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991.
992.
This paper further investigates integral generalized inverses of integral matrices. 相似文献
993.
994.
995.
The conversion ratiosK/L I andK/L II of the 238.6 keVγ transition of ThB have been measured with the new Heidelbergπ/2 √13Β-ray spectrometer. For this transition there are great discrepancies between the values as given bySliv andBand, and byRose. The experimental resultsK/L I=5.96±0.26 andK/L II=60.3±7.1 are in excellent agreement with the values ofSliv andBand. 相似文献
996.
Extensive data now available on the non-thermal background radio emission from different celestial directions, and recent measurements on the energy spectrum of cosmic ray electrons in the vicinity of the earth permit one to deduce information on the mean magnetic fields and cosmic electron spectra needed to exist in different regions of the Galaxy. It is found that in order to explain quantitatively the background radio brightness distributions from the Galaxy one needs (i) the same or nearly same electron spectrum that exists in the near interstellar space, to exist in almost all regions of Galactic space, (ii) a mean magnetic field close to 6×10?6 Gauss in the Disc in the direction of the Anti-centre, (iii) a mean magnetic field close to 2·5×10?6 Gauss in the radio Halo and (iv) a mean magnetic field probably close to 9·5×10?6 Gauss towards the Galactic Ridge in the direction of the Centre. Some inferences are also drawn on the confinement of cosmic rays in the Galaxy. 相似文献
997.
Extended supergravity theories with global O(2) and SO(3) internal symmetry have recently been constructed, and a mechanism which implements local O(2) and SO(3) gauge invariance is given here. The introduction of a minimal gauge coupling automatically leads to a mass and a cosmological term in order to preserve local supersymmetry. Local internal symmetry for a field is related to spontaneous breakdown of global supersymmetry. Perturbation theory results which confirm the physical consistency of the system are given. 相似文献
998.
Anthony V. Galanti Brian T. Keen Ruth H. Pater Daniel A. Scola 《Journal of polymer science. Part A, Polymer chemistry》1981,19(9):2243-2253
The amine catalyzed isomerization of itaconic to citraconic anhydride has been investigated. Studies show that the rate of isomerization is dependent on the base strength and solvent media. Triethylamine causes complete isomerization within 5 min at room temperature in acetone or chloroform solvent, whereas aromatic tertiary amines such as pyridine and N,N-dimethylaniline require time perods as long as 23h at room temperature for almost complete isomerization. In the presence of aniline no isomerization occures even under acetone reflux conditions over a 24 h period. For the preparation of citraconamic acids from itaconic anhydrides and aliphatic diamines nuclear magnetic resonance and infrared spectroscopic evidence is presented to support the reaction path of initial isomerization of itaconic anhydride to citraconic anhydride followed by amine attack on the anhydride to form the corresponding cis-citraconamic acids. The mechanism of isomerization of itaconic to citraconic acids is proposed. 相似文献
999.
R. Daniel Little George W. Muller Manuel G. Venegas Gary L. Carroll Ahmed Bukhari Larry Patton Keith Stone 《Tetrahedron》1981,37(25):4371-4383
A comparison of the inter- and intramolecular diyl trapping routes to linearly fused tricyclopentanoids is presented. In addition, several of the factors which are responsible for the stereoselectivity which is associated with the intramolecular process are examined and it is concluded that conformational rather than electronic (secondary orbital) factors play the dominant role. It is shown that gem methyl groups located on the acyclic chain which joins the diyl and diylophile (in reference to 32 and 35, but not to 47) have no practical effect upon the outcome of the trapping reaction. The intramolecular process is stereospecific with respect to diylophile geometry, and highly stereoselective with respect to the ring junction stereochemistry. Finally, an abortive attempt to synthesize the marine natural product Δ9(12)-capnellene (19) as well as a successful synthesis of the mold metabolite d,l- hirsutene (18) is presented. 相似文献
1000.
J. N. Spencer Eric S. Holmboe Daniel W. Firth Mindy R. Kirshenbaum 《Journal of solution chemistry》1981,10(10):745-756
Enthalpies of solution have been used to calculate transfer enthalpies for phenol, pyridine, and DMSO between the solvent cyclohexane and the solvents CCl4, benzene, and CHCl3. By use of model compounds, enthalpies due to interactions with phenol, pyridine, and DMSO have been determined. These enthalpies are used to calculate the effect of solvation relative to cyclohexane on hydrogen bonded complexes in CCl4 and benzene solvents. Correlations with enthalpies due to interactions and frequency shifts for the hydroxyl stretch in these solvents have also been made. 相似文献