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排序方式: 共有191条查询结果,搜索用时 321 毫秒
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The coordinating properties of a new bis(pyridylhydrazone) ligand derived from iminodiacetic acid diethyl ester and 2-pyridinecarboxaldehyde
(picolinaldehyde) H3Imdp and of the bis(salicylhydrazone) H5Imds and H4MeImds ligands derived, respectively, from iminodiacetic acid diethyl ester and from methyl-iminodiacetic acid diethyl ester
and salicylaldehyde were considered, by means of analytical and spectroscopic methods, towards first row transition metal
ions. These ligands showed various coordination modes in complexation with Cu(II), Co(II), Mn(II) and Zn(II) ions. In particular,
we have synthesized and characterized, by analytical, 1H NMR and IR techniques, tri-, di- and mononuclear metal complexes of formula Co3(HImdp)(NO3)4·2H2O, Cu3(HImdp)(NO3)4·C2H5OH·H2O, Cu3(HImdp)Cl4, Zn2(H3Imdp)(ClO4)4·2H2O, Co3(HImds)Cl2·CH3OH·H2O, Zn2(H3Imds)Cl2·2H2O, Co(H4Imds)NO3·2H2O, Mn(H4Imds)Cl·CH3OH·H2O, Cu(H3Imds)·CH3OH·H2O and Cu(H2MeImds).CH3OH·3H2O. Antibacterial, antifungal and antiprotozoal properties of H5Imds and H3Imdp together with three copper(II) trinuclear species of H5Imds of formula Cu3(HImds)(NO3)2.2CH3OH·2H2O, Cu3(HImds)(ClO4)2.EtOH·2H2O and Cu3(HImds)SO4·4H2O are also discussed. The H5Imds ligand and their trinuclear copper(II) complexes showed good activities versus Trichomonas vaginalis, Staphylococcus epidermidis and Acanthamoeba castellanii. 相似文献
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Waterborne polyurethane-acrylic hybrid nanoparticles by miniemulsion polymerization: applications in pressure-sensitive adhesives 总被引:2,自引:0,他引:2
Lopez A Degrandi-Contraires E Canetta E Creton C Keddie JL Asua JM 《Langmuir : the ACS journal of surfaces and colloids》2011,27(7):3878-3888
Waterborne polyurethane-acrylic hybrid nanoparticles for application as pressure-sensitive adhesives (PSAs) were prepared by one-step miniemulsion polymerization. The addition of polyurethane to a standard waterborne acrylic formulation results in a large increase in the cohesive strength and hence a much higher shear holding time (greater than seven weeks at room temperature), which is a very desirable characteristic for PSAs. However, with the increase in cohesion, there is a decrease in the relative viscous component, and hence there is a decrease in the tack energy. The presence of a small concentration of methyl methacrylate (MMA) in the acrylic copolymer led to phase separation within the particles and created a hemispherical morphology. The tack energy was particularly low in the hybrid containing MMA because of the effects of lower energy dissipation and greater cross-linking. These results highlight the great sensitivity of the viscoelastic and adhesive properties to the details of the polymer network architecture and hence to the precise composition and synthesis conditions. 相似文献
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After showing that the partial complex structure is defined by an inner derivation, we give a complete classification of semisimple Levi-Tanaka algebra. 相似文献
129.
Delizia Costantino Shumyatsky Pavel Tortora Antonio Tota Maria 《Archiv der Mathematik》2019,112(1):27-32
Archiv der Mathematik - We prove that a commutator of two non-commutator words is a concise word. 相似文献
130.
Costantino Sigismondi 《中国科学G辑(英文版)》2009,52(11):1773-1777
By inspection of central eclipses videorecords, data of Baily beads timings are retrievable. Knowing the lunar limb profile
at the moment of the eclipse we evaluate the excess or defect of solar limb when the Sun is assumed at its standard radius.
Two procedures of data analysis are here presented: one based on limb heights and the other on times. While these methods
are based upon Occult 4 software, they can be used with other ephemerides and new lunar profiles. The example of 2006 total
eclipse data, with its remarkably negative value of ΔR= − 0.41“± 0.04”, is presented. 相似文献