Heat conduction in laminates with a weak transversal inhomogeneity

The purpose of this contribution is to formulate a tolerance model, [1], for periodically laminated media with a weak transversal inhomogeneity. Laminates in which layers are of the same material but one of them is reinforced by thin fibers in parallel to the interfaces are this kind of media. Taking into account the weak transversal inhomogeneity makes possible to separate model equations for the averaged temperature and temperature fluctuations. To analyse and solve these equations we apply asymptotic expansions. Using the proposed model selected initial-boundary value problems were solved. Results were verified by direct numerical solutions obtained in the framework of the Fourier model. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

On the influence of buoyancy on the surface tension driven flow around a bubble on a heated wall

The surface tension driven flow in the liquid vicinity of gas bubbles on a heated solid wall has been investigated both, in a reduced gravity environment aboard a sounding rocket, and in an earth-bound experiment. Both experiments deal with temperature gradients within the liquid surrounding of a bubble which cause variations of the surface tension. These, in turn, lead to a liquid flow around the bubble periphery termed thermocapillary or thermal Marangoni-convection. On Earth, this phenomenon is widely masked by buoyancy. We therefore carried out an experiment under reduced gravitational acceleration. In order to simultaneously observe and record the flow field and the temperature field liquid crystal tracers have been applied. These particles offer the feature of selectively reflecting certain wavelengths of incident white light depending on the crystals temperature. Although the bubble injection system did not perform nominally during the flight experiment, some interesting flow characteristics could be observed. Comparison of results obtained in microgravity to data measured on Earth reveal that due to the interaction of thermocapillarity and buoyancy a very compact vortex flow results on ground, while in microgravity the influence on the surface tension driven flow penetrates much deeper into the bulk. This result is of special interest regarding the production of materials in space. Dedicated to Professor Dr. Julius Siekmann on the occasion of his 70th birthday The work described herein was supported by the German space agency DARA (Deutsche Agentur für Raumfahrtangelegenheiten GmbH) through DARA Grant 50 WM 9434. The authors thank the European Space Agency (ESA) for the opportunity to conduct the TEXUS 33 sounding rocket experiment. The flight hardware has been partly built by Daimler-Benz-Aerospace which is gratefully acknowledged. Also, the authors are indebted to Mr. H.-H. Wolf for his careful evaluation of the particle images     

Deuterium liner and multiparametric studies of the formation of an inverse Z-pinch

A method and results of measurements are presented of the ion energy distribution in a deuterium liner accelerated in the inverse Z-pinch, in which the plasma is accelerated electrodynamically from the liner axis. Knowledge of the deuteron energy distribution is of primary importance for the correct interpretation of the experimental results from the study of the dd-reaction in the range of infralow energies with the use of a liner plasma. Experiments were carried out in a high-current pulsed accelerator (I=950 kA, τ=80 ns) at the Institute of High-Current Electronics of the Siberian Division of the Russian Academy of Sciences (Tomsk, Russia). In the initial state, the liner is a supersonic hollow deuterium jet 32 mm in diameter and 20 mm in length. The liner parameters were measured with the help of optical detectors of H _α and H _β deuterium lines and magnetic probes arranged in a radial direction (along the direction the liner expansion). In addition, scintillation spectrometers and BF₃ counters were used to measure the intensity of the neutron flux produced in the d + d → ³He + n reaction. The results obtained by simultaneously analyzing the data from magnetic probes, optical detectors, and neutron detectors point to the possibility of using a rather simple method for measuring the parameters of the liner accelerated up to energies of 3–6 keV.     

An arbitrary correction function for CO(2) evolution in acid-base titrations and its use in multiparametric refinement of data

A great number of acid-base titrations are performed under an inert gas flow: in the procedure, a variable amount of CO(2)-from carbonated reactants-is carried away and thus prevents strict application of mass-balance equations. A function for the CO(2) evolution is proposed and introduced into the general expression for the volume of titrant. Use of this expression in multiparametric refinement yields, besides the usual values (concentrations, acidity constants...), a parameter characteristic of this departure of CO(2). Furthermore, a modified weighting factor is introduced to take into account the departure from equilibrium caused by the slow CO(2) evolution. The validity of these functions was successfully tested on three typical examples: neutralization of strong acid by sodium carbonate, of sodium carbonate by strong acid, and of a mixture of hydrochloric acid, 4-nitrophenol and phenol by carbonated potassium hydroxide.     

Multielemental Analysis of Bee Pollen,Propolis, and Royal Jelly Collected in West-Central Poland

Beehive products possess nutritional value and health-promoting properties and are recommended as so-called “superfoods”. However, because of their natural origin, they may contain relevant elemental contaminants. Therefore, to assess the quality of bee products, we examined concentrations of a broad range of 24 selected elements in propolis, bee pollen, and royal jelly. The quantitative analyses were performed with inductively coupled plasma-mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP-OES) techniques. The results of our research indicate that bee products contain essential macronutrients (i.e., K, P, and S) and micronutrients (i.e., Zn and Fe) in concentrations depending on the products’ type. However, the presence of toxic heavy metals makes it necessary to test the quality of bee products before using them as dietary supplements. Bearing in mind that bee products are highly heterogenous and, depending on the environmental factors, differ in their elemental content, it is necessary to develop standards regulating the acceptable levels of inorganic pollutants. Furthermore, since bees and their products are considered to be an effective biomonitoring tool, our results may reflect the environment’s condition in west-central Poland, affecting the health and well-being of both humans and bees.     

Chemical Composition,Antipathogenic and Cytotoxic Activity of the Essential Oil Extracted from Amorpha fruticosa Fruits

The purpose of this paper was to characterize and investigate the antimicrobial potential of Amorpha fruticosa fruits essential oil (EO). The EO was extracted by hydrodistillation, analyzed by GC-MS, and then evaluated for its interaction with microbial and mammalian cells. The antimicrobial activity was assessed against bacterial and fungal strains, in a planktonic and adherent growth state, using qualitative and quantitative assays. The main components identified in A. fruticosa fruits EO were δ-cadinene, γ-muurolene, and α-muurolene. The Gram-positive strains proved to be more susceptible than Gram-negative bacteria and fungal strains. The EO exhibited good antibiofilm activity, inhibiting the microbial adherence to the inert (96-well plates and Foley catheter section) and cellular substrata. The flow cytometry analysis revealed as one of the possible mechanisms of antimicrobial action the alteration of cell membrane hydrophobicity. The cytotoxicity on the L929 cell line occurred at concentrations higher than 0.3 mg/mL. Taken together, our results demonstrate that A. fruticosa fruits EO contains active compounds with selective inhibitory effect on different microbial strains in planktonic and biofilm growth state, explained at least partially by the interference with microbial membranes due to their hydrophobic character.