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61.
62.
The composition-independent virial coefficients of a d-dimensional binary mixture of (additive) hard hyperspheres following from a recent proposal for the equation of state of the mixture (Santos, A., Yuste, S. B., and López de Haro, M., 1999, Molec. Phys., 96, 1) are examined. Good agreement between theoretical estimates and available exact or numerical results is found for d = 2, 3, 4 and 5, except for mixtures whose components are very disparate in size. A slight modification that remedies this deficiency is introduced and the resummation of the associated virial series is carried out, leading to a new proposal for the equation of state. The case of binary hard sphere mixtures (d = 3) is analysed in some detail. 相似文献
63.
BARB FLORIN DAN; DE KONING WILLEM L.; IONESCU VLAD 《IMA Journal of Mathematical Control and Information》1995,12(3):253-298
This paper represents a Popov-theory-based assessment of thecurrent status of the digital control of infinitedimensionalsystems with certain unboundedness in control and/or observation,summarizing some results and indicating which, in the authors'opinion, would be the promising directions for future research. 相似文献
64.
This paper deals with robustness of adaptive control of continuoussystems subject to known output delay, input saturation, unmodelledlinear dynamics, and bounded disturbances. A simple gradient-typealgorithm with a relative deadzone is used. The relative deadzoneis built with an estimated contribution of the unmodelled dynamicsto the system output. The basic tool used for stability androbustness analysis is Gronwall's lemma. 相似文献
65.
An impulse approximation calculation is made on the reaction 51V(γ, π+)51Ti from the region just above photopion threshold to the tail of the (3, 3) resonance. Pion final state distortions are taken into account through realistic optical potentials. Results are compared to those for plane-wave and surface-produced pions and to recent experiment. Comparison is made between surface-produced pions and pions distorted by the s-wave component of the optical potential. 相似文献
66.
Sushil K. Misra Serguei I. Andronenko Prem Chand Keith A. Earle Sergei V. Paschenko Jack H. Freed 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2005,174(2):2308-269
EPR measurements have been carried out on a single crystal of Mn(2+)-doped NH(4)Cl(0.9)I(0.1) at 170-GHz in the temperature range of 312-4.2K. The spectra have been analyzed (i) to estimate the spin-Hamiltonian parameters; (ii) to study the temperature variation of the zero-field splitting (ZFS) parameter; (iii) to confirm the negative absolute sign of the ZFS parameter unequivocally from the temperature-dependent relative intensities of hyperfine sextets at temperatures below 10K; and (iv) to detect the occurrence of a structural phase transition at 4.35K from the change in the structure of the EPR lines with temperature below 10K. 相似文献
67.
Karl F. Freed 《Chemical physics letters》1974,24(2):275-279
Results of ab initio calculations of correlation energies are used to estimate the correlation contribution to true repulsion integrals γpq. The one-center true γpp and the distance dependence of the true γpq are shown to be in semi-quantitative agreement with the empirical resonance integrals used in pi-electron theories. The relationship between the true γpp and the difference between true molecular ionization potentials and electron affinities is also discussed. 相似文献
68.
The exact pi-electron hamiltonian is derived from the full many-electron Schrödinger equation. The derivation employs techniques which also enable the development of open shell generalized perturbation theory. The parameters occurring in the pi-hamiltonian are therefore amenable to calculation using the approximate theories and methods of Sinano?lu, Nesbet, Kelly, etc. To a good approximation, the pi-hamiltonian is found to be generally consistent with its customarily assumed form. 相似文献
69.
The vibrational relaxation of a polyatomic molecule in a condensed host is studied by a consideration of two molecular vibrations. Relaxation processes, intermode coupling terms and vibrational frequency fluctuation contributions are retained. Population decay (T1), dephasing (T2), and coherence transfer rates are evaluated through second order in the limit where the host bath dynamics are rapid compared to these molecular timescales. The rates are expressed in terms of temperature and frequency dependent bath correlation functions. For the special case of a three level system (the ground state and ones where one of the two vibrational modes is excited) the important effects of anharmonicity are incorporated. It is shown that certain coherence transfer terms involve zero frequency bath correlation functions, so they should be larger than the high frequency ones which obey modified energy gap laws. A discussion is presented of the types of interactions which may contribute to these coherence transfer processes. 相似文献
70.
The main focus of this work is to model macroscopically the effects of partial saturation upon the permeability of dual scale fibrous media made of fiber bundles when a Newtonian viscous fluid impregnates it. A new phenomenological model is proposed to explain the discrepancies between experimental pressure results and analytical predictions based on Darcy's law. This model incorporates the essential features of relative permeability but without the necessity of measuring saturation of the liquid for its prediction. The model is very relevant for the small scale industrial systems where a liquid is forced to flow through a fibrous porous medium. It requires four parameters. Two of them are the two permeability values based on the two length scales. One length scale is of the order of magnitude of the individual fiber radius and corresponds to the permeability of the completely staurated medium, the other is of the order of magnitude of the distance between the fiber bundles and corresponds to the permeability of the partially saturated medium. The other two parameters are the lengths of the two partially saturated regions of the flow domain. The two lengths of the partially saturated region and the permeability of the fully saturated flow domain can be directly measured from the experiments. The excellent agreement between the model and the experimental results of inlet pressure profile with respect to time suggests that this model may be used to describe the variation of the permeability behind a moving front in such porous media for correct pressure prediction. It may also be used to characterize the fibrous medium by determining the two different permeabilities and the relative importance of the unsaturated portion of the flow domain for a given architecture. 相似文献