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971.
972.
973.
G. T. Jones R. W. L. Jones B. W. Kennedy S. W. O'Neale H. Klein D. R. O. Morrison P. Schmid H. Wachsmuth F. Hamisi D. B. Miller M. M. Mobayyen S. Wainstein M. Aderholz D. Hantke E. Hoffmann U. F. Katz J. Kern N. Schmitz W. Wittek G. Corrigan G. Myatt D. Radojicic P. N. Shotton S. J. Towers F. W. Bullock S. Burke 《Zeitschrift fur Physik C Particles and Fields》1989,44(3):379-384
Within the framework of the quark-parton model, the quark and anti-quark structure functions of the proton have been measured by fitting them to the distributions of the events in the Bjorkeny variable. The data used form the largest sample of neutrino and antineutrino interactions on a pure hydrogen target available, and come from exposures of BEBC to the CERN wide band neutrino and antineutrino beams. It is found that the ratiod v /u v of valence quark distributions falls with increasing Bjorkenx. In the context of the quark-parton model the results constrain the isospin composition of the accompanying diquark system. Models involving scattering from diquarks are in disagreement with the data. 相似文献
974.
975.
976.
Christian Haase 《Tetrahedron》2009,65(23):4530-3950
The acid-mediated reaction of amines with γ-alkylidenebutenolides, readily available by cyclization of 1,3-bis(silyloxy)-1,3-butadienes with oxalyl chloride, allows a convenient synthesis of a variety of 5-alkylidene-2,5-dihydropyrrol-2-ones. The configuration of the exocyclic double bond of the products depends on the substitution pattern of the products. 相似文献
977.
Christian Zillober 《Numerical Algorithms》2001,27(3):265-289
The method of moving asymptotes (MMA) and its globally convergent extension SCP (sequential convex programming) are known to work well for certain problems arising in structural optimization. In this paper, the methods are extended for a general mathematical programming framework and a new scheme to update certain penalty parameters is defined, which leads to a considerable improvement in the performance. Properties of the approximation functions are outlined in detail. All convergence results of the traditional methods are preserved. 相似文献
978.
979.
980.
Christian Slugovc Eva Rüba Roland Schmid Karl Kirchner Kurt Mereiter 《Monatshefte für Chemie / Chemical Monthly》2000,131(12):1241-1251
Summary. This article gives an overview of recent chemistry based on the tris-acetonitrile complex [RuCp(CH3CN)3]+. Due to the labile nature of the CH3CN ligands, substitution reactions are a dominant feature of this complex. Important derivatives are the highly reactive complexes
[RuCp(PR
3)(CH3CN)2]+ which are a source of the 14e− fragment [RuCp(PR
3)]+. These species are catalytically active in the redox isomerization of allyl alcohols to give aldehydes and ketones. Furthermore,
the cationic complex [RuCp(κ1(P),η2-PPh2CH2CH2CH*CH2)(CH3CN)]PF6 derived from the reaction of [RuCp(CH3CN)3]+ with PPh2CH2CH2CH*CH2 is a model compound for studying coupling reactions of olefins and acetylenes. In addition, [RuCp(CH3CN)3]+ is a valuable precursor for the synthesis of configurationally stable chiral three-legged piano-stool ruthenium complexes.
These are currently being intensively investigated as Lewis acid catalysts in asymmetric synthesis.
Received May 31, 2000. Accepted June 13, 2000 相似文献