Einen Gang der Untersuchung zur Unterscheidung der wichtigeren Harze, Gummiharze und Balsame

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Geometrische Mittheilungen

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Zur allgemeinen Kolloidchemie

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Determination of low-level tritium concentrations in surface water and precipitation in the Czech Republic

Past tests of nuclear weapons in the atmosphere, nuclear energy facilities and tritium of natural origin are main sources of tritium in the environment. Thanks to its presence in environment and its favourable properties, tritium is used as a radiotracer. Since stopping of atmospheric nuclear tests, tritium in precipitation has been decreasing towards natural levels below 1 Bq l^?1 and precise analyses of low level tritium activities are necessary. This paper focuses on tritium development at sites not influenced by any technogenic release of tritium in Elbe River basin (Bohemia) in the Czech Republic using liquid scintillation measurement with electrolytic enrichment.     

Polycatenar liquid crystals based on bent-shaped chalcone and cyanopyridine molecules

In this study, the synthesis, structural characterisation and mesomorphic and optical properties of seven new bent-shaped and polycatenar bent-shaped compounds derived from chalcone and cyanopyridine are reported. The mesomorphic behaviour was investigated by differential scanning calorimetry (DSC), polarised optical microscopy (POM) and X-ray diffraction (XRD) and correlated with the molecular structure. Two bent-core hexacatenars molecules (Ic and IIc) presented liquid crystalline properties, showing a hexagonal columnar (Col_h) phases at room temperature, being each disc constituted by two mesogens. Optical studies were also performed for the final molecules, being conducted by ultraviolet-visible and fluorescence spectrometry. The cyanopyridine derivatives show moderate luminescence quantum yields, ranging between 18% and 27%, with emission maxima around 371 nm. It is also shown that while the chalcone central unit favours a calamitic liquid crystalline behaviour in molecules with lower number of aliphatic chains, a polycatenar structure with cyanopyridine as the central unit favours a Col_h arrangement, also providing luminescence properties to the molecule.     

Effective flow of a viscous liquid through a helical pipe

We study the flow of a viscous fluid through a pipe with helical shape parameterized with , where the small parameter stands for the distance between two coils of the helix. The pipe has small cross-section of size . Using the asymptotic analysis of the microscopic flow described by the Navier–Stokes system, with respect to the small parameter that tends to zero, we find the effective fluid flow described by an explicit formula of the Poisseuile type including a small distorsion due to the particular geometry of the pipe. To cite this article: E. Marušić-Paloka, I. Pažanin, C. R. Mecanique 332 (2004).

Résumé

On considère un écoulement dans un tube de section circulaire et de forme hélicoïdale paramétré par , où est la distance entre deux tours de la spirale. Le rayon de la section du tube est lui aussi supposé égal à . A partir de l'écoulement microscopique décrit par le système de Navier–Stokes et en utilisant l'analyse asymptotique par rapport à ce petit paramètre on obtient l'écoulemment effectif décrit par une formule explicite de type Poiseuille associée à une petite déviation due à la géometrie du tube. Pour citer cet article : E. Marušić-Paloka, I. Pažanin, C. R. Mecanique 332 (2004).     

Finite-dimensional asymptotic behavior of some semilinear damped hyperbolic problems

We prove that the solution semigroup $$S_t \left[ {u_0 ,v_0 } \right] = \left[ {u(t),u_t (t)} \right]$$ generated by the evolutionary problem $$\left\{ P \right\}\left\{ \begin{gathered} u_{tt} + g(u_t ) + Lu + f(u) = 0, t \geqslant 0 \hfill \\ u(0) = u_0 , u_t (0) = \upsilon _0 \hfill \\ \end{gathered} \right.$$ possesses a global attractorA in the energy spaceE _o=V×L ²(Ω). Moreover,A is contained in a finite-dimensional inertial setA attracting bounded subsets ofE ₁=D(L)×V exponentially with growing time.     

Cadmium(II) thio‐ and selenocyanate complexes of 3,3′‐bis(1,2,4‐triazol‐4‐yl)‐1,1′‐biadamantane,a ligand designed with an `extended nanodiamond' aliphatic platform

In the structures of the Cd^II pseudohalide coordination polymer poly[[diaquabis[μ₂‐3,3′‐bis(1,2,4‐triazol‐4‐yl)‐1,1′‐biadamantane‐κ²N¹:N^1′]cadmium(II)] dithiocyanate dihydrate], {[Cd(C₂₄H₃₂N₆)₂(H₂O)₂](NCS)₂·2H₂O}_n, (I), and the isomorphous selenocyanate analogue, {[Cd(C₂₄H₃₂N₆)₂(H₂O)₂](NCSe)₂·2H₂O}_n, (II), the Cd^II cations occupy inversion centres and have octahedral CdN₄O₂ environments, completed by four N atoms of the organic ligands [Cd—N = 2.316 (2) and 2.361 (2) Å for (I), and 2.313 (3) and 2.372 (3) Å for (II)] and two trans‐coordinated aqua ligands [Cd—O = 2.3189 (15) Å for (I) and 2.323 (2) Å for (II)]. In each compound, the ligand displays a bidentate N¹:N^1′‐bridging mode, connecting the metal centres at a distance of 14.66 Å into two‐dimensional nets of (4,4)‐topology, while the uncoordinated thio(seleno)cyanate anions reside inside the net cavities. Hydrogen bonding between the water molecules, anions and 1,2,4‐triazole N atoms supports the tight packing, with an interlayer distance of 6.09 Å.     

A new adamantanecarboxylate coordination polymer: poly[[(μ3‐adamantane‐1,3‐dicarboxylato)aquadioxidouranium(VI)] monohydrate]

The title compound, {[U(C₁₂H₁₄O₄)O₂(H₂O)]·H₂O}_n, is the first actinide complex featuring adamantanecarboxylate ligands. The metal ion possesses a pentagonal–bipyramidal UO₇ coordination involving two axial oxide ligands [U—O = 1.732 (5) and 1.764 (5) Å] and five equatorial O atoms [U—O = 2.259 (5)–2.494 (4) Å] of aqua and carboxylate ligands. The latter display pseudo‐chelating and bridging coordination modes of the carboxylate groups that are responsible for the generation of the centrosymmetric discrete uranium–carboxylate [UO₂(μ‐RCOO)₂UO₂] dimers [U...U = 5.5130 (5) Å] and their connection into one‐dimensional chains. Hydrogen bonding involving two coordinated and two solvent water molecules [O...O = 2.719 (7)–2.872 (7) Å] yields centrosymmetric (H₂O)₄ ensembles and provides noncovalent linkage between the coordination chains to generate a three‐dimensional network structure.