实验中满足；而工程上则多从对比态原理出发，从两参量或三参量的普遍化压缩因子图中近似求出，显然，其系统误差一般较大，一般说来，高压气体的Ｚ是系统温度Ｔ，压力Ｐ和偏心因子。的函数Ｚ＝Ｚ（Ｔ，Ｐ），其解析形式一直是热物性工作者努力探求的目标，…     

基于LabVIEW 8.0的pH电位滴定虚拟仪器

运用离子选择性电极、调理电路、DAQ卡和计算机,构建了基于LabVIEW 8.0的电位滴定虚拟仪器,实现了电位滴定实验数据的自动记录和自动处理.将该虚拟仪器应用到乙酸等的电位滴定实验表明,实验结果相对标准偏差小于0.65%,提高了实验结果的重现性和准确性;且虚拟仪器界面友好、操作简便、实时绘出滴定曲线,自动处理数据及即时得到结果.     

A Schr(o)idinger formulation research for light beam propagation

The wave equation of light beam propagation was written in the form of an axial-coordinate-dependent Schrdinger equation, and the expectation value of a dynamical variable, the trial function of variational approach and the ABCD law were discussed by use of quantum mechanics approach. In view of the evolution equations of expectation values of dynamical variables in the framework of quantum mechanics, the definition of a potential function representing the beam propagation stability and its universal formula with the quality factor, the universal formula of beam width and curvature radius for a paraxial beam and cylindrically symmetric non-paraxial beam, the general formula of second derivative of beam width with respect to the axial coordinate of beam for a paraxial beam, and the general criteria of the conservation of beam quality factor and the existence of a potential well of a potential function for a paraxial beam, were given or derived, respectively. Starting with the same trial function, the comparative research of our formulation with variational approach was done, which gave some further insight into the physical nature of a beam propagation parameters. The ABCD law of non-paraxial beam was discussed in terms of the definition of the non-paraxial expectation value of a dynamical variable for the first time. The applications to the media of constant second derivative of beam width with respect to the axial coordinate of a beam, square law media and the media of constant refractive index in the momentum representation were discussed, respectively.     

Spectroscopic analysis of asymmetric top free radicals——Application to pure rotational spectra of NO_2 in the ground vibronic state

Several key problems involved in the analyses of spectra of asymmetric top molecules, i.e., the effective Hamiltonian, the representation and basis vector, identification of energy levels, the selection rules, the relative intensity, and Zeeman tuning rate, were elucidated systematically. Introducing the high-order centrifugal distortion terms into the effective Hamiltonian, the precision for calculation has been improved substantially, which allows us to analyze the high-lying rotational transitions. A global analysis of all available spectra of 14N16O2 in the ground vibronic state has been made to obtain a set of molecular constants of 14N16O2 in the ground vibronic state which is the most precise and extensive so far. Using the improved parameters, some FIR LMR lines left unassigned hitherto have been identified successfully.     

Novel soluble fluorinated poly(ether imide)s with different pendant groups: Synthesis,thermal, dielectric,and optical properties

Three types of new bis(ether dianhydride) monomers, [4,4′‐(2‐(3′‐methylphenyl)‐1,4‐phenylenedioxy)‐diphthalic anhydride (4a)], [4,4′‐(2‐(3′‐trifluoromethylphenyl)‐1,4‐phenylenedioxy)‐diphthalic anhydride (4b)], and [4,4′‐(2‐(3′,5′‐ditrifluoromethylphenyl)‐1,4‐phenylenedioxy)‐diphthalic anhydride (4c)] were prepared via a multistep reaction sequence. Three series of soluble poly(ether imide)s (PEIs) were prepared from the obtained dianhydrides by a two‐step chemical imidization method. Experimental results indicated that all the PEIs had glass transition temperature in the range of 200–230 °C and the temperature of 5% weight loss in the range of 520–590 °C under nitrogen. The PEIs showed excellent solubility in a variety of organic solvents due to introduction of the bulky pendant groups and were capable of forming tough films. The casting films of PEIs (80–91 μm in thickness) had tensile strengths in the range from 88 to 117 MPa, tensile modulus from 2.14 to 2.47 GPa, and elongation at break from 15 to 27%. The casting films showed UV‐Vis absorption edges at 357–377 nm, low dielectric constants of 2.73–2.82, and water uptakes lower than 0.66 wt %. The spin‐coated films of PEIs presented a minimum birefringence value as low as 0.0122 at 650 nm and low optical absorption at the optical communication wavelengths of 1310 and 1550 nm. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3281–3289, 2010     

粉末衍射峰形拟合程序包CPOWDER

开发了一个Ｘ射线和中子粉末衍射峰形拟合程序包ＣＰＯＷＤＥＲ，它是由多个最小二乘峰形拟合程序与蒙特卡罗分峰程序组成的。最小二乘峰形拟合程序可用于约束条件下的峰形拟合分析，蒙特卡罗分峰程序可用于寻找全局最优解，为最小二乘拟合程序提供优质的峰形参数初始值，两者结合使用特别适合于多个严重重叠峰的分离。     

单重态H_2N=B:→HNBH重排反应的理论研究

用量子化学中的从头算方法, 在MP2/6-311++G(d,p)水平上研究了单重态H_2N=B→HNBH重排反应的机理。结果表明, 该重排反应经过一个三元环过渡态。根据计算结果，初步讨论了该反应的热力学及动力学函数。     

离子色谱法测定混凝土外加剂中硫酸钠含量

建立了一种离子色谱法测定混凝土外加剂中硫酸钠含量的方法,外加剂试样溶于水中,采用反相柱去除溶液中有机物,进样量25μL。经Dionex IonPac AS18色谱柱分离,用30 mmol·L~(-1)氢氧化钾溶液作流动相,以1.0 mL·min~(-1)流量进行洗脱,按峰面积定量。方法的检出限(3S/N)为3μg·L~(-1)。该方法可实现硫酸钠与氯离子同时测定的优点。在3个浓度水平上对方法的精密度作了考核,测得其相对标准偏差(n=6)均小于1%。用标准加入法,以实样为基体作回收试验,测得回收率在98.7%～100.5%之间。     

A pairing theorem between multi-parameter bialgebra and its dual bialgebra

This paper constructs a dual bialgebra for a multi-parameter FRT-bialgebra related to a Hayashi’sR-matrix by using the skew-derivation method and proves that the pairing between them is non-degenerate.