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51.
52.
Some scaling properties for a classical particle confined to bounce between two walls, where one wall is fixed and the other one moves in time according to a random signal with a memory length are studied. We have considered two different kinds of collisions of the particle with the moving wall namely: (i) elastic and (ii) inelastic. The dynamics of the model is described in terms of a two-dimensional nonlinear mapping. For the case of elastic collisions, we show that the memory of the stochastic signal affects directly the behaviour of the average velocity of the particle. It then exhibits different slopes for the average velocity at different stages of the series with β≅3/4 for a short time, β≅1 for the average stage and β≅1/2 for a long time, as predicted by the Central Limit Theorem, therefore leading to the Fermi acceleration. The situation where inelastic collisions are taken into account yields a more drastic change, particularly suppressing the Fermi acceleration. 相似文献
53.
Rafael Libanori Tania R. Giraldi Elson Longo Edson R. Leite Caue Ribeiro 《Journal of Sol-Gel Science and Technology》2009,49(1):95-100
Commercial TiO2 nanoparticles were superficially modified through polymeric resins obtained from polymerization of citrate complexes of Y3+ and Al3+ with ethylenglycol. The materials were treated at 450 °C for 4 h to obtain modified nanoparticles, which were characterized
by HR-TEM, Zeta potential and surface area through N2 fisisorption. Rhodamine B photodegradation by visible light irradiation and in presence of those modified nanoparticles was
compared with the same process in presence of unmodified commercial TiO2 nanoparticles. It was observed, by UV–visible spectroscopy, that the catalytic photoactivity in presence of modified nanoparticles
was smaller than that observed with commercial TiO2 nanoparticles. However, the surface modifier played an important role in the photodegradation kinetic process, showing a
non-linear relation between modifier amount and photodegradation rate, presenting a maximum value at 0.8% (w/w). 相似文献
54.
Eduardo Colli Marcio L. do Nascimento Edson Vargas 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2009,26(4):869
We study the growth of Dfn(f(c)) when f is a Fibonacci critical covering map of the circle with negative Schwarzian derivative, degree d2 and critical point c of order ℓ>1. As an application we prove that f exhibits exponential decay of geometry if and only if ℓ2, and in this case it has an absolutely continuous invariant probability measure, although not satisfying the so-called Collet–Eckmann condition. 相似文献
55.
Investigations of the catalytic properties of manganese oxides for the oxygen reduction reaction in alkaline media 总被引:2,自引:0,他引:2
Fabio H.B. Lima Marcelo L. Calegaro Edson A. Ticianelli 《Journal of Electroanalytical Chemistry》2006,590(2):152-160
The oxygen reduction reaction (ORR) was studied in KOH electrolyte on different manganese oxides, dispersed on a carbon powder (MnOx/C). The oxides were prepared by different methods, for producing MnO, Mn3O4 and MnO2 as major phases dispersed on the Vulcan XC-72 carbon. The oxides were characterized by XRD (X-ray diffraction) and in situ XANES (X-ray absorption near edge structure). The electrochemical measurements were made using cyclic voltammetry and steady state polarization curves carried out in an ultra-thin layer rotating ring/disk electrode. The results have shown lower activity for the ORR on the MnOx/C species compared to that on Pt/C, but higher activity compared to that of pure Vulcan carbon. Formation of involving 2e− per O2 molecule is the main path of the ORR in the studied MnOx/C catalysts but, at low overpotentials and rotation rates the number of electrons is raised to 4 due to the occurrence of a disproportionation reaction. Large differences of electrocatalytic activity were seen for the different oxide species, and these were related to the presence of a Mn(IV) phase and the occurrence of a mediation processes involving the reduction of Mn(IV) to Mn(III), followed by the electron transfer of Mn(III) to oxygen. 相似文献
56.
We studied the resistive state of a mesoscopic superconducting strip (bridge) at zero external applied magnetic field under a transport electric current, , subjected to different types of boundary conditions. The current is applied through a metallic contact (electrode) and the boundary conditions are simulated via the deGennes extrapolation length b. It will be shown that the characteristic current–voltage curve follows a scaling law for different values of b. We also show that the value of at which the first vortex–antivortex (V–Av) pair penetrates the sample, as well as their average velocities and dynamics, strongly depend on the b values. Our investigation was carried out by solving the two-dimensional generalized time dependent Ginzburg–Landau (GTDGL) equation. 相似文献
57.
The mechanical molecular degradation in drag reducing flows is a huge problem in the effort to improve the efficiency of drag reducers, which is clearly increased when a combination of materials is used. Here, we analyze mixtures of three kinds of water-soluble polymers: Poly (ethylene oxide) (PEO), Polyacrylamide (PAM), and Xanthan Gum (XG). Two kinds of mixtures are tested: (a) PAM and XG; (b) PEO and XG. The synergy between the polymers is clearly noticeable. The values of the drag reduction (DR) obtained by the polymer–polymer combination was larger than that observed for a single polymer in a solution with the same total concentration of the mixture. Our tests are conducted in straight tubes where the total pressure is fixed. The values of DR are computed step-by-step, as the total amount of solution pass through the system. In doing so, we carefully took into account the loss of efficiency caused by the turbulent flow in the straight tubes. It is quite clear that the degradation of the flexible polymers (PEO and PAM) is delayed in the mixtures. In other words, besides the increase in the DR, the flexible polymers are more resistant when in the presence of the rigid one (XG). Such observation is the main conclusion of this work. 相似文献
58.
Dynamical properties are studied for escaping particles, injected through a hole in an oval billiard. The dynamics is considered for both static and periodically moving boundaries. For the static boundary, two different decays for the recurrence time distribution were observed after exponential decay for short times: A changeover to: (i) power law or; (ii) stretched exponential. Both slower decays are due to sticky orbits trapped near KAM islands, with the stretched exponential apparently associated with a single group of large islands. For time dependent case, survival probability leads to the conclusion that sticky orbits are less evident compared with the static case. 相似文献
59.
Some dynamical properties for a classical particle confined in an infinitely deep box of potential containing a periodically oscillating square well are studied. The dynamics of the system is described by using a two-dimensional non-linear area-preserving map for the variables energy and time. The phase space is mixed and the chaotic sea is described using scaling arguments. Scaling exponents are obtained as a function of all the control parameters, extending the previous results obtained in the literature. 相似文献
60.
The dynamics of a driven stadium-like billiard is considered using the formalism of discrete mappings. The model presents a resonant velocity that depends on the rotation number around fixed points and external boundary perturbation which plays an important separation rule in the model. We show that particles exhibiting Fermi acceleration (initial velocity is above the resonant one) are scaling invariant with respect to the initial velocity and external perturbation. However, initial velocities below the resonant one lead the particles to decelerate therefore unlimited energy growth is not observed. This phenomenon may be interpreted as a specific Maxwell’s Demon which may separate fast and slow billiard particles. 相似文献