New high-energy luminescence bands from Co2+ in ZnSe

Three sharp absorption features in the energy range 2.36–2.55 eV have been detected in the transmission spectrum of Co-diffused ZnSe, and a number of luminescence transitions originating from the lowest of these states at 2.361 eV have been observed. Photoluminescence excitation spectra prove that these are high energy excited states of the Co²⁺_Zn impurity, a conclusion confirmed by comparison of measured and predicted luminescence energies. This represents the first identification of luminescence branching from a higher excited state of a transition metal ion in any semiconductor. The sharp, weakly phonon-coupled transitions involve either intra-impurity excitation or transitions from the impurity to localised states split off from a minimum in the conduction band. The implications of these observations for the mechanism of host-impurity energy transfer and for the nature of the excited state wavefunctions are discussed.     

Simultaneous attainment of high electron and ion temperatures in discharges with internal transport barriers in ASDEX upgrade

Internal transport barriers have been demonstrated to exist also under conditions with T(e) approximately T(i) approximately 10 keV and predominant electron heating of the tokamak core region. Central electron cyclotron heating was added to neutral beam injection-heated ASDEX Upgrade discharges with a preexisting internal transport barrier, established through programmed current ramping leading to shear reversal. Compared to a reference internal transport barrier discharge without electron cyclotron resonance heating, the electron heat conductivity in the barrier region was found not to increase, in spite of a fivefold increase in electron heat flux, and also angular momentum and ion energy transport did not deteriorate.     

Z4-Kerdock Codes, Orthogonal Spreads, and Extremal Euclidean Line-Sets

When m is odd, spreads in an orthogonal vector space of type⁺(2m + 2,2) are related to binary Kerdock codes and extremalline-sets in 2^{m + 1} with prescribed angles. Spreads in a 2m-dimensionalbinary symplectic vector space are related to Kerdock codesover Z₄ and extremal line-sets in with prescribed angles. These connections involve binary, realand complex geometry associated with extraspecial 2-groups.A geometric map from symplectic to orthogonal spreads is shownto induce the Gray map from a corresponding Z₄-Kerdock codeto its binary image. These geometric considerations lead tothe construction, for any odd composite m, of large numbersof Z₄-Kerdock codes. They also produce new Z₄-linear Kerdockand Preparata codes. 1991 Mathematics Subject Classification:primary 94B60; secondary 51M15, 20C99.     

Application of Combinatorial Procedures in the Search for Serine-Protease-Like Activity with Focus on the Acyl Transfer Step

Recursive deconvolution of a 729-membered peptide library has identified three active sequences, in which both Ser and His are present in one of the two tripeptidic chains generated on a steroidal scaffold (see structural formula), for the cleavage of an activated p-nitrophenyl ester. This combinatorial approach aims at searching for serine-protease-like activity.