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The technique of ferromagnetic resonance at 23 GHz has been used to determine the first three anisotropy constants of pure Ni down to 4.2K. A temperature and orientation dependent linewidth has also been observed. 相似文献
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P. Imhoff R. Van Asselt C. J. Elsevier K. Vrieze K. Goubitz K. F. Van Malssen 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4):401-415
Abstract The synthesis of novel bis(N-aryl-imino-phosphoranyl)methanes of the type CH2(PR2?N-Ar)2 has been accomplished by reaction of methylene-bisphosphines with arylazides. These compounds have been fully characterized by 1H, 31P and 13C NMR, IR spectroscopy, Field Desorption Mass Spectroscopy (? FDMS) and elemental analysis. Variable temperature NMR experiments and single crystal X-ray structure determinations of CH2(PPh2?N-C6H4-CH3-4)2 (la) and CH2(PMe2?N-C6H4-NO2-4)2 (1f) reveal that bis(N-aryl-imino-phosphorany1)methane occurs as tautomer 1. Crystals of la are orthorhombic, space group Pcab, with a = 26.602(2), b = 20.521(1), c = 11.8859(7) Å and V = 6488.5(7) Å3 (2 = 8, R = 0.045 and Rw = 0.066). The crystals of lf are monoclinic, space group C/2c, with a = 20.153(4), b = 5.952(1), c = 16.930(5) Å, β = 106.24(3)° and V = 1949.6(6) Å3 (Z = 4, molecular symmetry C2, Rw = 0.051 and R, = 0.079). Both molecules consist of 2 iminophosphoranyl units bridged by a methylene group. The P?N bond distances of 1.568(2) and 1.566(2) Å for la and 1.580(4) Å for lf represent normal values for iminophosphoranyl compounds. The N-C bond lengths of 1.386(2) and 1.390(2) A (la) or 1.372(5) A for If indicate that some electron delocalisation over the N-aryl moiety takes place. In la the electron delocalisation takes place separately in each iminophosphoranyl entity, while in lf electron delocalisation occurs only in the N-aryl-NO2 moiety. Compound la is easily deprotonated using lithium-diisopropylamide or NaH and shows typical iminophosphoranyl chemistry, since with CO2 an aza-Wittig reaction has been found and with HX (X?CI, Br) protonation of both imide nitrogen atoms has been observed. 相似文献
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Dr. Matthew P. Conley Ruben M. Drost Dr. Mathieu Baffert Dr. David Gajan Prof. Dr. Cornelis Elsevier Dr. W. Trent Franks Prof. Dr. Hartmut Oschkinat Laurent Veyre Alexandre Zagdoun Dr. Aaron Rossini Dr. Moreno Lelli Dr. Anne Lesage Dr. Gilles Casano Dr. Olivier Ouari Prof. Dr. Paul Tordo Prof. Dr. Lyndon Emsley Prof. Dr. Christophe Copéret Dr. Chloé Thieuleux 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(37):12234-12238
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