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101.
Tong Su Yafei Wang Yi Liu William G. Branton Eugene Asahchop Christopher Power Bei Jiang Linglong Kong Niansheng Tang 《Entropy (Basel, Switzerland)》2020,22(11)
Distance weighted discrimination (DWD) is an appealing classification method that is capable of overcoming data piling problems in high-dimensional settings. Especially when various sparsity structures are assumed in these settings, variable selection in multicategory classification poses great challenges. In this paper, we propose a multicategory generalized DWD (MgDWD) method that maintains intrinsic variable group structures during selection using a sparse group lasso penalty. Theoretically, we derive minimizer uniqueness for the penalized MgDWD loss function and consistency properties for the proposed classifier. We further develop an efficient algorithm based on the proximal operator to solve the optimization problem. The performance of MgDWD is evaluated using finite sample simulations and miRNA data from an HIV study. 相似文献
102.
103.
S. N. Nikolaev V. S. Krivobok E. T. Davletov V. S. Bagaev E. E. Onishchenko A. V. Novikov M. V. Shaleev 《Journal of Russian Laser Research》2018,39(1):83-89
We realize for the first time an experimental investigation of the IR and visible luminescence of SiGe/Si heterostructures with quantum well subjected to an external anisotropic deformation. We show that tensile strain along the [100] direction enhances the absolute and relative intensities of visible luminescence by a factor of 7/3 at a temperature of 5 K. This effect is absent for a tensile strain along the [110] direction. We explain the phenomenon observed in view of the model of single-photon biexciton recombination for the system in which the bottom of the conduction band is formed by only two opposite electronic valleys. 相似文献
104.
P. G. Volkov S. I. Korobeinikov V. I. Nikolaev V. B. Sovkov 《Journal of Analytical Chemistry》2016,71(5):471-475
Possibilities of the experimental measurement and theoretical modeling of a fluorescence spectrum of a solid-anode X-ray tube are studied. A setup for the direct measurement of spectra of X-ray tubes of different types is created, spectra of a commercial BKh15 Svetlana X-ray tube are measured in wide range of anode voltages and currents. Calculations of spectra using the Ebel algorithm (Horst Ebel, 2006) with the parameters recommended in the original work ensure the satisfactory quality of the reproduction of the measured spectra, but demonstrate some statistically noticeable deviations. The optimization of model parameters ensures the improvement of the quality of simulation. 相似文献
105.
V. V. Ragulin M. E. Bofanova Eugene N. Tsvetkov 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4):237-241
Abstract The communication is concerned with the synthesis of phosphonic aminocarboxylic acids by phosphorylation of diethyl ω-halogen alkyl acetamidomalonates with tris(trimethylsilyl) phosphite, followed by alcoholysis and acid hydrolysis of the resulting intermediate esters. 相似文献
106.
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108.
S. N. Nikolaev V. S. Krivobok V. S. Bagaev E. E. Onishchenko 《Bulletin of the Lebedev Physics Institute》2017,44(12):371-373
The possibility of increasing the photoluminescence signal of Si1?xGex/Si quantum wells in the visible spectral range due to a change in the conduction band structure and the interaction of many-body states with plasma oscillations of metal nanoparticles is studied. The sample band structure was controlled using a uniaxial strain of ~10?4. It is found that such an approach allows an increase in the emission intensity of biexcitons in the quantum well (x = 9%) by a factor of 2.4 at a temperature of 5 K. Metal nanoparticles deposited on the sample surface with a protective layer thickness of 20 nm allowed us to increase the luminescence intensity of quantum wells approximately by a factor of 2.7. 相似文献
109.
Yu. I. Kostyukevich A. S. Kononikhin I. A. Popov A. E. Bugrova N. L. Starodubtseva E. N. Nikolaev 《High Energy Chemistry》2016,50(6):427-432
At present, the secondary structure of oligonucleotide ions in a gas phase is almost not understood. One of the main points is the retention of a hairpin secondary structure during ionization. In this work, we used a deuterium–hydrogen exchange reaction in a gas phase at atmospheric pressure for studying the conformational dynamics of oligonucleotide ions formed as a result of electrospray ionization. The exchange reactions of two oligonucleotides, which consisted of the identical sets of nucleotides but differed in their sequence, have been studied. One of these oligonucleotides formed a hairpin secondary structure, but the other did not. It has been found that both of the oligonucleotides demonstrate similar reaction dynamics of deuterium/hydrogen exchange in the gas phase; thereby indicating that the secondary structure has been completely destroyed during ionization. 相似文献
110.
In articles by Kokalas et al.1,2 studies were made of the interaction of FeCl3 with diisopropyl methylphosphonate (DIMP), diethyl ethylphosphonate (DEEP), and dimethyl methyl phosphonate (DMMP) and structures were proposed for the reaction products. When the reactions are run under much milder conditions, there is much evidence3–5 to support a different mechanism than that proposed by Kokalas and an altogether different structure of the complexes formed. In the structures proposed by Kokalas et al. the iron atom is surrounded by six oxygen atoms and these are the only bonding atoms to the iron. But on the other hand, in donor-acceptor complexes as are formed in chemisorption reactions,3–5 some of these sites are filled by chloride ions and this difference should be ascertained quite easily by far-infrared spectroscopy. It was the purpose of this study to look at the far-infrared data and either further substantiate the structures proposed or to propose new ones. 相似文献