Zur Bestimmung des Glycerins

Ohne Zusammenfassung     

Ueber die L?slichkeit des Thonerdehydrates in Ammoniak

Ohne Zusammenfassung     

Cellulose

Ohne Zusammenfassung     

Salt effects in capillary zone electrophoresis. IV. Resolution versus time and the effect of potassium phosphate and its concentration in the high ionic strength separation of sulphonamides.

The effects of potassium phosphate buffer and its concentration upon the capillary zone electrophoretic separation of 23 sulphonamides and a neutral marker were examined at pH 7. The resolution between the pairs was improved with the increased concentration of the buffer from 65 mM to 174 mM. Nineteen sulphonamides, a hydrolysis product and several unidentified minor components were baseline resolved in both 101 and 138 mM phosphate buffers. In 174 mM buffer all 21 ionised sulphonamides and the other compounds were separated. A simple relationship between the resolution of analyte pairs (Rs) and the square root of the mean analysis time for the pair (square root of tapp) was derived, but few of the pairs displayed this behaviour. For the majority of pairs of compounds, Joule heating appeared to cause a maximum in the Rs versus square root of tapp relationship, while non-ideality and shifts in ionisation with increasing salt concentration appeared dominant in other cases.     

Interpretation of graphs with logarithmic scales

Summary The use of logarithmic scales for the graphical presentation of experimental data can lead to errors in interpretation. Consideration is given to two examples in rheology, namely the viscosity — molecular weight relationship for a polymer system, and flow behaviour at low rates of shear.

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Zusammenfassung Die Verwendung logarithmischer Skalen bei der graphischen Darstellung experimenteller Ergebnisse kann zu Interpretationsfehlern führen. Dies wird an zwei Beispielen aus der Rheologie diskutiert, nämlich an der Viskositäts-Molekulargewichts-Beziehung von Polymersystemen und am Fließverhalten bei kleinen Schergeschwindigkeiten.

     

On the dynamic response of viscoelastic fluids

Summary To define the dynamic shear behaviour of a viscoelastic fluid we require two functions — one elastic and one viscous. There are two simple alternatives based on the Voigt and Maxwell concepts which are mathematically interrelated. Current practice interprets the dynamic response of fluids as a function of angular frequency () in terms of the storage (G) and loss (G) moduli: the loss function is commonly converted to a viscosity = G/. As is well known the parameters andG are the elements of a Voigt model whereas it is near universal practice to interpret steady flow in terms of the Maxwell model. This paper shows how the interpretation of dynamic experiments on fluids in terms of the apparent Maxwell parameters is more simple, more sensitive, more consistent with steady flow behaviour, and physically more realistic.

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Zusammenfassung Zur Festlegung des dynamischen Scherverhaltens einer viskoelastischen Flüssigkeit benötigt man zwei Funktionen, eine für das elastische und eine für das viskose Verhalten. Dafür gibt es zwei einfache, mathematisch miteinander verknüpfte Alternativen, die entweder auf dem Voigtschen oder dem Maxwellschen Konzept gründen. Die übliche Praxis beschreibt das dynamische Verhalten der Flüssigkeiten als Funktion der Winkelgeschwindigkeit durch den SpeichermodulG und den VerlustmodulG bzw. die zugeordnete Viskosität = G/. Die Parameter undG sind bekanntlich die Elemente eines Voigt-Modells, wohingegen es nahezu allgemein üblich ist, das stationäre Fließen durch ein Maxwell-Modell zu beschreiben. Diese Arbeit zeigt nun, daß die Beschreibung dynamischer Versuche mit Hilfe von apparenten Maxwell-Parametern einfacher, empfindlicher, mit dem stationären Verhalten konsistenter und in physikalischer Hinsicht realistischer ist.

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Paper presented at British Society of Rheology conference. Rheometry: Methods of measurement and analysis of results, Shrivenham, April 8–11, 1975.

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With 13 figures and 2 tables     

Supporting disciplinary and interdisciplinary knowledge development and design thinking in an informal,pre‐engineering program: A Workplace Simulation Project

In this paper, we examined students’ engagement in an implementation of a Workplace Simulation Project (WSP). The WSP was designed to actively engage students in learning disciplinary content by inviting engineers from industry to have a physical presence within the school building to collaborate with teachers and students to complete projects which simulate the tasks authentic to their work. We focus on the first year implementation of the program that partnered a high school in the rural Midwest with an engineering unit of a government organization. Using a multiple methods study design, we analyzed disciplinary and interdisciplinary pre and posts test along with students’ interviews to determine learning gains as well as students’ interpretations of creative and critical thinking as experienced in the project and their knowledge of the engineering design process. Effect sizes showed that students in the WSP group had notable gains over the control group participants. Additionally, students’ knowledge of core elements of the design process were identified in inductive analyses of the interviews. Findings from this study will provide usable knowledge about effective ways to support systems and design thinking and ways to support expert‐novice collaboration to ensure success.     

Free surface Nvier-Stokes flows with simultaneous heat transfer and solidification/melting

A mathematical model to analyse some key aspects of the metal cast process is described involving the filling of the mould by liquid metal and simultaneously, undergoing both cooling and solidification (re-melting) phase change. A computational solution procedure based upon a finite volume discretisation approach, on both structured and unstructured meshes, is described. The overall flow solution procedure is based on the pressure correction algorithm SIMPLE suitably adapted to: (a) solve for the free surface with minimal smearing by the SEA algorithm, and (b) solve for the solidification/melting phase change using an enthalpy conservation algorithm developed by Voller, but with its root in the work of Crank many years ago.Dedicated to Professor J. Crank on the occasion of his 80th birthday     

The contribution of 2N photon absorption in C(γ,2N) reactions for Eγ = 150–400 MeV

The ¹²C(γ,pn) and ¹²C(γ,pp) reactions have been studied using tagged photons of energy E_γ = 150–400 MeV. Recoil momentum distributions are compared to the results of Monte Carlo calculations based on a two-nucleon photon absorption model and two different phase space models. The ¹²C(γ,pn) data at low missing energy are consistent with absorption on 1p² and 1s1p nucleon pairs.