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161.
The contact domain utilized by horse cytochrome c when adsorptively bound to a C(10)COOH self-assembled monolayer (SAM) was delineated using a chemical method based on differential modification of surface amino acids. Horse cytochrome c was adsorbed at low ionic strength (pH 7.0, 4.4 mM potassium phosphate) onto 10 microm diameter gold particles coated with HS(CH(2))(10)COOH SAMs. After in situ modification of lysyl groups by reductive Schiff-base methylation, the protein was desorbed, digested using trypsin, and the peptide mapped using LC/MS. Relative lysyl reactivities were ascertained by comparing the resulting peptide frequencies to control samples of solution cytochrome c modified to the same average extent. The least reactive lysines in adsorbed cytochrome c were found to be 13, 72, 73, 79, and 86-88, consistent with a contact region located up and to the left (Met-80 side) of the solvent-exposed heme edge (conventional front face view). The most reactive lysines were 39, 53, 55, and 60, located on the lower backside. The proposed orientation features a heme tilt angle of approximately 35-40 degrees with respect to the substrate surface normal. Factors that can complicate or distort data interpretation are discussed, and the generality of differential modification relative to existing in situ methods for protein orientation determination is also addressed. 相似文献
162.
The Grubbs' first and second generation catalysts were occluded into cross-linked slabs of polydimethylsiloxane with volumes from 1 mm3 to 1 cm3 by swelling the polymer with catalyst and methylene chloride. Methylene chloride was evaporated under vacuum to yield occluded catalysts where their solvent was polydimethylsiloxane. These occluded catalysts were reacted with alkenes dissolved in H2O or H2O/MeOH mixtures that diffused into the polydimethylsiloxane to react by ring-closing metathesis and cross metathesis. Control experiments revealed that the catalysts remained occluded and metathesis did not occur in the solvent. Occlusion of these catalysts allowed commercially available Grubbs' catalysts to be used with H2O as the solvent while isolating the H2O sensitive ruthenium methylidene from exposure to H2O. Functional group selective experiments were carried out where the polydimethylsiloxane was an "active" membrane to exclude salts. Polydimethylsiloxane is a hydrophobic polymer, so the deprotonated salt of diallylmalonic acid did not diffuse into it while a diallylether diffused into it and reacted by metathesis. Thus, by controlling the polarity of reagents their reactivity can be controlled owing to the properties of polydimethylsiloxane rather than those of the Grubbs' catalysts. Occlusion of catalysts in polydimethylsiloxane has been shown to add new selectivities to mature catalysts. 相似文献
163.
Intensity clamping and re-focusing of intense femtosecond laser pulses in nitrogen molecular gas 总被引:3,自引:0,他引:3
A. Becker N. Aközbek K. Vijayalakshmi E. Oral C.M. Bowden S.L. Chin 《Applied physics. B, Lasers and optics》2001,73(3):287-290
We present results of measurements of fluorescence spectra due to the interaction of a Ti:sapphire laser pulse with N2 molecules at different gas pressures and pulse energies. The analysis of the data together with the results of numerical
simulations, using a propagation model, reveal signatures of the phenomena of intensity clamping and of re-focusing of the
laser pulse at high gas pressure. The laser pulse energy for intensity clamping as a function of the gas pressure is determined.
Received: 21 May 2001 / Revised version: 10 July 2001 / Published online: 19 September 2001 相似文献
164.
Hutchison W. D. Chaplin D. H. Harker S. J. Bowden G. J. 《Hyperfine Interactions》2001,136(3-8):307-312
A NMRON study of magnetically ordered HoF3 using in-situ neutron activated 166m
Ho (I=7) isoelectronic probes in a spherical single crystal is presented. The optimal sensitivity to resonant change in the gamma-ray
anisotropy of the 810 keV daughter gamma-ray emission has been utilised to track the lowest nuclear Zeeman substate resonance
over an applied magnetic field range from 0.300 to 0.524 T, corresponding to the frequency range 1.56 to 1.78 GHz. The 2nd
lowest substate resonance has also been observed at 0.3 T leading to a value P/h=−32.9(14) MHz for the 166m
Ho quadrupolar splitting which is consistent with predictions of a dominant negative pseudo-quadrupole interaction in this
system. The Ho3+ electronic moment, in zero applied magnetic field, is projected to be 16% smaller than measured previously with neutron diffraction.
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献
165.
166.
Dr. Biao Jin Ying Chen Jinhui Tao Dr. Kacper J. Lachowski Mark E. Bowden Zihao Zhang Dr. Lilo D. Pozzo Nancy M. Washton Karl T. Mueller James J. De Yoreo 《Angewandte Chemie (International ed. in English)》2023,62(28):e202303770
Hierarchical nucleation pathways are ubiquitous in the synthesis of minerals and materials. In the case of zeolites and metal–organic frameworks, pre-organized multi-ion “secondary building units” (SBUs) have been proposed as fundamental building blocks. However, detailing the progress of multi-step reaction mechanisms from monomeric species to stable crystals and defining the structures of the SBUs remains an unmet challenge. Combining in situ nuclear magnetic resonance, small-angle X-ray scattering, and atomic force microscopy, we show that crystallization of the framework silicate, cyclosilicate hydrate, occurs through an assembly of cubic octameric Q38 polyanions formed through cross-linking and polymerization of smaller silicate monomers and other oligomers. These Q38 are stabilized by hydrogen bonds with surrounding H2O and tetramethylammonium ions (TMA+). When Q38 levels reach a threshold of ≈32 % of the total silicate species, nucleation occurs. Further growth proceeds through the incorporation of [(TMA)x(Q38)⋅n H2O](x−8) clathrate complexes into step edges on the crystals. 相似文献