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91.
Holschumacher D Bannenberg T Ibrom K Daniliuc CG Jones PG Tamm M 《Dalton transactions (Cambridge, England : 2003)》2010,39(44):10590-10592
Frustrated carbene-borane Lewis pairs are able to affect the selective cleavage of one of the six P-P bonds in white phosphorus (P(4)) to afford an adduct, in which an abnormal carbene of the imidazolium-4-yl type and B(C(6)F(5))(3) are bound in a trans,trans fashion to a butterfly-like bicyclo[1.1.0]tetraphosphabutane moiety. 相似文献
92.
Constantin JG Fris AR Appignanesi G Carignano M Szleifer I Corti H 《The European physical journal. E, Soft matter》2011,34(11):126
The structure of water clusters (H2O)n (n = 40 -200) and bulk water were examined by molecular dynamics simulations using the TIP4P-ice water model. The analysis of
the low-temperature structures in terms of the local structure index (LSI) showed a bimodal distribution. This finding supports
the two-state picture derived from the analysis of the inherent dynamics of bulk SPC/E water. The water molecules at the outer
interface of the coldest clusters are more structured than those in the inner core. The geometrical constraint of the interface
forces the surface molecules to lose one neighbor and adopt a local angular distribution of hydrogen bonds resembling that
found in the basal plane of ice Ih. 相似文献
93.
94.
In this note we are concerned with numerical solutions to Dirichlet problem $$[\phi(u')]' =f(x) \quad \mbox{in} [\alpha, \beta]; \quad u(\alpha)=A, \; u(\beta)=B, $$ where \(\phi :(-\eta , \eta ) \to \mathbb {R}\) \((\eta <+ \infty )\) is an increasing diffeomorphism with \(\phi '(y)\geq d >0\) for all \(y\in (-\eta , \eta )\) . The obtained algorithm combines the shooting method with Euler’s method and it is convergent whenever the problem is solvable. We provide numerical experiments confirming the theoretical aspects. 相似文献
95.
In constraining iterative processes, the algorithmic operator of the iterative process is pre-multiplied by a constraining operator at each iterative step. This enables the constrained algorithm, besides solving the original problem, also to find a solution that incorporates some prior knowledge about the solution. This approach has been useful in image restoration and other image processing situations when a single constraining operator was used. In the field of image reconstruction from projections a priori information about the original image, such as smoothness or that it belongs to a certain closed convex set, may be used to improve the reconstruction quality. We study here constraining of iterative processes by a family of operators rather than by a single operator. 相似文献
96.
We prove in this paper that the Hilbert geometry associated with an open convex polygonal set is Lipschitz equivalent to the Euclidean plane. 相似文献
97.
The electrochemical stability of TiO2 nanoarchitecture fabricated in fluoride electrolyte presented in this paper is related to 2D and 3D geometries that present a shift from nanopores toward nanotubes. The fabrication conditions involve a 60 V applied voltage for 2 hours of anodizing in order to create the ordered structures, in a mixture of low‐water glycerol electrolyte and fluoride. With the use of different ultrasonication times, a variety of nanotubes/nanopores were observed. The surface interfacial aspects were investigated mainly by surface microscopy and hydrophilic/hydrophobic balance for the grown structures ultrasonicated at various periods of time. The electrochemical behavior of the nanotube‐structured surface was performed by potentiodynamic evaluation and electrochemical impedance spectroscopy in a simulated body fluid solution. As a most important result, all surface analysis and electrochemical data interpretation permitted the proposition of a model for elaboration of different nanostructures from nanopores to nanotubes. These different surface nanoarchitectures were obtained as a result of ultrasonication at various periods of time. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
98.
Constantin Krauss 《Fresenius' Journal of Analytical Chemistry》1891,30(1):227-242
Ohne Zusammenfassung 相似文献
99.
100.