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71.
Analysis of recognition of fructose by imprinted polymers 总被引:1,自引:0,他引:1
Binding of fructose to the fructose imprinted polymer (MIP(Frc)) and pinacol imprinted polymer (control) were studied both in batch and a flow through mode. The influence of the cross-linkers ethylene glycol dimethacrylate (EDMA) and trimethylolpropane trimethacrylate (TRIM) on the binding characteristics was analysed. TRIM cross-linked MIPs showed a lower (unspecific) binding for the control polymer (pinacol imprinted) and higher binding of fructose as compared with the EDMA-MIPs. Furthermore interactions of a TRIM cross-linked molecularly imprinted polymer against fructose and its corresponding template were studied using a thermistor. Label-free detection of fructose was realised in the range of 0.5-10mM. The difference in enthalpy changes between specific binding of fructose to boronic acid moieties of the MIP and non-specific binding to the matrix leads to an 18-fold higher apparent imprinting factor than batch binding studies. Cross-reactivity studies using MIP sensor indicate that the interaction of fructose to MIP generates higher signal than disaccharides. The studies described in this paper demonstrate the potential of direct characterisation of molecular binding events. 相似文献
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73.
Garipcan B Winters J Atchison JS Cathell MD Schiffman JD Leaffer OD Nonnenmann SS Schauer CL Pişkin E Nabet B Spanier JE 《Langmuir : the ACS journal of surfaces and colloids》2008,24(16):8944-8949
We report on the nanopatterning of double-bond-terminated silane (5-hexenyltrichlorosilane, HTCS) molecules on titania (TiO2) using conductive atomic force microscopy (AFM). The influences of tip electrostatic potential and scanning velocity, relative humidity and of the repeated application of voltage on the topographic height, width, and hydrophilic and hydrophobic contrast of the resultant patterns were investigated. Tip voltage and tip velocity ( v) were applied between -10 V 相似文献
74.
Mikolasch A Wurster M Lalk M Witt S Seefeldt S Hammer E Schauer F Jülich WD Lindequist U 《Chemical & pharmaceutical bulletin》2008,56(7):902-907
Novel cephalosporins, penicillins, and carbacephems were synthesized by amination of catechols with amino-beta-lactams like cefadroxil, amoxicillin, ampicillin and the structurally related carbacephem loracarbef using laccase from Trametes sp. All isolated monoaminated products inhibited the growth of several Gram positive bacterial strains in the agar diffusion assay, among them methicillin-resistant Staphylococcus aureus strains and vancomycin-resistant Enterococci. Observed differences in the cytotoxicity and in vivo activity in a "Staphylococcus-infected, immune suppressed mouse" model are discussed. 相似文献
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77.
[BuN(CH2CH2)3NBu]3[Pb5I16] · 4 DMF – an Iodoplumbate Anion with approximately D 5h Symmetry The star‐shaped anion of [BuN(CH2CH2)3NBu]3‐[Pb5I16] · 4 DMF ( 1 ) consists of a cyclic arrangement of five PbI6 octahedra sharing one common I atom in the centre of an almost planar Pb5 ring. Compound 1 crystallizes in space group P21 with a = 1657.2(1), b = 2029.2(1), c = 1773.6(1) pm, β = 113.238(8)°, Z = 2. 相似文献
78.
Polymeric Iodoplumbates – Synthesis and Crystal Structures of (Pr3N–C2H4–NPr3)[Pb6I14(dmf)2] · 4 DMF, (Pr3N–C2H4–NPr3)[Pb(dmf)6][Pb5I14] · DMF, and (Me3N–C2H4–NMe3)2[Pb2I7]I (Pr3N–C2H4–NPr3)[Pb6I14(dmf)2] · 4 DMF ( 1 ) and (Pr3N–C2H4–NPr3)[Pb(dmf)6][Pb5I14] · DMF ( 2 ) have almost the same composition, but completely different structures. Both compounds are formed selectively depending on the reaction and crystallization conditions. In 2 the PbII atoms are coordinated either by six bridging I– ligands in the two-dimensional [Pb5I14]4– network or by six DMF ligands in the [Pb(dmf)6]2+ cations. In contrast, (Me3N–C2H4–NMe3)2[Pb2I7]I ( 3 ) contains non-coordinating I– anions between the iodoplumbate layers. The iodoplumbate anions in 2 and 3 consist of face and corner sharing PbI6 octahedra, whereas in 1 PbI6 and PbI5(dmf) octahedra share common edges to form a one-dimensional polymeric section of the PbI2 structure. (Pr3N–C2H4–NPr3)[Pb6I14(dmf)2] · 4 DMF ( 1 ): Space group P1, a = 920.1(3), b = 1597.2(5), c = 1613.9(4) pm, α = 66.02(2), β = 84.53(2), γ = 85.99(2)°, V = 2156(1) · 106 pm3; (Pr3N–C2H4–NPr3)[Pb(dmf)6][Pb5I14]·DMF ( 2 ): Space group P21, a = 1201.21(9), b = 3031.1(2), c = 1294.96(9) pm, β = 108.935(7)°, V = 4459.8(5) · 106 pm3; (Me3N–C2H4–NMe3)2[Pb2I7]I ( 3 ): Space group Pnma, a = 2349.9(2), b = 1623.83(9), c = 980.75(7) pm, V = 3742.4(5) · 106 pm3. 相似文献
79.
Schaller Ch. Schauer T. Dirnberger K. Eisenbach C.D. 《The European physical journal. E, Soft matter》2001,6(1):365-376
The European Physical Journal E - A series of well-defined amphipolar block, graft and statistical copolymers based on the same polar and non-polar monomers were synthesized and investigated for... 相似文献
80.
Iodoplumbates with Tetra‐ and Penta‐coordinated Pb2+ Ions In contrast to all known iodoplumbates with octahedrally coordinated Pb2+ ions, square pyramidal geometry is observed in the iodoplumbate chains of (Pr4N)[PbI3] ( 1 ) and [Mg(dmf)6][PbI3]2 ( 2 ), whereas the isolated anions in (Ph4P)2[Pb2I6] ( 3 ) and [Bu3N–(CH2)3–NBu3][PbI4] ( 4 ) contain tetra‐coordinated lead atoms. (Pr4N)[PbI3] ( 1 ): a = 910.86(6), b = 1221.46(7), c = 1907.7(1) pm, V = 2122.5(2) · 106 pm3, space group P212121; [Mg(dmf)6][PbI3]2 ( 2 ): a = 891.24(9), b = 1025.34(7), c = 1234.82(9) pm, α = 92.938(8), β = 106.457(8), γ = 98.100(7)°, V = 1066.4(2) · 106 pm3, space group P1; (Ph4P)2[Pb2I6] ( 3 ): a = 1174.5(1), b = 722.29(7), c = 3104.8(4) pm, β = 100.50(1)°, V = 2589.8(5) · 106 pm3, space group P21/n; [Bu3N–(CH2)3–NBu3][PbI4] ( 4 ): a = 2178.3(1), b = 1008.63(5), c = 1888.3(1) pm, β = 110.003(5)°, V = 3898.6(4) · 106 pm3, space group P2/c. 相似文献