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61.
Substituted 2-bromobenzaldehydes were synthesized from benzaldehydes using a three-step sequence involving a selective palladium-catalyzed ortho-bromination as the key step. O-Methyloxime serves as a directing group in this reaction. A rapid deprotection of substituted 2-bromobenzaldoximes afforded substituted 2-bromobenzaldehydes with good overall yields. 相似文献
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65.
The identification of (3, 4-dihydro-2H-pyran-5-yl)-oxo-acetic acid methyl ester has been realized by combination of two dimensional HETCOR and HMBC techniques. 13C and 1H chemical shifts asignements are described. 相似文献
66.
Frederic Paik Schoenberg 《Annals of the Institute of Statistical Mathematics》2002,54(2):445-457
The process obtained by rescaling a homogeneous Poisson process by the maximum likelihood estimate of its intensity is shown to have surprisingly strong self-correcting behavior. Formulas for the conditional intensity and moments of the rescaled Poisson process are derived, and its behavior is demonstrated using simulations. Relationships to the Brownian bridge are explored, and implications for point process residual analysis are discussed. 相似文献
67.
LetG be a connected Poisson-Lie group. We discuss aspects of the question of Drinfel'd:can G be quantized? and give some answers. WhenG is semisimple (a case where the answer isyes), we introduce quantizable Poisson subalgebras ofC ∞(G), related to harmonic analysis onG; they are a generalization of F.R.T. models of quantum groups, and provide new examples of quantized Poisson algebras. 相似文献
68.
We have designed and tested a new relativistic Lagrangian hydrodynamics code, which treats gravity in the conformally flat
approximation to general relativity. We have tested the resulting code extensively, finding that it performs well for calculations
of equilibrium single-star models, collapsing relativistic dust clouds, and quasi-circular orbits of equilibrium solutions.
By adding a radiation reaction treatment, we compute the full evolution of a coalescing binary neutron star system. We find
that the amount of mass ejected from the system, much less than a per cent, is greatly reduced by the inclusion of relativistic
gravitation. The gravity wave energy spectrum shows a clear divergence away from the Newtonian point-mass form, consistent
with the form derived from relativistic quasi-equilibrium fluid sequences. 相似文献
69.
Philip Birch Gongde Li Frederic Claret-Tournier Rupert Young Chris Chatwin 《Optics and Lasers in Engineering》2004,41(6):919-926
Two optical lenses are used to compose a surface position measuring system. A measurand is positioned near the front focal point of the first lens. At the output end of the other lens, a beam splitter is used to split the beam into two paths. One photodetector is positioned before the focal point of the lens in one path and another after the focal point in the other so that the intensities falling onto the two detectors can be adjusted to be equal when the first lens is in focus. This device provides a compact and high-accuracy surface sensor. In this paper, the design and experimental study of the sensor system is described. It is shown that such a sensor embodiment can lead to a resolution of 1 μm. 相似文献
70.
Frederic Paik Schoenberg 《Annals of the Institute of Statistical Mathematics》2006,58(2):223-233
Simple point processes are often characterized by their associated compensators or conditional intensities. Non-simple point
processes are not uniquely determined by their conditional intensity and compensator, so instead one may identify with the
point process its associated simple point process and corresponding conditional intensity, on an expanded mark space. Some
relations between the conditional intensity on the expanded mark space and the ordinary conditional intensity are investigated
here, and some classes of separable non-simple processes are presented. Transformations into simple point processes, involving
thinning and rescaling, are presented. 相似文献