首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   12502篇
  免费   2030篇
  国内免费   1761篇
化学   9140篇
晶体学   165篇
力学   748篇
综合类   127篇
数学   1635篇
物理学   4478篇
  2024年   27篇
  2023年   176篇
  2022年   283篇
  2021年   374篇
  2020年   433篇
  2019年   443篇
  2018年   396篇
  2017年   382篇
  2016年   548篇
  2015年   570篇
  2014年   717篇
  2013年   906篇
  2012年   1074篇
  2011年   1220篇
  2010年   878篇
  2009年   896篇
  2008年   1011篇
  2007年   876篇
  2006年   799篇
  2005年   607篇
  2004年   458篇
  2003年   371篇
  2002年   412篇
  2001年   346篇
  2000年   313篇
  1999年   268篇
  1998年   201篇
  1997年   173篇
  1996年   206篇
  1995年   172篇
  1994年   108篇
  1993年   105篇
  1992年   87篇
  1991年   84篇
  1990年   67篇
  1989年   67篇
  1988年   39篇
  1987年   40篇
  1986年   34篇
  1985年   25篇
  1984年   19篇
  1983年   21篇
  1982年   14篇
  1981年   10篇
  1980年   5篇
  1979年   4篇
  1974年   4篇
  1972年   4篇
  1971年   3篇
  1957年   3篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
This paper undertakes a systematic treatment of the low regularity local wellposedness and ill-posedness theory in Hs andHs for semilinear wave equations with polynomial nonlinearity in u and (e)u. This ill-posed result concerns the focusing type equations with nonlinearity on u and (e)tu.  相似文献   
22.
We develop the three-step explicit and implicit schemes of exponential fitting methods. We use the three- step explicit exponential fitting scheme to predict an approximation, then use the three-step implicit exponential fitting scheme to correct this prediction. This combination is called the three-step predictor-corrector of exponential fitting method. The three-step predictor-corrector of exponential fitting method is applied to numerically compute the coupled nonlinear Schroedinger equation and the nonlinear Schroedinger equation with varying coefficients. The numerical results show that the scheme is highly accurate.  相似文献   
23.
A series of pyrimidoquinoline derivatives were synthesized through one‐pot condensation of 2,6‐diaminopyrimidin‐4‐one, aldehyde and cyclic a 1,3‐dicarbonyl compound in glycol under microwave irradiation without catalyst. The protocol in the absence of catalyst has the advantage of good yield (87‐95%), short reaction time (4‐7 min) and an environmentally friendly technique.  相似文献   
24.
A stochastic approximation algorithm for estimating multichannel coefficients is proposed, and the estimate is proved to converge to the true parameters a.s. up-to a constant scaling factor. The estimate is updated after receiving each new observation, so the output data need not be collected in advance. The input signal is allowed to be dependent and the observation is allowed to be corrupted by noise, but no noise statistics are used in the estimation algorithm.  相似文献   
25.
In this Note, we shall consider the Riemannian distance on loop groups, which will be identified to one introduced by Hino and Ramirez [M. Hino, J.A. Ramirez, Small-time Gaussian behavior of symmetric diffusion semigroups, Ann. Probab. 31 (2003) 1254–1295]. A transportation cost inequality is established. To cite this article: S. Fang, J. Shao, C. R. Acad. Sci. Paris, Ser. I 341 (2005).  相似文献   
26.
A new series of copolymers was synthesized through the oxidative polymerization of pyrrole (PY) and o‐phenetidine (PHT) with inorganic oxidants in acidic media. The polymerization parameters including the mixing method of the oxidant with the comonomer, the comonomer ratio, the time, the temperature, the oxidant, the organic medium, and the acid were systematically optimized for the synthesis of copolymers with high yields, intrinsic viscosities, and solubility. The resultant copolymers were characterized by elemental analysis, infrared, ultraviolet–visible, solution high‐resolution 1H NMR and solid‐state high‐resolution 13C NMR, circular dichroism spectroscopy, and cyclic voltammetry. The results showed that the PY observed content in the copolymers was much higher than the PY feed content. The regular variation of the polymerization yield, intrinsic viscosity, solubility, macromolecular structure, and electroactivity of the resulting polymers with the comonomer ratio, together with the complete solubility of a PY/PHT (10/90) polymer in highly polar solvents, indicated the formation of real random copolymers containing both PY and PHT units rather than a mixture of two homopolymers. However, the polymers containing more than 59 mol % PY were not homogeneous copolymers consisting of soluble and insoluble parts. A semiquantitative relationship between the polymerization yield or solubility of the copolymers and the polarity index of the organic solvents was examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2073–2092, 2004  相似文献   
27.
Liquid‐crystalline, segmented polyurethanes with methoxy–biphenyl mesogens pendant on the chain extender were synthesized by the conventional prepolymer technique and esterification reaction. Two, side‐chain, liquid‐crystalline (SCLC) polyurethanes with mesogens having spacers of six and eight methylene units were prepared. The structures of the mesogenic units and SCLC polyurethanes were confirmed by Fourier transform infrared spectroscopy and 1H NMR. Polymer properties were also examined by solubility tests, water uptakes, and inherent viscosity measurements. Differential scanning calorimetry studies indicated that the transition temperature of the isotropic to the liquid‐crystalline phase decreased with increasing spacer length. Wide‐angle X‐ray diffraction (WAXD) studies revealed the existence of liquid‐crystalline phases for both SCLC polyurethanes. Polarized optical microscopic investigations further confirmed the thermotropic liquid‐crystalline behaviors and nematic mesophases of both samples. Thermogravimetric analysis displayed better thermal stabilities for both SCLC polymers and indicated that the presence of mesogenic side chains may increase the thermal stability of segmented polyurethanes. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 290–302, 2004  相似文献   
28.
The melt mixing technique was used to prepare various polypropylene (PP)‐based (nano)composites. Two commercial organoclays (denoted 20A and 30B) served as the fillers for the PP matrix, and two different maleated (so‐called) compatibilizers (denoted PP‐MA and SMA) were employed as the third component. The results from X‐ray diffraction (XRD) and transmission electron microscope (TEM) experiments revealed that 190 °C was an adequate temperature for preparing the nanocomposites. Nanocomposites were achieved only if specific pairs of organoclay and compatibilizer were simultaneously incorporated in the PP matrix. For example, PP/20A(5 wt %)/PP‐MA(10 wt %) and PP/30B(5 wt %)/SMA(5 wt %) composites exhibited nanoscaled dispersion of 20A or 30B in the PP matrix. Differential scanning calorimetry (DSC) results indicated that the organoclays served as nucleation agents for the PP matrix. Generally, their nucleation effectiveness increased with the addition of compatibilizers. The thermal stability enhancement of PP after adding 20A was confirmed with thermogravimetric analysis (TGA). The enhancement became more evident as a suitable compatibilizer was further added. However, for the 30B‐included composites, thermal stability enhancement was not evident. The dynamic mechanical properties (i.e., storage modulus and loss modulus) of PP increased as the nanocomposites were formed; the properties increment corresponded to the organoclay dispersion status in the matrix. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4139–4150, 2004  相似文献   
29.
用He_Ne激光对掺有偶氮苯聚合物DR 13的PMMA薄膜样品进行Z扫描研究 ,发现其折射率改变量与光强的关系存在着饱和效应 ,且线偏振光引起的折射率改变明显大于圆偏振光引起的折射率改变 .对于这些现象 ,用光致异构的角烧孔机理进行解释  相似文献   
30.
潘佰良  毛邦宁  陈钢  方本民  姚志欣 《物理学报》2004,53(11):3748-3751
对用Blumlein电路放电激励的钡蒸气激光在掺氢和不掺氢时的输出特性进行了实验研究.结果表明,用掺氢1.5%的氖气作缓冲气体能使激光功率增加近2倍.在此基础上,进一步比较了相互作用电路与Blumlein电路时钡蒸气激光的输出特性,发现相互作用电路能显著提高钡蒸气激光的输出功率和效率,获得了3W最大功率和0.4%效率的1.5μm波长激光输出.测量并分析了各工作参量与激光功率之间的关系,定性解释了掺氢与相互作用电路的作用机理 . 关键词: Blumlein电路 相互作用电路 掺氢 钡蒸气激光  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号