Study of intermediates formed in the oxidation of thiols

The oxidation of aminoethanethiol (1) was investigated in acid solutions on a glass carbon anode. It was shown that at relatively low anode potentials thiyl radicals RS^· are released into the solution, but this does not lead to binding of the oxygen in the solution. Raising the anode potential leads to binding of oxygen, which is probably due to the formation of the intermediate RS⁺. The oxidation of 1 was studied in Ce(SO₄)₂+H₂SO₄ solution. It was shown that under certain conditions the intermediate is RS⁺, which subsequently converts to a product that could not be identified as any previously described product of the oxidation of thiols. Proposals are made regarding its structure and conversion pathways.B. P. Konstantinov Institute of Nuclear Physics, Russian Academy of Sciences, 188350 Leningrad. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 2, pp. 278–288, February, 1992.     

Natural convection from a buried elliptic heat source

Numerical solutions are presented for the natural convection heat transfer from an elliptic heat source buried beneath a semi-infinite, saturated, porous medium. The surface of the medium is assumed to be permeable. The governing equations for Darcy flow are solved using finite differences. The complicated geometry is handled through the use of a body-fitted curvilinear coordinate system. Results are presented for Ra values ranging from 10 to 200 and ellipse aspect ratio values from 1.0 (circular cylinder) to 0.167. Two body orientations have been considered. The slender orientation yields much higher hear transfer rates (especially at low ellipse aspect ratio values) than the blunt orientation. The numerical simulations indicate that the boundary-layer approximations cannot be employed for low ellipse aspect ratios. In addition, the heat loss does not depend on the burial depth.     

On the deficiency index of a certain class of differential operators

This paper studies problems on the behavior of solutions for a certain class of differential equations of the form l _n y = λy as x → +0, where l _n is a scalar, formally self-adjoint, quasidifferential expression of an arbitrary order with complex coefficients. The results obtained allow us to find the defficiency index of the operator generated by the expression l _n . __________ Translated from Sovremennaya Matematika i Ee Prilozheniya (Contemporary Mathematics and Its Applications), Vol. 36, Suzdal Conference-2004, Part 2, 2005.     

Mössbauer study of layered iron hydroxysulfides: Tochilinite and valleriite

Natural and synthetic layered iron hydroxysulfides: tochilinite and valleriite, have been investigated by Mössbauer spectroscopy. Tochilinite, magnetite, troilite, and pyrite phases were found in the products of tochilinite synthesis under different conditions. The relative contents of the phases found are determined as functions of the relative magnesium content in the initial mixture. Crystallochemical identification of the ⁵⁷Fe subspectra of valleriite has been performed.     

Effect of optical blooming of a nanocrystal monolayer and the interface between two media

It is shown that several parameters of the near-field interaction of particles effectively control the reflectance of the interface between vacuum and a semi-infinite medium in a structured monolayer of nanoparticles, changing it from 0 to 1. The formulas derived for the electric field amplitudes inside and outside the nanostructural layer take into account the periodic arrangement of nanoparticles. The ideal blooming condition of the boundary of the underlying medium is derived, under which the reflectance of the interface tends to zero in a wide range of wavelengths in the visible optical range.     

Synthesis and structure of O-(arylcarbamoyl)butyrhydroximoyl chlorides

The O-(arylcarbamoyl)butyrhydroximoyl chlorides were synthesized, and the x-ray structural analysis (XSA) of one of them — O-(o-tolylcarbamoyl)butyrhydroximoyl chloride — was performed. It was established from the data of the XSA and the PMR spectra that all synthesized compounds are the Z isomers.Institute of Physiologically Active Substances, Russian Academy of Sciences, 142432 Chernogolovka. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 2, pp. 315–319, February, 1992.     

Patterns in parabolic problems with nonlinear boundary conditions

We obtain existence of asymptotically stable nonconstant equilibrium solutions for semilinear parabolic equations with nonlinear boundary conditions on small domains connected by thin channels. We prove the convergence of eigenvalues and eigenfunctions of the Laplace operator in such domains. This information is used to show that the asymptotic dynamics of the heat equation in this domain is equivalent to the asymptotic dynamics of a system of two ordinary differential equations diffusively (weakly) coupled. The main tools employed are the invariant manifold theory and a uniform trace theorem.