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排序方式: 共有199条查询结果,搜索用时 656 毫秒
31.
The local structure around the Nd impurity introduced at the Bi site in the Bi4Ge3O12 compound is theoretically investigated by density-functional theory based augmented plane wave method. A set of parameters that completely describes the Nd neighborhood is calculated by treating the Nd 4f electrons either as localized or as delocalized. In both cases the local structure was dominantly determined by the Nd departure from the ideal host position along the trigonal axis. Displacement occurs in the direction towards the center of the Oxygen octahedron around the Nd. 相似文献
32.
Vera S. O. Farias Wilton Pereira da Silva Cleide M. D. P. S. e Silva Vicente P. T. Rocha Antonio G. B. Lima 《Heat and Mass Transfer》2013,49(5):695-709
This article proposes a numerical solution for the diffusion equation applied to solids with arbitrary geometry using non-orthogonal structured grids for the boundary condition of the first kind. A transient three-dimensional mathematical formulation written in boundary fitted coordinates and numerical formalism to discretize the diffusion equation by using the finite volume method, including numerical analysis of the computational solution are presented. To validate the proposed solution, the results obtained in this work were compared with well-known numerical solution available in literature and good agreement was observed. In order to verify the potential of the proposed numerical solution, it was applied to describe mass transfer inside ceramic roof tiles during drying. For that, it was used experimental data of the drying kinetics at the following temperatures: 55.6; 69.7; 82.7 and 98.6 °C. An optimization technique using experimental dataset has been presented to estimation of transport properties. The obtained statistical indicators enable to conclude that the numerical solution satisfactorily describes the drying processes. 相似文献
33.
G. A. Farias M. M. Auto E. L. Albuquerque P. Fulco 《Zeitschrift für Physik B Condensed Matter》1990,80(2):207-211
We consider the effects of a charge layer (accumulation and depletion layers) on the spectrum of collective plasmon-polariton modes of a semiconductor superlattice consisting of alternating mediaA andB, where mediumA is an-doped semiconductor and mediumB an insulator. The effect of the charge layer is taken into account assuming a linear position dependence for the free-carrier concentration and for the dielectric function, within mediumA. Applications are made considering mediumA asn-type semiconductor and mediumB being vacuum. We compare our results with those obtained in the abscence of the charge layer and we discuss their differences. 相似文献
34.
Supercritical fluid chromatography with photodiode array detection for pesticide analysis in papaya and avocado samples 下载免费PDF全文
Norma S. Pano‐Farias Silvia G. Ceballos‐Magaña Jorge Gonzalez José M. Jurado Roberto Muñiz‐Valencia 《Journal of separation science》2015,38(7):1240-1247
To improve the analysis of pesticides in complex food matrices with economic importance, alternative chromatographic techniques, such as supercritical fluid chromatography, can be used. Supercritical fluid chromatography has barely been applied for pesticide analysis in food matrices. In this paper, an analytical method using supercritical fluid chromatography coupled to a photodiode array detection has been established for the first time for the quantification of pesticides in papaya and avocado. The extraction of methyl parathion, atrazine, ametryn, carbofuran, and carbaryl was performed through the quick, easy, cheap, effective, rugged, and safe methodology. The method was validated using papaya and avocado samples. For papaya, the correlation coefficient values were higher than 0.99; limits of detection and quantification ranged from 130–380 and 220–640 μg/kg, respectively; recovery values ranged from 72.8–94.6%; precision was lower than 3%. For avocado, limit of detection values were ?450 μg/kg; precision was lower than 11%; recoveries ranged from 50.0–94.2%. Method feasibility was tested for lime, banana, mango, and melon samples. Our results demonstrate that the proposed method is applicable to methyl parathion, atrazine, ametryn, and carbaryl, toxics pesticides used worldwide. The methodology presented in this work could be applicable to other fruits. 相似文献
35.
Effects of Ultraviolet Radiation (UVA+UVB) and Copper on the Morphology,Ultrastructural Organization and Physiological Responses of the Red Alga Pterocladiella capillacea 下载免费PDF全文
Éder C. Schmidt Marianne Kreusch Marthiellen R. de L. Felix Debora T. Pereira Giulia B. Costa Carmen Simioni Luciane C. Ouriques Francine L. Farias‐Soares Neusa Steiner Fungyi Chow Fernanda Ramlov Marcelo Maraschin Zenilda L. Bouzon 《Photochemistry and photobiology》2015,91(2):359-370
The effect of ultraviolet (UV) radiation and copper (Cu) on apical segments of Pterocladiella capillacea was examined under two different conditions of radiation, PAR (control) and PAR+UVA+UVB (PAR+UVAB), and three copper concentrations, ranging from 0 (control) to 0.62, 1.25 and 2.50 μm . Algae were exposed in vitro to photosynthetically active radiation (PAR) at 70 μmol photons m?2 s?1, PAR + UVB at 0.35 W m?2 and PAR +UVA at 0.70 W m?2 during a 12‐h photocycle for 3 h each day for 7 days. The effects of radiation and copper on growth rates, content of photosynthetic pigments and photosynthetic performance were analyzed. In addition, samples were processed for light and transmission electron microscopy. The content of photosynthetic pigments decreased after exposure to radiation and Cu. Compared with PAR radiation and copper treatments modified the kinetics patterns of the photosynthesis/irradiance curve. The treatments also caused changes in the ultrastructure of cortical and subcortical cells, including increased cell wall thickness and accumulation of plastoglobuli, as well as changes in the organization of chloroplasts. The results indicate that the synergistic interaction between UV radiation and Cu in P. capillacea, led to the failure of protective mechanisms and causing more drastic changes and cellular imbalances. 相似文献
36.
Influence of substrate temperature and N2/Ar flow ratio on the stoichiometry,structure and hardness of TaNx coatings deposited by DC reactive sputtering 下载免费PDF全文
K. Valdez D. G. Espinosa‐Arbeláez J. E. García‐Herrera J. Muñoz‐Saldaña M. H. Farias W. De la Cruz 《Surface and interface analysis : SIA》2015,47(11):1015-1019
The effect of substrate temperature and N2/Ar flow ratio on the stoichiometry, structure and hardness of TaNx coatings prepared on (111) Si substrates by DC reactive sputtering was investigated. For the structural, chemical and morphological analysis, X‐ray diffraction (XRD), Auger electron scanning and atomic force microscopy were respectively used. Hardness values of thin films were determined using the work of indentation model from nanoindentation measurements. TaN stoichiometric coatings were obtained for samples deposited at room temperature. The stoichiometric TaN phase was not obtained by increasing the temperature up to 773 K, even when increasing the N2/Ar flow ratio. Even when a saturation in nitrogen content was achieved, nitrogen vacancies are still present in those samples. For coatings prepared at 773 K and low N2/Ar flow ratio, a phase mixture between TaNx and cubic α‐Ta was observed, while a cubic structure δ‐TaN was formed by increasing the N2/Ar flow ratio. A maximum in hardness and (38 GPa) was obtained for the sample deposited at 773 K and a N2/Ar flow ratio of 0.2, which presented a δ‐TaN cubic crystalline structure and a roughness value of 1.6 nm. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
37.
L. A. Farias D. I. T. Favaro V. A. Maihara Vasconcellos M. B. A. L. K. Yuyama J. P. L. Aguiar F. J. Alencar 《Journal of Radioanalytical and Nuclear Chemistry》2006,270(1):217-223
Summary Daily dietary intake of Hg and some essential elements in diets of children from communities in the Jaú National Park, Amazon
region, were assessed. Diet samples were analyzed for total Hg content using cold vapor atomic absorption spectrometry and
Ca, Fe, K, Na, Se and Zn contents by instrumental neutron activation analysis. The weekly tolerable provisional intake for
Hg in the communities studied varied from 13 to 57 mg of Hg per kg of body weight, exceeding the limit of 5 mg . kg-1 set by the WHO. Comparison of the daily dietary intake values to the new Dietary Reference Intakes (4-8 years), showed prevalence
of inadequacy. 相似文献
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