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81.
M. C. Lpez Gallego-Preciado P. Ballesteros R. M. ClaramuntM. Cano J. V. Heras E. PinillaA. Monge 《Journal of organometallic chemistry》1993,450(1-2):237-244
The syntheses of a new tripodal ligand bis(indazol-1-yl)pyridin-2′-ylmethane (BIPM) and of a cationic complex (Rh(BIPM)(NBD)]PF6, (NBD = 2,5-norbornadiene) are reported. Both compounds were characterized by infrared, 1H, and 13C NMR spectroscopy and by single crystal X-ray analysis. BIPM crystallizes in the monoclinic system in space group P21/n with an β helical conformation. The [Rh(BIPM)(NBD)]PF6 complex crystallizes in the monoclinic space group C/2c, the rhodium atom being pentacoordinate with a distorted trigonal bipyramidal geometry. 相似文献
82.
Andrade Breno Henrique da Silva Caluête Rafael Evaristo de Oliveira Danniel Ferreira Gomes Rodinei Medeiros Melo Tadeu Antônio de Azevedo 《Journal of Thermal Analysis and Calorimetry》2020,139(2):905-911
Journal of Thermal Analysis and Calorimetry - Cu–Al–Be polycrystalline SMAs modified with the addition of inoculants show improved ductility, which accredits them for technological... 相似文献
83.
Vicente Compañ L. F. Del Castillo S. I. Hernández M. Mar López‐González Evaristo Riande 《Journal of Polymer Science.Polymer Physics》2007,45(14):1798-1807
This article describes the solubility of carbon dioxide, ethylene and propane in 1‐octene based polyethylene of 0.94, 0.92, 0.904, and 0.87 densities. The isotherms obtained in the gas sorption experimental device display a sorption behavior similar to that of glassy polymers. We apply the dual model to semicrystalline polymers assuming that Henry's sites are related to the amorphous phase, which decreases when the crystallinity percentage increases, whereas the surface of the crystalline phase acts as a Langmuir site with higher gas‐polymer affinity than glassy polymers. The good concordance of the calculated kD values, using the Flory‐Huggins theory of polymer diluent mixtures, with the experimental results suggest that Henry's gas sorption fulfills this theory and, therefore, it may be a suitable way to estimate polymer‐gas enthalpic interactions. Particularly, the variation of kD with the crystallinity fraction is exponential and the proportionality of the total sorption with the amorphous content seems only apparent. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1798–1807, 2007 相似文献
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Ronen Kreizman Sung You Hong Jeremy Sloan Dr. Ronit Popovitz‐Biro Dr. Ana Albu‐Yaron Dr. Gerard Tobias Dr. Belén Ballesteros Dr. Benjamin G. Davis Prof. Malcolm L. H. Green Prof. Reshef Tenne Prof. 《Angewandte Chemie (International ed. in English)》2009,48(7):1230-1233
Multiwall WS 2 nanotube templates were used as hosts to prepare core–shell PbI2@WS2 nanotubes by a capillary‐wetting method. Conformal growth of PbI2 layers on the inner wall of the relatively wide WS2 nanotubes (i.d. ca. 10 nm) leads to nanotubular structures which were not previously observed in narrow carbon nanotube templates. Image simulation after structural modeling (see picture) showed good agreement with the experimental HRTEM image.
88.
Chadlaoui M Abarca B Ballesteros R Arellano CR Aguilar J Aucejo R García-España E 《The Journal of organic chemistry》2006,71(24):9030-9034
The characteristics as a chemosensor of the compound 3-methyl-6,8-di(2-pyridyl)-[1,2,3]triazolo[5',1':6,1]pyrido[2,3-]pyrimidine (1) have been analyzed. Interaction with Cu(2+) produces a quenching of the fluorescence, while interaction with Zn(2+) leads to a quenching of the fluorescence followed by a bathochromic shift. The crystal structure of the Zn(1)(H(2)O)(3)(ClO(4))(2) x H(2)O complex shows the coordination of Zn(2+) through the terpyridine moiety. The octahedral site is completed by three water molecules. Interactions of the Zn(2+) complex with the anions sulfate, nitrate, nitrite, and dihydrogenphosphate in ethanol produce hypsochromic shifts and restoration of the fluorescence whose magnitude depends on the anion involved. The maximum interaction is observed for H(2)PO(4)(-). Interactions of the Zn(2+) complex with the amino acids l-aspartate and l-glutamate have also been explored showing a higher interaction with l-aspartate. 相似文献
89.
We report the synthesis of two novel Gd(III)-complexes derived from linear and macrocyclic polyaminopolycarboxylic acids 1 and 2, which contain a 3,5- dimethylpyrazolyl-ethyl arm, and a study of their relaxivity properties. The relationships between the experimental and theoretical results have provided interesting information about the kinetic and thermodynamic stability of these complexes. 相似文献
90.
Bartelmess J Ballesteros B de la Torre G Kiessling D Campidelli S Prato M Torres T Guldi DM 《Journal of the American Chemical Society》2010,132(45):16202-16211
In the present work, a new family of pyrene (Py)-substituted phthalocyanines (Pcs), i.e., ZnPc-Py and H(2)Pc-Py, were designed, synthesized, and probed in light of their spectroscopic properties as well as their interactions with single-wall carbon nanotubes (SWNTs). The pyrene units provide the means for non-covalent functionalization of SWNTs via π-π interactions. Such a versatile approach ensures that the electronic properties of SWNTs are not impacted by the chemical modification of the carbon skeleton. The characterization of ZnPc-Py/SWNT and H(2)Pc-Py/SWNT has been performed in suspension and in thin films by means of different spectroscopic and photoelectrochemical techniques. Transient absorption experiments reveal photoinduced electron transfer between the photoactive components. ZnPc-Py/SWNT and H(2)Pc-Py/SWNT have been integrated into photoactive electrodes, revealing stable and reproducible photocurrents with monochromatic internal photoconversion efficiency values for H(2)Pc-Py/SWNT as large as 15 and 23% without and with an applied bias of +0.1 V. 相似文献