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81.
Susan A. Bourne Katherine L Gifford Nash Fumio Toda 《Journal of inclusion phenomena and macrocyclic chemistry》1999,34(2):169-187
The 2-hexanone inclusion compounds of hexakis(3-hydroxy-3,3-diphenyl-2-propynyl)benzene and 1,2,3,5,6,7-hexakis(3-hydroxy-3,3-diphenyl-2-propynyl)naphthalene have been prepared and characterised by single crystal X-ray diffraction and thermal analysis. The kinetic parameters and mechanisms for the desolvation reaction have also been determined for both compounds. 相似文献
82.
Masashi Shiotsuki Atsushi Nakagawa Jesus Rodriguez Castañon Naoya Onishi Tatsurou Kobayashi Fumio Sanda Toshio Masuda 《Journal of polymer science. Part A, Polymer chemistry》2010,48(23):5549-5556
End‐functionalized poly(phenylacetylene)s were synthesized by the polymerization of phenylacetylene (PA) using the well‐defined palladium catalysts represented as [(dppf)PdBr(R)] {dppf = 1,1′‐bis(diphenylphosphino)ferrocene}. The Pd catalysts having a series of R groups such as o‐tolyl, mesityl, C(Ph)?CPh2, C6H4‐o‐CH2OH, C6H4‐p‐CN, and C6H4‐p‐NO2 in conjunction with silver triflate polymerized PA to give end‐functionalized poly(PA)s bearing the corresponding R groups in high yields. The results of IR and NMR spectroscopies and MALDI‐TOF mass analyses proved the introduction of these R groups at one end of each polymer chain. The poly(PA) bearing a hydroxy end group was applied as a macroinitiator to the synthesis of a block copolymer composed of poly(PA) and poly(β‐propiolactone) moieties. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
83.
We consider a massless scalar Bose field interacting with two particles, one of them infinitely heavy. Neither an infrared nor an ultraviolet cutoff is imposed. In case the charge of the particles is of the same sign and sufficiently small, we prove the existence of a ground state. 相似文献
84.
Takeshi Endo Yuji Shibasaki Fumio Sanda 《Journal of polymer science. Part A, Polymer chemistry》2002,40(13):2190-2198
This article reviews recent topics in the controlled synthesis of polycarbonates and polylactones with small polydispersity indices by activated monomer cationic ring-opening polymerizations, especially with new initiator systems, such as alcohol/protonic acid and boron alkoxide/protonic acid. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 2190–2198, 2002 相似文献
85.
Fumio Morito 《Surface and interface analysis : SIA》1990,15(7):427-432
Bend properties of plasma beam and/or electron beam melted molybdenum and several dilute alloys containing C, B, T, V and Re were investigated. Fracture surfaces and microstructure were examined in detail by SEM and AES. Considerable intergranular fracture occurred in almost all of the samples as the test temperature decreased. But proper alloy addition, such as B and Ti, and hot-rolling induced a change in the fracture mode to a transgranular mode. Segregation of nitrogen and/or oxygen to grain boundaries was often recognized in plasma beam or electron beam melted ingots and decreased the strength of grain boundaries. Small precipitates due to comparatively low alloy addition such as C, B, Ti and Re, were effective to enhance the grain boundary cohesion. 相似文献
86.
Kouji Kuramochi Ryo Takeuchi Masaharu Takemura Kengo Sakaguchi Susumu Kobayashi Fumio Sugawara 《Tetrahedron》2006,62(34):8006-8015
Synthesis of plakevulin A and structure-activity relationships of its related compounds against DNA polymerases is described. We have achieved a total synthesis and revised the structure of plakevulin A. Several analogues including untenone A, manzamenone A, and optically active plakevulin A, were prepared and tested with an enzyme inhibition assay for mammalian DNA polymerases. The effect of the methyl ester moiety, and the substituents at the 1- and 4-positions of plakevulin A on DNA polymerase activities are discussed. 相似文献
87.
We analyze by wave optics an integral method that produces three-dimensional (3D) images. The point light source is given at the pickup stage, and the light wave passing through each elemental lens is obtained at the display stage. The amplitude distributions of the waves from each elemental image are the same around a specific point where a 3D image is formed. Since the light waves approaching the image plane from different elemental lenses are incoherent, the synthesized value is the sum of the squared amplitudes of the waves. Therefore the modulation transfer function of this integral method is given by that of a single elemental lens. 相似文献
88.
Lingling Wang Yilan Jiang Yi Zhou Ruikai Shi Fumio Hosokawa Osamu Terasaki Qing Zhang 《Particle & Particle Systems Characterization》2023,40(1):2200122
It has become very important to study and find optimal conditions for imaging electron-beam (e-beam) sensitive materials in scanning transmission electron microscopy under low electron-dose with high signal-to-noise ratio (SNR). Convergence and collection angles and electron-probe current are essential parameters. However, these parameters have rarely been discussed in a systematic way. In this paper, the illumination and collection conditions are optimized according to the resolution requirement of different materials by adjusting the condenser and intermediate lenses in a commercial transmission electron microscope. To demonstrate the significance of optimizing these parameters, two examples, zeolite MFI and metal–organic framework (MOF) MIL-101, are taken among the sensitive materials, with the most important electron incidences along the [010] and <110> directions, respectively. High SNR atomic resolution images of MFI are obtained with e-beam current as low as 0.50 pA, reaching information transfer for reflection up to 18 0 2 corresponding to d-spacing of 0.11 nm, close to the resolution limit of 0.098 nm from resolvable diffraction limit. MOF MIL-101 is characterized under an even lower e-beam 0.2 pA to avoid severe beam damage. High-quality annular dark and bright field images are obtained, which proves the wide applicability of this method on more e-beam sensitive materials. 相似文献
89.
Polymerization of optically active disubstituted acetylene monomers by Pd catalyst bearing bulky phosphine ligand 下载免费PDF全文
Yuta Goto Yu Miyagi Natsuhiro Sano Fumio Sanda 《Journal of polymer science. Part A, Polymer chemistry》2017,55(18):3011-3016
Chloro- and aryl-substituted acetylene monomers having an optically active group were polymerized by a Pd catalyst [(tBu3P)PdMeCl] bearing a bulky phosphine ligand, and by MoCl5 for comparison. The corresponding disubstituted acetylene polymers with Mn's = 2000–19,500 and 6900–10,800 were obtained in 29–83% and 11–62% yields when the Pd and Mo catalysts were used, respectively. The formation of polyacetylenes, poly[(R)- 1p ], poly[(R)- 1m ], and poly[(S)- 2p ] were confirmed by SEC and the presence of a Raman scattering peak based on the alternating double bonds of the main chain. Pd-based poly[(R)- 1m ] exhibited CD signals around 350 nm assignable to a certain secondary structure, while Mo-based poly[(R)- 1m ] did not. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 3011–3016 相似文献
90.
Rapid one-step synthesis, characterization and functionalization of silica coated gold nanoparticles
Newaz Mohammed Bahadur Shun WatanabeTakeshi Furusawa Masahide Sato Fumio KurayamaIqbal Ahmed Siddiquey Yoshio KobayashiNoboru Suzuki 《Colloids and surfaces. A, Physicochemical and engineering aspects》2011,392(1):137-144
This paper describes a rapid, simple and one-step method for preparing silica coated gold (Au@SiO2) nanoparticles with fine tunable silica shell thickness and surface functionalization of the prepared particles with different groups. Monodispersed Au nanoparticles with a mean particle size of 16 nm were prepared by citrate reduction method. Silica coating was carried out by mixing the as prepared Au solution, tetraethoxysilane (TEOS) and ammonia followed by microwave (MW) irradiation. Although there are several ways of coating Au nanoparticles with silica in the literature, each of these needs pre-coating step as well as long reaction duration. The present method is especially useful for giving the opportunity to cover the colloidal Au particles with uniform silica shell within very short time and forgoes the use of a silane coupling agent or pre-coating step before silica coating. Au@SiO2 nanoparticles with wide range of silica shell thickness (5-105 nm) were prepared within 5 min of MW irradiation by changing the concentration of TEOS only. The size uniformity and monodispersity were found to be better compared to the particles prepared by conventional methods, which were confirmed by dynamic light scattering and transmission electron microscopic techniques. The prepared Au@SiO2 nanoparticles were further functionalized with amino, carboxylate, alkyl groups to facilitate the rapid translation of the nanoparticles to a wide range of end applications. The functional groups were identified by XPS, and zeta potential measurements. 相似文献