Multicommuted fluorometric multiparameter sensor for simultaneous determination of naproxen and salicylic acid in biological fluids.

A combined approach based on solid-phase optosensing and multicommutation principles has been applied to develop a method for the simultaneous analysis of two pharmaceuticals (naproxen and salicylic acid) in biological fluids. The multicommuted flow-through optosensor was based on direct native fluorescence measurements of both analgesics using a non-polar sorbent (C18 silica gel) as a solid sensing zone. The flow system was controlled by Java-written home-made software and designed using three-way solenoid valves for an independent automated manipulation of sample and carrier solutions. Using an optimized sampling time, the method was calibrated in the range of 1 - 25 and 5 - 200 ng mL(-1). The obtained detection limits were 0.3 and 1.3 ng mL(-1) for naproxen and salicylic acid, respectively, with RSD (%) values of better than 2% for both analytes. The proposed methodology was successfully applied to urine, serum and pharmaceutical preparations. Recovery percentages ranging from 96.1 to 104% were obtained for both analytes.     

Dynamic mechanical analysis

Using dynamic mechanical analysis (DMA) we have studied thermal degradation for a system containing a diglycidyl ether of bisphenol A (DGEBA) and 1,3-bisaminomethylcylohexane (1,3-BAC). The changes of dynamic mechanical properties during thermal degradation indicated a shift of the glass transition temperature (T _g) to higher temperatures and a decrease in the peak value of the dynamic loss factor (tan δ) with an increasing of aging time. The value of dynamic storage modulus (E′) at the rubbery state showed an increase with aging time, whiteE′ at the glassy state only underwent a moderate change with increased thermal degradation. From these results it can be argued that thermal degradation during the stage prior to the onset of the severe degradation involves structural changes in the epoxy system, as further crosslinking and loss of dangling chains in the crosslinked network.     

Nonlocal Effects in Two-Dimensional Conductivity

The paper deals with the asymptotic behaviour as ε → 0 of a two-dimensional conduction problem whose matrix-valued conductivity a _ε is ε-periodic and not uniformly bounded with respect to ε. We prove that only under the assumptions of equi-coerciveness and L ¹-boundedness of the sequence a _ε , the limit problem is a conduction problem of same nature. This new result points out a fundamental difference between the two-dimensional conductivity and the three-dimensional one. Indeed, under the same assumptions of periodicity, equi-coerciveness and L ¹-boundedness, it is known that the high-conductivity regions can induce nonlocal effects in three (or greater) dimensions.     

Use of new composite materials for the determination of Cu, Cd, Mo, As, and Sb in biological samples by radiochemical neutron activation analysis

Summary  Vezetéknév     

Study of a fiber-optic LAN with a distributed controller

In this paper the performance of a fiber-optic LAN with spread spectrum multiplexing is discussed from the viewpoint of transmission parameters. Two architectures are considered. The first concerns a structure with cascade-connected Y-type fiber-optic couplers. The second concerns an architecture with cascade-connected active optoelectronic repeater-coupler (ORCA) devices.     

SpecTool: a knowledge-based hypermedia system for interpreting molecular spectra

Summary A hypermedia environment was designed to set up a collection of reference data, reference spectra and computational tools. The system may serve as an aid for the combined interpretation of molecular spectra. This paper describes the context dependent presentation of the pieces of information.     

Local solution for the Kadomtsev-Petviashvili equation with periodic conditions

In this article we prove a local existence and uniqueness theorem for the Kadomtsev-Petviashvili Equation (u _t +u _xxx +uu _x ) _x −u _yy =0) in the Sobolev spaces of orders≥3, with initial values in the same spaces, and periodic boundary conditions. This theorem improves previous results based upon the application of singular perturbation techniques.     

Mössbauer spectroscopic study of Prussian Blue from different provenances

Ferric ferrocyanides synthesized from different sources of ferric cations and ferrocyanide anions and those derived from ferrous ferricyanide, ferrous ferrocyanide and ferric ferricyanide have been studied using Mössbauer and XRD techniques. Structural information of the effect of the provenance on the properties of the final compound is obtained. Significant correlations between isomer shift and quadrupole splitting of inner and outer iron cations have been observed.     

TDPAC study in ZnTiF6·6H2O between room temperature and 1273 K

Using the time differential perturbed angular correlation technique, the hyperfine interactions as titanium sites in ZnTiF6·6H₂O and its decomposition products were determined between room temperature (300 K) and 1273 K. The different steps in the decomposition pattern were identified and a simple model is given for it.