全文获取类型
收费全文 | 367篇 |
免费 | 30篇 |
专业分类
化学 | 249篇 |
晶体学 | 1篇 |
力学 | 13篇 |
数学 | 60篇 |
物理学 | 74篇 |
出版年
2023年 | 1篇 |
2022年 | 5篇 |
2021年 | 8篇 |
2020年 | 7篇 |
2019年 | 10篇 |
2018年 | 11篇 |
2017年 | 9篇 |
2016年 | 10篇 |
2015年 | 18篇 |
2014年 | 21篇 |
2013年 | 20篇 |
2012年 | 38篇 |
2011年 | 40篇 |
2010年 | 18篇 |
2009年 | 17篇 |
2008年 | 32篇 |
2007年 | 32篇 |
2006年 | 32篇 |
2005年 | 18篇 |
2004年 | 10篇 |
2003年 | 8篇 |
2002年 | 11篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1997年 | 1篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1989年 | 3篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有397条查询结果,搜索用时 31 毫秒
81.
Bernard Fongang Yvan Labaye Florent Calvayrac Serge Zekeng Jean-Marc Grenèche 《Journal of magnetism and magnetic materials》2012
We present a numerical study of the magnetic structure of nanostructured iron fluoride, using the Monte Carlo Metropolis simulated annealing technique and a classical Heisenberg Hamiltonian with superexchange angle dependent interactions. The parameters are adjusted on experimental results, and the atomic structure and topology taken from a previous atomistic model of grain boundaries in the same system. We find perfect antiferromagnetic crystalline grains and a disordered magnetic configuration (speromagnetic) at the grain boundary, in agreement with experimental features. Both the lowest magnetic energy and the rate of magnetic frustration are found to be dependent on the relative disorientation of crystalline grains, i.e. on the cationic topology. We conclude on possible extensions of the model. 相似文献
82.
Core–shell and gradient morphology polymer particles analyzed by X‐ray photoelectron spectroscopy: Effect of monomer feed order 下载免费PDF全文
Florent Jasinski Victoria L. Teo Rhiannon P. Kuchel Monique Mballa Mballa Stuart C. Thickett Richard H. G. Brinkhuis William Weaver Per B. Zetterlund 《Journal of polymer science. Part A, Polymer chemistry》2017,55(15):2513-2526
The synthesis of composite latex particles possessing core–shell and gradient morphologies, respectively, using seeded starve‐fed semibatch emulsion polymerization of styrene (St) and methyl methacrylate (MMA) is presented. The focus is on the effect of the monomer feed order on the particle morphology development. The particle morphology is assessed using a novel approach which entails comparing the experimental surface composition as a function of polymerization time (particle growth) obtained by X‐ray photoelectron spectroscopy with the predicted surface composition using a mass balance mathematical model. Both types of composite latexes (core–shell and gradient) feature changes with polymerization time in the oxygen/carbon surface composition which enables one to track the morphology development. Differential scanning calorimetry is also implemented to analyze the extent of phase separation. The monomer feed order is shown to play a crucial role—under the present conditions, gradient and core–shell particles are obtained if the feed order is St/MMA (St fed first), but not if the feed order is reversed. These findings illustrate that thermodynamic factors are important, given that thermodynamically it is more favorable for MMA‐rich chains to occupy the oil–water interface to reduce the interfacial tension. Systems where St is the second stage monomer lead to mixed structures rather than the targeted core–shell or gradient morphology with St‐rich chains at the particle surface. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 2513–2526 相似文献
83.
84.
85.
Gilles Chaumat Florent Duval Rémi Blinder Pierre-Alain Bayle Michel Bardet 《Magnetic resonance in chemistry : MRC》2020,58(9):820-829
Conservation treatment of degraded archaeological osseous materials is still an open challenge, since no specific conservation protocol is currently available for restorers or museum curators. This work aims to test the efficiency of two original consolidant solutions in consolidating archaeological material. Archaeological osseous materials remain rare and sparsely available, it is a real drawback for optimization of conservation treatments, therefore in the present work a set of representative samples was chosen. The consolidants tested were a solution of disodium sebacate and a novel polyalcohol (SG1.2) obtained by esterification of 5 succinic diacids with 6 molecules of glycerol at 150°C. Characterization studies of archaeological bones, combining SEM microscopy, IR spectroscopy and high-resolution solid-state 13C NMR investigations, have been carried out to assess the effective permeation of bone by the consolidant solutions and to determine their chemical interactions with the residual components of archaeological bones. Although both water solutions significantly impregnate bone, we show that, the solution with disodium sebacate leads to chemical attack on the mineral component due to preferential precipitation of endogenous calcium by the sebacate ions. Such deleterious behaviour is not observed at all with the SG1,2 chemicals. The added value of the polyalcohol treatment as strengthening agent suitable for archaeological bony materials should be further demonstrated by mechanical and ageing tests. 相似文献
86.
87.
Florent Moutier Dr. Jana Schiller Dr. Constance Lecourt Dr. Ali Moustafa Khalil Dr. Vincent Delmas Dr. Guillaume Calvez Dr. Karine Costuas Dr. Christophe Lescop 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(24):e202104497
A new highly solid-state luminescent phase of a previously reported weakly luminescent CuI8PdII1 dicationic assembly is reported revealing the high geometrical versatility of this moiety that importantly alters its luminescent properties. This very minor new species Bc is based on a different conformer scaffold than the one encountered in the previously reported Bo form and, essentially differs from Bo by displaying shorter CuI-CuI intermetallic distances. DFT calculations allow concluding that the predominance in the solid-state of the weakly luminescent and less stable Bo phase is due to the extra stability induced by a larger number of intermolecular non-covalent π-CH interactions in its crystalline packing and not by the intrinsic stability of the CuI8PdII1 dicationic moiety. Calculations also revealed that a more stable conformation Bcalc is expected in vacuum, which bears a different distribution of CuI-CuI intermetallic distances than the dications in Bo and Bc phases. Taking into account that the geometrical alterations are associated to drastic changes of luminescence properties, this confer to the CuI8PdII1 assembly high potentiality as stimuli-sensitive luminescent materials. Indeed, by applying mechanical or thermal stress to samples of Bo phase, new phases Bg and Bm , respectively, were obtained. Alterations of the solid-state photophysical properties of these new species compared to those recorded for Bo are reported together with a combined experimental and computed study of the structures/properties relationships observed in these phases. 相似文献
88.
Modulation of Relaxivity,Suspension Stability,and Biodistribution of Dendronized Iron Oxide Nanoparticles as a Function of the Organic Shell Design 下载免费PDF全文
Aurélie Walter Audrey Parat Antonio Garofalo Sophie Laurent Luce Vander Elst Robert N. Muller Tao Wu Emilie Heuillard Eric Robinet Florent Meyer Delphine Felder‐Flesch Sylvie Begin‐Colin 《Particle & Particle Systems Characterization》2015,32(5):552-560
Nanoparticles (NPs) with a mean diameter of 10 nm are functionalized with three dendrons: D1 a PEGylated PAMAM dendron of generation 0.5, D2 a hydrophilic oligoethyleneglycol‐derivatized dendron (D2) displaying a phosphonic acid at the focal point, and D2–2P the same dendron than D2 but with two phosphonic acid anchoring agents. Their grafting is confirmed by IR spectroscopy and elemental analysis. All dendronized NPs are stable over a long period of time in suspensions in water and in different physiological media and display a mean hydrodynamic diameter smaller than 50 nm whatever the molecule architecture. NMRD profiles and relaxivity measurements highlight the influence of the molecule architecture on the water diffusion close to the magnetic core thus influencing the relaxation properties at low magnetic field. The high hydrophilic architecture of the dendron D2 by contrast to dendron D1 allows maintaining the colloidal stability in different conditions while ensuring a very good accessibility of water molecule close to the magnetic core. Coupling of a fluorescent dye on dendrons have allowed investigating the biodistribution of dendronized NPs, which are found to be quickly eliminated through urinary and hepatobiliary pathways within 4 h. Furthermore, no enhanced permeation and retention effect in tumors can be observed. 相似文献
89.
90.
Florent Hivert Jean-Christophe Novelli Lenny Tevlin Jean-Yves Thibon 《Selecta Mathematica, New Series》2009,15(1):105-119
We prove conjectures of the third author [L. Tevlin, Proc. FPSAC’07, Tianjin] on two new bases of noncommutative symmetric
functions: the transition matrices from the ribbon basis have nonnegative integral coefficients. This is done by means of
two composition-valued statistics on permutations and packed words, which generalize the combinatorics of Genocchi numbers.
相似文献