A non-product type non-singular transformation which satisfies Krieger’s Property A

In this paper we give an example of an ergodic non-singular transformation of type III, which satisfies Krieger’s Property A, but which is not orbit equivalent to any product type odometer.     

Sestak–Berggren function in temperature-programmed reduction

From the peculiarities of Temperature-programmed reduction (TPR) method and using the Sestak–Berggren conversion function, we describe first the TPR curve simulation procedure. The influence of the Sestak–Berggren exponents on the TPR peak maximum and shape is demonstrated, by analyzing several synthetic TPR profiles. Finally, the kinetic parameters of Au/CeO₂ promoted with yttrium as well as those of Au/CeO₂–Al₂O₃ promoted with V₂O₅ are discussed.     

The Poisson equation on complete manifolds with positive spectrum and applications

In this paper we investigate the existence of a solution to the Poisson equation on complete manifolds with positive spectrum and Ricci curvature bounded from below. We show that if a function f has decay f=O(r−1−ε) for some ε>0, where r is the distance function to a fixed point, then the Poisson equation Δu=f has a solution u with at most exponential growth.We apply this result on the Poisson equation to study the existence of harmonic maps between complete manifolds and also existence of Hermitian-Einstein metrics on holomorphic vector bundles over complete manifolds, thus extending some results of Li-Tam and Ni.Assuming moreover that the manifold is simply connected and of Ricci curvature between two negative constants, we can prove that in fact the Poisson equation has a bounded solution and we apply this result to the Ricci flow on complete surfaces.     

Mediator-modified electrodes for catalytic NADH oxidation: high rate constants at interesting overpotentials

Carbon paste electrodes were modified with a nitrofluorenone derivative, 2,4,7-trinitro-9-fluorenone, adsorbed on zirconium phosphate (ZP). After electrochemical reduction of the fluorenone derivative, it turns into a very efficient mediator for electrocatalytic NADH oxidation, with a formal potential of about +250 mV vs. Ag/AgCl. The electrochemistry and the electrocatalytic properties of the mediator were investigated with cyclic voltammetry and rotating disk electrode methodology. The second order rate constant with NADH was evaluated and found to be higher than 10(6) M(-1) s(-1), thus approaching true diffusion controlled currents for NADH oxidation.     

Efficient one pot preparation of variously substituted thieno [2,3‐b] thiophene

An efficient one pot access to variously substituted thieno[2,3‐b]thiophene is described. The title compounds were obtained from 1,3‐dicarbonyl or equivalent compounds, carbon disulfide and halomethyl derivatives in good to high yields and fully characterized.     

Multifunctional materials based on polyazomethines derived from 2,5‐dihydroxy‐1,4‐benzoquinone and siloxane diamines

New polyazomethines have been synthesized by the reaction between 2,5‐dihydroxy‐1,4‐benzoquinone and siloxane diamines differing by the siloxane sequence length. A dimer has also been prepared as a model compound. The products were characterized by spectral (FTIR and ¹H‐NMR) and elemental analyses, GPC, viscosity measurements, solubility tests, and transmission electron microscopy (TEM). The different properties have been investigated by adequate techniques: thermal (DSC and TGA), spectral (UV–vis and fluorescence spectroscopy), redox (Differential Pulse Voltammetry). pH‐sensitivity and metal complexing ability were also evaluated. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1862–1872, 2008     

Sensitivity and Approximation of Coupled Fluid-Structure Equations by Virtual Control Method

The formulation of a particular fluid--structure interaction as an optimal control problem is the departure point of this work. The control is the vertical component of the force acting on the interface and the observation is the vertical component of the velocity of the fluid on the interface. This approach permits us to solve the coupled fluid--structure problem by partitioned procedures. The analytic expression for the gradient of the cost function is obtained in order to devise accurate numerical methods for the minimization problem. Numerical results arising from blood flow in arteries are presented. To solve the optimal control problem numerically, we use a quasi-Newton method which employs the analytic gradient of the cost function and the approximation of the inverse Hessian is updated by the Broyden, Fletcher, Goldforb, Shano (BFGS) scheme. This algorithm is faster than fixed point with relaxation or block Newton methods.     

Bonding and metal-atom dynamics in two unique Sn(I)-Sn(III) complexes

Two recently reported tin complexes, which incorporate both Sn(I) and Sn(III) sites in their structure, have been examined by temperature-dependent 119Sn M?ssbauer effect (ME) spectroscopy. The distinct hyperfine parameters of the two sites make it possible to assign relative occupancies of the two sites (at 90 K) on the basis of the recoil-free fraction data extracted from the ME spectra. The temperature dependencies of the recoil-free fractions, elucidated from the ME spectra, show that the metal-atom dynamics are very similar for the two sites in the temperature range 90相似文献   

Bound excitons in p-doped GaAs quantum wells

Photoluminescence attributed to excitons bound to neutral impurities has been observed from GaAs quantum wells in Al_xGa_1?xAs-GaAs heterostructures grown by molecular beam epitaxy. The quantum wells were either doped with [Be] ≈ 10¹⁷ cm^-3 or Zn-diffused. At low temperatures both single and multiple quantum wells exhibited this extrinsic luminescence which is ascribed to the radiative recombination of the n=1 ground state heavy hole exciton E_1h bound to a neutral acceptor A^o. The dissociation energy E_D of the A^o-E_1h complex is obtained directly from the measured separation of this extrinsic peak from the intrinsic E_1h free exciton peak. For 46Å wide GaAs wells, E_D=6.5meV and E_D decreases with increasing well width.