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71.
Molecular structure of tris(acetylacetonato)scandium, Sc(C5H7O2)3, is investigated by gas-phase electron diffractometry. The main structural parameters of the molecule are evaluated. The
average internuclear distances and angles correspond to C3 symmetry. The chief structural motif is trigonal antiprisms of six oxygen, carbon, and hydrogen atoms with a scandium atom
at the center. It is found that rg(Sc-O) = 204.1(8) pm and rg(C-O) = 124.7(4) pm.
Translated fromZhumal Strukturnoi Khimii, Vol. 39, No. 4, pp. 633–639, July–August, 1998. 相似文献
72.
A. M. Dubrovkin A. A. Ezhov S. A. Magnitskii D. V. Malakhov N. M. Nagorskii V. I. Panov S. V. Savinov 《JETP Letters》2009,88(9):564-568
The observation of spiral spatial structures of light formed by an unmetallized nanoobject is reported. It is shown experimentally that a single polymer nanocylinder is capable of forming single and double spirals in two-dimensional cross sections of the spatial intensity distribution of cw laser radiation in the space above the nanocylinder top. 相似文献
73.
Earlier unknown 1,3-bisketene organoelement derivatives RMeE(C(E ’Me3)=C=O)2 (E = Si, Ge; E’ = Si, Ge, Sn) have been synthesized by the reaction of bis(alkoxyethynyl)silanes and -germanes with Me3E’Hal. Bis(1-trimethylsilyl-2-oxovinyl)silane is also formed by the reaction of trimethylsilyl- and (dimethylsilylene)bisketenes
with dimethylsilylene bistriflate and trimethylsilyl triflate, respectively. Addition of nucleophiles to the ketene fragment
of compounds synthesized has been studied. 相似文献
74.
It is shown how one can transform scalar first-order ordinarydifferential equations which admit non-local symmetries of theexponential type to integrable equations admitting canonicalexponential non-local symmetries. As examples we invoke theAbel equation of the second kind, the Riccati equation and naturalgeneralizations of these. Moreover, our method describes howa double reduction of order for a second-order ordinary differentialequation which admits a two-dimensional Lie algebra of generatorsof point symmetries can be affected if the second-order equationis first reduced in order once by a symmetry which does notspan an ideal of the two-dimensional Lie algebra. 相似文献
75.
K. A. Zhdanova A. P. Zhdanov A. V. Ezhov N. A. Bragina K. Yu. Zhizhin I. P. Ushakova A. F. Mironov N. T. Kuznetsov 《Russian Chemical Bulletin》2014,63(1):194-200
Amphiphilic meso-aryl-substituted porphyrins containing an amino group and long-chain hydrophobic substituents were synthesized. Two strategies of the synthesis of asymmetric amino-containing porphyrins using p-acetamidobenzaldehyde and p-nitrobenzaldehyde were developed and investigated. A series of new substituted porphyrin-containing closo-decaborates were prepared based on the synthesized porphyrins and nitrilium derivatives of the closo-decaborate anion [B10H10]2?. 相似文献
76.
Catalyst precursors containing 1% Au were synthesized by the impregnation of Al2O3 and CeO2-Al2O3 supports with an aqueous solution of HAuCl4 followed by drying, treatment with aqueous ammonia for the removal of chlorine residues, and final drying at 90°C. The oxidation of CO in gas containing ~1 vol % O2, ~1 vol % CO, 60 vol % H2, and the balance N2 on the activated catalysts was studied. In a number of experiments, to 18 vol % water was added to the gas mixture. The activation of precursors by the initial gas was studied. It was found that the prolonged storage of a precursor in air made its activation difficult to perform. The 1%Au/Al2O3 catalyst activated by the gas mixture stably operated in the preferential oxidation of CO at room temperature with the occurrence of the reaction in the mode of catalyst surface ignition (a hot spot at the bed inlet) under a change in the feed gas flow rate by a factor of 3. The effect of the presence of additional CO2 (to 39 vol %) on the oxidation of H2 was studied: the catalyst activity decreased. Because the reaction of CO2 reduction to CO did not occur, the effect can be due to the adsorption of CO2 on gold. The effect of the addition of water vapor to the feed gas was studied with the use of 1%Au/CeO2-Al2O3 as an example. The exo/endo effects related to the adsorption/desorption of water on the catalyst surface were detected upon steam supply and shutoff at a bed temperature of 100–150°C. It was noted that the addition of water vapor to a certain level favorably affected the selectivity (decreased the residual concentration of CO). The boundary water concentration, at which the effect became negative, depended on catalyst bed temperature. The higher was the bed temperature, the greater amount of water could be added until the manifestation of a negative effect. 相似文献
77.
78.
We find the distribution of the maximum of the difference of two renewal processes with discrete time that is semicontinuous
in discrete topology.
Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 50, No. 10, pp. 1426–1432, October, 1998. 相似文献
79.
80.
Ezhov I. S. Nazarov D. V. Vishnyakov P. S. Koshtyal Yu. M. Rumyantsev A. M. Kumar Rajesh Popovich A. A. Maksimov M. Yu. 《Russian Journal of Applied Chemistry》2022,95(3):352-356
Russian Journal of Applied Chemistry - The deposition of Ni–Mn–O thin films by molecular layering with equivalent feeding of organometallic reactants was studied.... 相似文献