Mechanism on oscillating lifted flames in nonpremixed laminar coflow jets

The oscillating lifted flame in a laminar nonpremixed nitrogen-diluted fuel jet is known to be a result of buoyancy, though the detailed physical mechanism of the initiation has not yet been properly addressed. We designed a systematic experiment to test the hypothesis that the oscillation is driven by competition between the positive buoyancy of flame and the negative buoyancy of a fuel stream heavier than the ambient air. The positive buoyancy was examined with various flame temperatures by changing fuel mole fraction, and the negative buoyancy was investigated with various fuel densities. The density of the coflow was also varied within a certain range by adding either helium or carbon dioxide to air, to study how it affected the positive and negative buoyancies at the same time. As a result, we found that the range of oscillation was well-correlated with the positive and the negative buoyancies; the former stabilized the oscillation while the latter triggered instability and became a source of the oscillation. Further measurements of the flow fields and OH radicals evidenced the important role of the negative buoyancy on the oscillation, detailing a periodic variation in the unburned flow velocity that affected the displacement of the flame.     

Multiphysics Simulation Combining Large-Eddy Simulation,Wall Heat Conduction and Radiative Energy Transfer to Predict Wall Temperature Induced by a Confined Premixed Swirling Flame

A multi-physics simulation combining large-eddy simulation, conjugate heat transfer and radiative heat transfer is used to predict the wall temperature field of a confined premixed swirling flame operating under atmospheric pressure. The combustion model accounts for the effect of enthalpy defect on the flame structure whose stabilization is here sensitive to the wall heat losses. The conjugate heat transfer is accounted for by solving the heat conduction within the combustor walls and with the Hybrid-Cell Neumann-Dirichlet coupling method, enabling to dynamically adapt the coupling period. The latter coupling procedure is enhanced to determine statistics (mean, RMS, \(\ldots \)) in a permanent regime accurately and efficiently thanks to an acceleration technique which is derived and validated. The exact radiative heat transfer equation is solved with an advanced Monte Carlo method with a local control of the statistical error. The coupled simulation is carried out with or without accounting for radiation. Excellent results for the wall temperature are achieved by the fully coupled simulation which are then further analyzed in terms of radiative effects, global energy budget and fluctuations of wall heat flux and temperature.     

A method to stabilize the incident X‐ray energy for anomalous diffraction measurements

A method to calibrate and stabilize the incident X‐ray energy for anomalous diffraction data collection is provided and has been successfully used at the single‐crystal diffraction beamline 1W2B at the Beijing Synchrotron Radiation Facilities. Employing a feedback loop to control the movement of the double‐crystal monochromator, this new method enables the incident X‐ray energy to be kept within a 0.2 eV range at the inflection point of the absorption edge.     

飞机舱音记录器背景声的联合时频分析研究

飞机舱音记录器记录的舱音主要是由话语音、噪声和具有不同物理意义的背景声组成的复杂混合体,用传统的辨听和分析方法难以获取较多的舱音特征参数。本文以一个舱音记录器记录的主告警声为例,针对传统短时傅立叶变换在舱音辨听、分析的不足,将联合时频分析引入到飞机舱音分析中,扩展了舱音分析方法。对比分析结果表明:时频分布及其重排,在时频分辨率、时频凝聚性、交叉项干扰的抑制上各有所长,都适合分析非平稳舱音背景声,从而为飞行事故调查提供一种值得采用的方法。     

修饰聚合物液-固亲和萃取体系分离钪与钕及机理探讨

研究了加修饰聚合物(PEG-IDA)的吐温(Tween)80-盐水液-固体系亲和萃取稀土(RE)离子时体系酸度对萃取率的影响,并控制萃取酸度实现了Sc与Nd的定量分离,平均回收率Sc：99．72％;Nd：100.88％。测定新络合物的稳定常数,两者相差4倍,是分离的原因。对该体系分离Sc与Nd的机理进行探讨表明,RE-PEG-IDA络合物主要是与Tween 80形成了氢键。     

Analysis of fatty acids in sputum from patients with pulmonary tuberculosis using gas chromatography–mass spectrometry preceded by solid-phase microextraction and post-derivatization on the fiber

A method based on solid-phase microextraction (SPME) and post-derivatization on the fiber coupled to gas chromatography–mass spectrometry (GC–MS) was developed for the analysis of fatty acids in sputum from patients with pulmonary tuberculosis. The sputum specimens were digested, hydrolyzed, extracted, derivertized, injected and analyzed without cultivation or isolation of the microorganism. Under optimized conditions, the relative standard deviations (RSD, n = 5) for all analytes were below 17% and the limits of detection varied from 1.68 (C_24:0) to 150.4 μg L⁻¹ (C_12:0). Good linearity was observed for all the fatty acids studied except for C_12:0 within a wide concentration range of three orders of magnitudes with the correlation coefficients ranging from 0.91 (C_24:0) to 0.99 (C_14:0). Fatty acids in sputum specimens from 21 persons were directly analyzed using the proposed method. The results show that in all the sputum specimens from patients, who were clinically diagnosed with tuberculosis (TB), tuberculosis stearic acid (TBSA) was detected, while in all the sputum samples from persons without TB, TBSA was not found. The possibility of using the proposed method to detect mycobacterium tuberculosis (MTB) via the identification of TBSA in sputum was discussed. The comparison with other methods including sputum culture and microscopy of direct smears indicated that the proposed method is fast and sensitive for the analysis of fatty acids in sputum and offers an alternative for the detection of MTB in sputum.