全文获取类型
收费全文 | 419篇 |
免费 | 19篇 |
国内免费 | 3篇 |
专业分类
化学 | 261篇 |
力学 | 16篇 |
数学 | 43篇 |
物理学 | 121篇 |
出版年
2023年 | 4篇 |
2022年 | 5篇 |
2021年 | 5篇 |
2020年 | 9篇 |
2019年 | 14篇 |
2018年 | 23篇 |
2017年 | 14篇 |
2016年 | 33篇 |
2015年 | 15篇 |
2014年 | 32篇 |
2013年 | 49篇 |
2012年 | 38篇 |
2011年 | 51篇 |
2010年 | 23篇 |
2009年 | 30篇 |
2008年 | 27篇 |
2007年 | 19篇 |
2006年 | 14篇 |
2005年 | 8篇 |
2004年 | 6篇 |
2003年 | 1篇 |
2002年 | 3篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1995年 | 1篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
排序方式: 共有441条查询结果,搜索用时 15 毫秒
71.
Rahmat Sadeghi Rahim Hosseini 《Colloids and surfaces. A, Physicochemical and engineering aspects》2009,348(1-3):177-185
The volumetric, compressibility and electrical conductivity properties of sodium n-heptyl sulfonate (C7SO3Na) in pure water and in aqueous poly(ethylene glycol) (PEG) solutions were determined at different temperatures below and above the micellar composition range. At each temperature, the infinite dilution apparent molar volumes of the monomer and micellar state of C7SO3Na in aqueous PEG solutions respectively are smaller and larger than those in pure water. However, the values of the infinite dilution apparent molar isentropic compressibility of both monomer and micellar states of C7SO3Na in aqueous PEG solutions are larger than those in pure water. Thermodynamic parameters of micellization of investigated surfactant in water and in aqueous solutions of PEG at different temperatures were estimated and it was found that the micelle formation process is endothermic and therefore, this process must be driven by entropy increase. The calculated Gibbs free energies of micellization for aqueous PEG solutions are more negative than those for pure water and become more negative by increasing temperature. The variation of the critical micelle concentration (CMC) of C7SO3Na in water and in aqueous PEG solutions with temperature was obtained and a comparison between the CMC of C7SO3Na obtained from different thermodynamic properties was also made. 相似文献
72.
Cu2+ selective PVC membrane electrode based on new Schiff base 2, 2'-[1,9 nonanediyl bis (nitriloethylidyne)]-bis-(1-naphthol) as a selective carrier was constructed. The electrode exhibited a linear potential response within the activity range of 1.0 x 10(-6) - 5.0 x 10(-3) moll(-1) with a Nernstian slope of 29 +/- 1 mV decade(-1) of Cu2+ activity and a limit of detection 8.0 x 10(-7) mol l(-1). The response time of the electrode was fast, 10 s, and stable potentials were obtained within the pH range of 3.5- 6.5. The potentiometric selectivity coefficients were evaluated using two solution method and revealed no important interferences except for Ag+ ion. The proposed electrode was applied as an indicator electrode to potentiometric titration of Cu2+ ions and determination of Cu2+ content in real samples such as black tea leaves and multivitamin capsule. 相似文献
73.
Two simple and accurate spectrophotometric methods for determination of Rifampicin (RIF) are described. The first method is based on charge transfer (CT) complex formation of the drug with three pi-electron acceptors either 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 7,7,7,8-Tetracyanoquinodimethane (TCNQ) or 2,3,5,6-Tetrachloro-1,4-benzoquinone (p-chloranil) in acetonitrile. The method is followed spectrophotometrically by measuring the maximum absorbance at 584 nm, 761 nm (680 nm) or 560 nm for DDQ, TCNQ and p-chloranil, respectively. Under the optimized experimental conditions, the calibration curves showed a linear relationship over the concentration ranges of 5-140 microg/ml, 2-45 microg/ml (5-120 microg/ml) and 15-200 microg/ml, respectively. The second method is based on the reaction of RIF with iron(III) forming a water insoluble violet complex which is extracted into chloroform. The method determines RIF in concentration range of 10-240 microg/ml at 540 nm. The proposed methods applied to determination of RIF in capsule, human serum and urine samples with good accuracy and precision. The results were compared statistically with the official method and showed no significant different between the methods compared in terms of accuracy and precision. 相似文献
74.
A computational method for flutter prediction of turbomachinery cascades is presented. The flow through multiple blade passages is calculated using a time-domain approach with coupled aerodynamic and structural models. The unsteady Euler/Navier-Stokes equations are solved in quasi-three-dimensions using a second-order implicit scheme with dual time-stepping and a multigrid method. A structural model for the blades with bending and torsion degrees of freedom is integrated in time together with the flow field. Information between structural and aerodynamic models is exchanged until convergence in each real-time step. Computational results for a cascade are presented and compared with those obtained by the conventional energy method and with experimental and numerical data by other authors. Significant differences are found between the coupled and uncoupled methods at low mass ratios. A transonic test case with strong nonlinear phenomena is investigated with the fluid-structure coupled method. Results for inviscid flow are compared with results of Navier-Stokes computations. 相似文献
75.
Hamid Reza Farmani Mohammad Hossein Mosslemin Bahareh Sadeghi 《Molecular diversity》2018,22(3):743-749
Rapid, efficient, simple and green procedure for the synthesis of 4,5-dihydro-1H-pyrazole-1-carbothioamides via the multicomponent reaction of aryl aldehydes, acetophenones and thiosemicarbazide in water in the presence of tetrabutylammonium hydroxide under microwave irradiation is reported. 相似文献
76.
Mohammad Sadegh Sadeghi Zadeh Monireh Houshmand Hossein Aghababa 《International Journal of Theoretical Physics》2018,57(1):175-183
A new protocol of bidirectional quantum teleportation (BQT) is proposed in which the users can transmit a class of n-qubit state to each other simultaneously, by using (2n + 2)-qubit entangled states as quantum channel. The state of the art approaches can only transmit two-qubit states in each round. This scheme is based on control-not operation, single-qubit measurements and appropriate single-qubit unitary operations. It is shown that the protocol is secure in preparation phase. 相似文献
77.
Designing and introducing novel wheel-shaped supramolecular as host complexes with new magnetic properties is the theme of the day. So in this study, new eight binuclear chromium (III) complexes, as models of real chromium-wheel host complexes, were designed based on changing of bridged-ligands and exchange coupling constants (J) of them were calculated using the broken symmetry density functional theory approach. Substitution of fluorine ligand in fluoro-bridged model [Cr2F(tBuCO2)2(H2O)2(OH)4]?1 by halogen anions (Cl?, Br? and I? ) decreased the antiferromagnetic exchange coupling between Cr(III) centres such that by going from F? to I? the J values became more positive. In the case of hydroxo-bridged model [Cr2OH(tBuCO2)2(H2O)2(OH)4]?1, replacement of hydroxyl by methoxy anion (OMe?) strengthened the antiferromagnetic property of the complex but substitution by sulfanide (SH?) and amide (NH2?) anions weakened it and changed the nature of complexes to ferromagnetic. Because of their different magnetic properties, these new investigated complexes can be suggested as interesting synthetic targets. Also, the J value changes due to ligand substitution were evaluated and it was found that the Cr–X bond strength and partial charges of involved atoms were the most effective factors on it. 相似文献
78.
Faezeh Farzaneh Yasaman Sadeghi Mahboobeh Maghami Zeinab Asgharpour 《Journal of Cluster Science》2016,27(5):1701-1718
In this study, magnetically recoverable vanadium complexs designated as VO(Sal-Tryp)/AmpSCMNPs and VO(Sal-His)/AmpSCMNPs were prepared through immobilization of Schiff bases of histidine or tryptophan with salicylaldehyde on the surface of modified silica coated iron oxide magnetite nanoparticles with (3-aminopropyl) trimethoxysilane as aminopropyl (Amp) spacer followed by complexation with VOSO4. Characterization was carried out by chemical analysis, Fourier transform infrared spectroscopy, XRD, scanning electron microscopy and vibrating sample magnetometry techniques. VO(Sal-Tryp)/AmpSCMNPs and VO(Sal-His)/AmpSCMNP were found to catalyze the epoxidation of allyl alcohols and olefins with tert-butyl hydroperoxide with excellent conversions and selectivities. Investigation of the stability and reusability revealed the heterogeneity character of the catalyst with no desorption during the course of epoxidation reactions. High yields, clean reactions, easily catalyst separation and recyclability of the solid catalyst are some advantages of this method. 相似文献
79.
J. Sadeghi B. Pourhassan Z. Abbaspour Moghaddam 《International Journal of Theoretical Physics》2014,53(1):125-135
In this paper we consider holographic dark energy model with corrected holographic energy density and show that this model may be equivalent to the modified Chaplygin gas model. Then we obtain relation between entropy corrected holographic dark energy model and scalar field models. We do these works by using choices of IR cut-off length proportional to the Hubble radius, the event horizon radius, the Ricci length, and the Granda-Oliveros length. 相似文献
80.
In this paper we study thermodynamics, statistics and spectroscopic aspects of a charged black hole with a scalar hair coupled to the gravity in (2+1) dimensions. We obtained effects of the black hole charge and scalar field on the thermodynamical and statistical quantities. We find that scalar charge may increase entropy, temperature and probability, while may decrease black hole mass, free and internal energy. Also electric charge increases probability and decreases temperature and internal energy. Also we investigate stability of the system and find that the thermodynamical stability exists. 相似文献