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91.
Pedro de Vries Kristel Michielsen Hans De Raedt 《Zeitschrift für Physik B Condensed Matter》1994,95(4):475-479
It is shown that the single-particle self-energy of the one and two-dimensional simplified Hubbard model exhibits different behavior characterized by Fermi-liquid, non-Fermi-liquid quasiparticle, or non-quasiparticle excitations, as a function of the strength of the on-site Coulomb repulsionU, temperature, and electron filling. For half-filled lattices, results for the optical conductivity indicate that the d.c. conductivity is zero for all temperatures andU>0. 相似文献
92.
93.
94.
Vajiheh Neshati Samaneh Mollazadeh Bibi Sedigheh Fazly Bazzaz Antoine A. F. de Vries Majid Mojarrad Hojjat Naderi-Meshkin Zeinab Neshati Mahdi Mirahmadi Mohammad Amin Kerachian 《Applied biochemistry and biotechnology》2018,186(1):245-255
Since the adult mammalian heart has limited regenerative capacity, cardiac trauma, disease, and aging cause permanent loss of contractile tissue. This has fueled the development of stem cell-based strategies to provide the damaged heart with new cardiomyocytes. Bone marrow-derived mesenchymal stem cells (BM-MSCs) are capable of self-renewal and differentiation into cardiomyocytes, albeit inefficiently. MicroRNAs (miRNAs, miRs) are non-coding RNAs that have the potential to control stem cell fate decisions and are employed in cardiac regeneration and repair. In this study, we tested the hypothesis that overexpression of miR-499a induces cardiomyogenic differentiation in BM-MSCs. Human BM-MSCs (hBM-MSCs) were transduced with lentiviral vectors encoding miR-499a-3p or miR-499a-5p and analyzed by immunostaining and western blotting methods 14 days post-transduction. MiR-499a-5p-transduced cells adopted a polygonal/rod-shaped (myocyte-like) phenotype and showed an increase in the expression of the cardiomyocyte markers α-actinin and cTnI, as cardiogenic differentiation markers. These results indicate that miR-499a-5p overexpression promotes the cardiomyogenic differentiation of hBM-MSCs and may thereby increase their therapeutic efficiency in cardiac regeneration. 相似文献
95.
Andreas de Vries 《Mathematische Nachrichten》1996,179(1):27-45
The covariant Weyl (spin s = 1/2) and Maxwell (s = 1) equations in certain local charts (u, φ) of a space-time (M, g) are considered. It is shown that the condition g00(x) > 0 for all x ε u is necessary and sufficient to rewrite them in a unified manner as evolution equations δtφ = L(s)φ. Here L(s) is a linear first order differential operator on the pre—Hilbert space (C (Ut, 2s+1). (…)), where Ut ? IR3 is the image of the coordinate map of the spacelike hyper-surface t = const, and (φ, C) = ?Ut ? *Q d(3)x with a suitable Hermitian n × n- matrix Q = Q(t,x). The total energy of the spinor field ? with respect to Ut is then simply given by E = 〈?,?〉. In this way inequalities for the energy change rate with respect to time, δt|?|2 = 2Re (?, L(s)?) are obtained. As an application, the Kerr—Newman black hole is studied, yielding quantitative estimates for the energy change rate. These estimates especially confirm the energy conservation of the Weyl field and the well—known superradiance of electromagnetic waves. 相似文献
96.
Bruins EE Bauer TS den Bok HW Duif CP van Hoek WC de Lange DJ Misiejuk A Papandreou Z Sichtermann EP Tjon JA Willering HW Yeomans DM Reike H Durek D Frommberger F Gothe R Jakob D Kranefeld G Kunz C Leiendecker N Pfeiffer G Putsch H Reichelt T Schoch B Wacker D Wehrmeister D Wilhelm M Jans E Konijn J de Vries R Furget C Voutier E Arenhövel H 《Physical review letters》1995,75(1):21-24
97.
Photofragmentation spectroscopy offers a possibility to determine the dissociation energy of diatomic molecules with an accuracy of about 0.01 eV, which is half an order of magnitude better than any other applicable method. In this letter the method will be compared with other known techniques and results will be given for NaBr, KBr, NaI ad KI. 相似文献
98.
Anna S. Bondarenko Ilias Patmanidis Riccardo Alessandri Paulo C. T. Souza Thomas L. C. Jansen Alex H. de Vries Siewert J. Marrink Jasper Knoester 《Chemical science》2020,11(42):11514
Supramolecular aggregates of synthetic dye molecules offer great perspectives to prepare biomimetic functional materials for light-harvesting and energy transport. The design is complicated by the fact that structure–property relationships are hard to establish, because the molecular packing results from a delicate balance of interactions and the excitonic properties that dictate the optics and excited state dynamics, in turn sensitively depend on this packing. Here we show how an iterative multiscale approach combining molecular dynamics and quantum mechanical exciton modeling can be used to obtain accurate insight into the packing of thousands of cyanine dye molecules in a complex double-walled tubular aggregate in close interaction with its solvent environment. Our approach allows us to answer open questions not only on the structure of these prototypical aggregates, but also about their molecular-scale structural and energetic heterogeneity, as well as on the microscopic origin of their photophysical properties. This opens the route to accurate predictions of energy transport and other functional properties.Multiscale modeling resolves the molecular structure of a synthetic light-harvesting complex, unraveling the microscopic origin of its photophysical properties.Supramolecular structures may self-assemble from a variety of building blocks, resulting in a wide range of advanced materials with attractive biomimetic, sensing, catalytic, optoelectronic and photonic functionalities.1–10 The close-packed nanoscale organization of the individual molecules within a supramolecular system, held together via noncovalent interactions, gives rise to the aggregate''s (collective) properties. Assemblies consisting of dye molecules often exhibit unique collective optical properties and are of interest for opto-electronic applications as well as artificial light-harvesting complexes that mimic natural antenna systems of photosynthetic bacteria and plants.11–13 For example, chlorosomal antenna complexes of photosynthetic green sulfur bacteria are self-assembled into multilayer tubular structures having bacteriochlorophyll pigments as building blocks.14–16 The structure of these antenna complexes and the underlying molecular arrangement ensures that the process of light-harvesting and excitation energy transport is very efficient, even under extremely low light conditions.17,18 The quest to recreate such efficiency under laboratory conditions has sparked numerous studies of synthetic self-assembled systems mimicking natural chlorosomes, e.g. using porphyrins,19 zinc chlorin,20 and cyanine dyes.21 Of particular interest are the tubular aggregates of 3,3′-bis(2-sulfopropyl)-5,5′,6,6′-tetrachloro-1,1′-dioctylbenzimidacarbocyanine (C8S3).22–25 Cryo-TEM reveals a hierarchy of supramolecular architectures, including double-walled nanotubes; under certain conditions, bundles of nanotubes arise.26 Thus, this system allows for the occurrence of electronic excitation energy transport at various levels: within one wall, between walls of one tube, and between different tubes, similar to the situation in natural systems.27,28To understand how such supramolecular systems work, as well as propose design rules for new materials, it is essential to determine the relationship between molecular structure and optical properties. Current experimental techniques, however, are unable to resolve the structure at the molecular level. This, in combination with the sensitivity of spectral properties to the details of the molecular packing, leads to a crucial role for theoretical modeling.29 For example, molecular dynamics (MD) simulations have been used to predict the molecular packing within a variety of supramolecular assemblies.30–34 However, synthetic amphiphiles with aromatic groups, such as cyanine dyes—often used to prepare aggregates with optical functionality—tend to fall into kinetic traps during spontaneous self-assembly simulations and the packing of the aromatic chromophores remains highly disordered on the accessible time scale, leading to predicted (optical) spectra that are not consistent with experimental data.35 This problem can be overcome by building assemblies based upon proposed architectures and assessing their stability in relatively short MD simulations.36–38 The drawback of this approach is the requirement of a thorough understanding of what to use as a starting point and how to validate the structure. In any case, proper validation requires the modeling of the optical spectra of the obtained structure, and finally, comparing it to the experiment. The demanding character of such methods explains why an important role is played by phenomenological modeling, in which a molecular packing is guessed and the optics is obtained from parametrizing an exciton model that describes the collective excited states of the assembly with interactions dictated by the guessed packing. By comparing the calculated spectra to experimental ones, the structure and exciton model may be fine-tuned. While this method has been successful in describing spectra,23,39 it is limited in its predictive power and also lacks access to essential microscopic parameters, such as tuning of the optical excitation energies imposed by the environment, disorder in these energies and structural heterogeneity.In this work, we use an advanced multiscale approach to determine structure–optical property relationships for the C8S3 double-walled nanotubes, guided by comparison to experiments. The optical spectrum of these aggregates, in which multiple exciton peaks may be discerned, suggests a rather complex underlying molecular packing. This fact, combined with their sheer size going up to many thousands of molecules, makes these systems exceptionally challenging to resolve and leaves important questions concerning structure–function relationships unanswered or under debate, for instance the origin of the splitting between the two lowest-energy spectral bands.23,38 Here, we answer these questions by iteratively combining MD simulations to capture the details of molecular packing and structural disorder, an exciton Hamiltonian approach to calculate optical signatures, and explicit microelectrostatic calculations to estimate energetic disorder and solvent shifts. Previous attempts to reveal the structure of cyanine-based nanotubes were limited to small-scale system sizes,37,38 modeling optical features phenomenologically rather than using atomistic information38 or featuring simpler, single-walled systems.37 In addition to answering important questions for the C8S3 double-walled nanotubes, our study opens the way to explain and predict at an unprecedented level of detail the functional properties of other highly complex molecular materials. 相似文献
99.
100.
Orientational effects in collisions between a diatomic molecule and a noble gas atom are studied by classical trajectory calculations. A preferable ”perpendicular orientation“ of the molecule is found at the moment of closest approach of the atom. This orientational effect is more pronounced in collisions with heavy atoms. 相似文献