New isomers and states of (πg 9/2 ⊗vg 9/2) parentage in84Rb

Excited states in the doubly-odd nucleus⁸⁴Rb have mainly been studied via the (α,n) reaction by means of in- beam γ-ray spectroscopy. Two new isomers have been found, a 5^? level at 467.1 keV and a 5⁽⁺⁾ level at 544.2 keV with half-lives of 9(2) ns. and 11(1) ns, respectively. On top of the 5⁽⁺⁾ isomer a level sequence with increasing spins up to 10 ? and probably positive parity has been identified. These states are ascribed to the configuration (πg_9/2?vg_9/2).     

On the microwave conductivity of α-AgI. part II: Complex conductivity by measurement of the complex transmission factor

The electrical conductivity and the dielectric constant of α-AgI are computed in the frequency region from 8.2 to 40 GHz from the complex transmission factor of polycrystalline samples, which totally fill the crossection of a rectangular waveguide. No frequency dependence of both the conductivity and the permittivity is found in the entire temperature range studied (400 K to 720 K). The high frequency values coincide with the static ones.     

Quasielastic and inelastic scattering of cold neutrons from silver iodide

New information about the movement of the ions in AgI has been obtained from cold-neutron time-of-flight measurements performed at the Institut Laue-Langevin at Grenoble. Whereas the ordered β-phase shows very pronounced low energy lattice excitations, no well-defined phonon groups are observed in the structurally disordered α-phase. Instead we find enhanced very low energy transfer scattering due to the self-diffusion of the silver ions.     

Zur Korrelationsfunktionn-ter Ordnung für die Überlagerung von Thermischem und Kohärentem Licht

Then-th order correlation function for superimposed coherent and chaotic light is calculated in coherent state formalism. This function reduces to products and sums of the first-order correlations of coherent and chaotic fields alonge. It is demonstrated that superimposed fields cannot have full coherence farther then to the first order.     

Rotation alignment in 190Pt and 192Pt

Levels with spins up to 18 (20) in the ground-state bands of ¹⁹⁰Pt and ¹⁹²Pt have been observed. The very small energy spacing between the 12⁺ and 10⁺ levels in both nuclides is interpreted as a sudden decoupling of two i_{$\text{13}\text{2}$} neutrons from the collective core.     

Heegner Divisors and Nonholomorphic Modular Forms

We consider an embedded modular curve in a locally symmetric space M attached to an orthogonal group of signature (p, 2) and associate to it a nonholomorphic elliptic modular form by integrating a certain theta function over the modular curve. We compute the Fourier expansion and identify the generating series of the (suitably defined) intersection numbers of the Heegner divisors in M with the modular curve as the holomorphic part of the modular form. This recovers and generalizes parts of work of Hirzebruch and Zagier.     

Retroviral display and high throughput screening

Retroviruses distinguish themselves from all other mammalian viruses by their abilities to infect and propagate in mammalian cells without causing a cytopathic effect and to stably integrate their genetic information into the genome of the host cell. These unique properties make them an ideal platform for the display and directed evolution of proteins in a mammalian cell environment. This review will describe the essentials about retrovirus biology and then discuss in detail display and screening strategies that have been developed during the past 15 years of retroviral display technology.     

Electrochemical and complexation behavior of neptunium in aqueous perchlorate and nitrate solutions

Electrochemical and complexation properties of neptunium (Np) are investigated in aqueous perchlorate and nitrate solutions by means of cyclic voltammetry, bulk electrolysis, UV-visible absorption, and Np L(III)-edge X-ray absorption spectroscopies. The redox reactions of Np(III)/Np(IV) and Np(V)/Np(VI) couples are reversible or quasi-reversible, while the electrochemical reaction between Np(III/IV) and Np(V/VI) is irreversible because they undergo structural rearrangement from spherical coordinating ions (Np(3+) and Np(4+)) to transdioxoneptunyl ions (NpO2(n+), n = 1 for Np(V) and 2 for Np(VI)). The redox reaction of the Np(V)/Np(VI) couple involves no structural rearrangement on their equatorial planes in acidic perchlorate and nitrate solutions. A detailed analysis on extended X-ray absorption fine structure (EXAFS) spectra suggests that Np(IV) forms a decaaquo complex of [Np(H2O)10](4+) in 1.0 M HClO4, while Np(V) and Np(VI) exist dominantly as pentaaquoneptunyl complexes, [NpO2(H2O)5](n+) (n = 1 for Np(V) and 2 for Np(VI)). A systematic change is observed on the Fourier transforms of the EXAFS spectra for all of the Np oxidation states as the nitrate concentration is increased in the sample, revealing that the hydrate water molecules are replaced by bidentate-coordinating nitrate ions on the primary coordination sphere of Np.     

Pressure-dependent diffusion coefficients and haven ratios in cation-conducting glasses

The influence of hydrostatic pressure on diffusion and ionic conduction is providing deeper insights into the atomistic mechanisms of ionic motion in glasses. We have studied the tracer diffusion of 22Na in a sodium borate glass and of 86Rb in a rubidium borate glass as functions of hydrostatic pressures. The activation volumes of tracer diffusion are DeltaVD(Rb) = 33.5 cm3 mol-1 and DeltaVD(Na) = 6.1 cm3 mol-1. In comparison, the activation volumes of charge diffusion obtained recently from the pressure dependence of conductivity are smaller: DeltaVsigma(Rb) = 7.2 cm3 mol(-1) and DeltaVsigma(Na) = 2.8 cm3 mol(-1). These differences, where (DeltaVD - DeltaVsigma) > 0, imply that the Haven ratios decrease with pressure. This effect is particularly significant for the rubidium borate glass. Starting from basic equations of linear response theory for mass and charge transport, we develop a model that accounts for these experimental findings. The difference between the activation volumes, DeltaVD and DeltaVsigma, and the pressure-dependent Haven ratios are consequences of collective movements of ions in glass, implying a concerted motion of ions in a chain- or caterpillar-like fashion. In our treatment, it is a vacant site (with ions jumping into it successively) that moves along an extended pathway. Hence, we regard vacant sites as the carriers of charge and ions as the carriers of diffusing matter. The decrease of the Haven ratio with pressure is attributed to the influence of pressure on the topology of the conduction pathways, which are progressively straightened out with increasing pressure.     

Conductivity dispersion in supercooled calcium potassium nitrate: caged ionic motion viewed as part of standard behaviour

Conductivity spectra of ionic materials with disordered structures are usually thought to consist of several parts, i.e., the DC conductivity, a power-law component, a nearly-constant-loss feature (if identified) and the (far-)infrared conductivity caused by vibrational motion. Such a decomposition may, however, easily lead to a misinterpretation of the underlying dynamics. Here, we discuss broad-band conductivity data of the supercooled glass-forming melt calcium potassium nitrate, of composition 0.4 Ca(NO(3))(2).0.6 KNO(3), often abbreviated as CKN. Data have been taken at frequencies up to the far infrared. We show that the frequency-dependent conductivity is very well reproduced by a superposition of only two components. One of them is due to vibrations, the other is caused by displacements of the mobile ions. The latter component, which does not follow a power law, is described in terms of a physical model called the MIGRATION concept. This model treatment has been found to apply in many solid electrolytes as well and is, therefore, considered to provide a "standard" formulation of the ion dynamics. The gradual transition from a correlated forward-backward ("caged") ionic motion to a stepwise translational motion may be regarded as the main feature of the MIGRATION concept.