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101.
We theoretically analyze the nonlinear phase shifts induced by cascaded chi((2)):chi((2)) processes in one-dimensional photonic bandgap structures. We find that the enhancement of the density of modes near the band edge, coupled with a suitable choice of relative phase mismatch, leads to a remarkable new effect: The relative phase shift of the fundamental field on transmission can be of the order of pi over a distance of 7mum , with input intensities of the order of only 10 MW/cm(2).  相似文献   
102.
103.
A new hexacyclic pyridoacridine alkaloid, nordehydrocyclodercitin (1), from an ascidian, Aplidium sp., cf. Aplidium cratiferum collected at Arab Reef, Great Barrier Reef, Australia is reported. Nordehydrocyclodercitin is structurally related to stellettamine (2) and cyclodercitin (3), which are sponge metabolites, and cycloshermilamine D (4) which was isolated from the marine tunicate Cystodytes violatinctus. The structure of nordehydrocyclodercitin was determined by interpretation of spectroscopic data, particularly those obtained from HMBC correlations, and by comparison with reported data for known related pyridoacridine alkaloids.  相似文献   
104.
This paper reports the first examples of poly(diaminosulfide)s that were synthesized by the reaction of a sulfur transfer reagent and several secondary diamines. The diaminosulfide group has the general structure of R(2)N-S-NR(2) and, although it has been used in the synthesis of small molecules, it has never been utilized in the synthesis of macromolecules until this report. A series of poly(diaminosulfide)s were synthesized at elevated temperatures, and the molecular weights of the polymers were as high as 12,400 g mol(-1) with conversions for the polymerization reaction up to 99%. The rate constants for the transamination reactions that lead to the polymers were measured in several solvents to provide an understanding the reaction conditions necessary to polymerize the monomers. The degradation of diaminosulfides were studied in D(2)O, C(6)D(6), CD(3)OD, CDCl(3), and DMSO-d(6)/D(2)O to demonstrate that they were very stable in organic solvents but degraded within hours under aqueous conditions. These results clearly demonstrated that diaminosulfides are very stable in organic solvents under ambient conditions. Poly(diaminosulfide)s have sufficient stabilities to be useful for many applications. The ability of these polymers to function as drug delivery vehicles were studied by the fabrication of nanoparticles of a water-insoluble poly(diaminosulfide) with a dye. The microparticles were readily absorbed into human embryonic 293 cells and possessed no measureable toxicity towards these same cells.  相似文献   
105.
Thimbles composed of polydicyclopentadiene retained Pd and phosphines used in Buchwald-Hartwig and Sonogashira coupling reactions but allowed the products to permeate. The products were isolated in high yields on the exteriors of the thimbles with no detectable contamination from phosphine and with Pd loadings as low as < 5.5 ppm.  相似文献   
106.
In situ liquid secondary ion mass spectrometry (SIMS) enabled by system for analysis at the liquid vacuum interface (SALVI) has proven to be a promising new tool to provide molecular information at solid–liquid and liquid–vacuum interfaces. However, the initial data showed that useful signals in positive ion spectra are too weak to be meaningful in most cases. In addition, it is difficult to obtain strong negative molecular ion signals when m/z>200. These two drawbacks have been the biggest obstacle towards practical use of this new analytical approach. In this study, we report that strong and reliable positive and negative molecular signals are achievable after optimizing the SIMS experimental conditions. Four model systems, including a 1,8-diazabicycloundec-7-ene (DBU)-base switchable ionic liquid, a live Shewanella oneidensis biofilm, a hydrated mammalian epithelia cell, and an electrolyte popularly used in Li ion batteries were studied. A signal enhancement of about two orders of magnitude was obtained in comparison with non-optimized conditions. Therefore, molecular ion signal intensity has become very acceptable for use of in situ liquid SIMS to study solid–liquid and liquid–vacuum interfaces.
Graphical Abstract ?
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107.
It is shown, both theoretically and experimentally, that during laser pulse filamentation in air an intense ultrashort third-harmonic pulse is generated forming a two-colored filament. The third-harmonic pulse maintains both its peak intensity and energy over distances much longer than the characteristic coherence length. We argue that this is due to a nonlinear phase-locking mechanism between the two pulses in the filament and is independent of the initial material wave-vector mismatch. A rich spatiotemporal propagation dynamics of the third-harmonic pulse is predicted. Potential applications of this phenomenon to other parametric processes are discussed.  相似文献   
108.
The stratification of two fluid phases, namely gas and liquid, within flow distribution devices, such as headers, that have side or bottom oriented fluid pipe connections, or discharges, has shown relevance to loss-of-coolant accidents in nuclear power plants. Under critical conditions the gas phase could entrain into the predominantly liquid discharge flow causing the fluid quality to be dramatically affected. This condition is referred to as the onset of gas entrainment (OGE) phenomenon and it occurs at a specific critical liquid height which changes with the Froude number. The liquid velocity field at the OGE is of importance, for example, to theorists who may find a semi-empirical approach to model this phenomenon. Stereoscopic particle image velocimetry (PIV) technique is an excellent candidate for non-intrusively investigating the velocity field. The liquid-phase velocity field was investigated for three discharge Froude numbers at the OGE. It was found that the stereoscopic PIV could be used to extract the velocity field experimentally, yet a high degree of error was found in the region closest to the discharge. The relative error was determined through conservation of mass by comparing the flow rate obtained with the PIV data to that obtained using a flow meter. In summary it was found that the number of image planes used, the resolution of the image planes, and consequently the number of vectors used to calculate the flow rate, all contributed a great deal to the relative error.  相似文献   
109.
This paper presents a comparison of some of our results on the polymerization of methacrylic acid, octadecyl methacrylate, zinc methacrylate, and barium methacrylate monohydrate in the solid state. Polymerization was initiated by cobalt-60 γ rays, both in-source and post-irradiation polymerization techniques being used. Electron spin resonance studies showed that the polymerization proceeded by a free radical mechanism in all cases. The initial radicals formed by irradiation at low temperatures added a first monomer unit about 100° below the temperature of long-chain polymerization. Some radical decay occurred in the early stages of polymerization. The rate of polymerization increased rapidly, approaching the melting point or other phase change in the monomer.  相似文献   
110.
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