Postsynthetic modifications (PSMs) of metal–organic frameworks (MOFs) play a crucial role in enhancing material performance through open metal site (OMS) functionalization or ligand exchange. However, a significant challenge persists in preserving open metal sites during ligand exchange, as these sites are inherently bound by incoming ligands. In this study, for the first time, we introduced alkoxides by exchanging bridging chloride in Ni2Cl2BTDD (BTDD=bis (1H-1,2,3,–triazolo [4,5-b],–[4′,5′-i]) dibenzo[1,4]dioxin) through PSM. Rietveld refinement of synchrotron X-ray diffraction data indicated that the alkoxide oxygen atom bridges Ni(II) centers while the OMSs of the MOF are preserved. Due to the synergy of the existing OMS and introduced functional group, the alkoxide-exchanged MOFs showed CO2 uptakes superior to the pristine MOF. Remarkably, the tert-butoxide-substituted Ni_T exhibited a nearly threefold and twofold increase in CO2 uptake compared to Ni2Cl2BTDD at 0.15 and 1 bar, respectively, as well as high water stability relative to the other exchanged frameworks. Furthermore, the Grand Canonical Monte Carlo simulations for Ni_T suggested that CO2 interacts with the OMS and the surrounding methyl groups of tert-butoxide groups, which is responsible for the enhanced CO2 capacity. This work provides a facile and unique synthetic strategy for realizing a desirable OMS-incorporating MOF platform through bridging ligand exchange. 相似文献
We present an experimental technique to determine the magnetic anisotropy of ferromagnetic nanowires. In the technique, the magnetization state is monitored by measuring the anisotropic magnetoresistance with rotating the external magnetic field. The measured magnetoresistance curves exhibit basically the same curves typically appeared in the torque magnetometric measurements, which are then readily analyzed based on the Stoner–Wohlfarth theory with a single fitting parameter – the magnetic anisotropy. By applying the present technique to Permalloy nanowires, it is shown that the shape anisotropy in real nanowires is significantly influenced by the edge roughness. 相似文献
Dictyostelium cells secrete the proteins AprA and CfaD. Cells lacking either AprA or CfaD proliferate faster than wild type, while AprA
or CfaD overexpressor cells proliferate slowly, indicating that AprA and CfaD are autocrine factors that repress proliferation.
CfaD interacts with AprA and requires the presence of AprA to slow proliferation. To determine if CfaD is necessary for the
ability of AprA to slow proliferation, whether AprA binds to cells, and if so whether the binding requires the presence of
CfaD, we examined the binding and effect on proliferation of recombinant AprA. 相似文献
We report domain reversal behavior in perpendicular ferromagnetic nanothin films investigated by means of a novel magneto-optical microscope magnetometer, capable of grabbing domain reversal patterns in real time under an applied field as well as simultaneous measurements of 8000 local hysteresis loops with 400-nm special resolution. Three contrasting domain reversal behaviors are found to exist: wall-motion dominant, dendritic-growth dominant, and nucleation dominant reversal. Quantitative analysis reveals that the contrasting reversal behavior is mainly caused by a sensitive change in wall-motion speed and that the reversal ratio of wall-motion speed over nucleation rate is a governing parameter for the contrasting domain reversal dynamics. The activation volumes of the wall-motion and nucleation processes are found generally unequal, and the inequality is closely related with the domain dynamics. The domain reversal pattern is truly coincident with submicron-scale local coercivity variation and local switching time of domain evolution is exponentially dependent on local coercivity governed by a thermal activation relaxation process. The observed domain reversal behavior could be well predicted by a Monte Carlo simulation of a micromagnetic model based on the uniaxial magnetic anisotropy of nanothin films. 相似文献
The noise power spectrum (NPS) is one of the most general methods for measuring the noise amplitude and the quality of an image acquired from a uniform radiation field. The purpose of this study was to compare different NPS methodologies by using megavoltage X-ray energies. The NPS evaluation methods in diagnostic radiation were applied to therapy using the International Electrotechnical Commission standard (IEC 62220-1). In order to measure the region of interest (ROI) of the NPS, we used the following five factors: the overlapping impact, the non-overlapping impact, the penumbra, the flatness and different ROI sizes. We used NPS from four different types of detectors, the CR-IP (computed radiography image plate: photo-stimulable phosphor screen), the CR-IP-lead (hexalon lead screen), the CR-IP-back [lanex TM fast back screen: {terbium-doped gadolinium oxysulfide granular phosphor screen (Gd2O2S:Tb,133 mg/cm2)} + 1-mm-thick copper plate and the CR-IP-front (lanex TM fast front screen). A Kodak 2000 RT photo-stimulable phosphor-based computed radiographic (CR) system showed that the normalized noise power spectrum (NNPS) curve gradually decreased, in compliance with increasing spatial resolution. In addition, each detector showed a different reactivity of the NPS to megavoltage. The results of multivariate analysis of variance (MANOVA) test (methods × detectors) revealed significant main effects of the methods [F(1, 4) = 53.543, P = 0.001 and of the detectors [F(1, 4) = 17.556, P = 0.001]. The present study revealed that various factors could be employed to produce megavoltage imaging (MVI) of the NPS and as a baseline standard for NPS control in MVI.
In this paper, we investigated the electrochemical and surface behavior of hydroxyapatite (HA)/Ti films on the nanotubular Ti-35Nb-xZr alloy. The Ti-35Nb-xZr ternary alloys with 3-10 wt.% Zr content were made by an arc melting method. The nanotubular oxide layers were developed on the Ti-35Nb-xZr alloys by an anodic oxidation method in 1 M H3PO4 electrolyte containing 0.8 wt% NaF at room temperature. The HA/Ti composite films on the nanotubular oxide surfaces were deposited by a magnetron sputtering method. Their surface characteristics were analyzed by field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS) and an X-ray diffractometer (XRD). The corrosion behavior of the specimens was examined through potentiodynamic and AC impedance tests in 0.9% NaCl solution. From the results, the Ti-35Nb-xZr alloys showed a solely β phase microstructure that resulted from the addition of Zr. The nanotubular structure formed with a diameter of about 200 nm, and the HA/Ti thin film was deposited on the nanotubular structure. The HA/Ti thin film-coated nanotubular Ti-35Nb-xZr alloys showed good corrosion resistance in 0.9% NaCl solution. 相似文献
A necessary and sufficient condition that a densely defined linear operator A in a sequentially complete locally convex space X be the infinitesimal generator of a quasi-equicontinuous C0-semigroup on X is that there exist a real number β ? 0 such that, for each λ > β, the resolvent (λI ? A)?1 exists and the family {(λ ? β)k(λI ? A)?k; λ > β, k = 0, 1, 2,…} is equicontinuous. In this case all resolvents (λI ? A)?1, λ > β, of the given operator A and all exponentials exp(tA), t ? 0, of the operator A belong to a Banach algebra which is a subspace of the space L(X) of all continuous linear operators on X, and, for each t ? 0 and for each x?X, one has limk → z (I ? k?1tA)?kx = exp(tA) x. A perturbation theorem for the infinitesimal generator of a quasi-equicontinuous C0-semigroup by an operator which is an element of is obtained. 相似文献
We study the action of composition operators on Sobolev spaces of analytic functions having fractional derivatives in some weighted Bergman space or Hardy space on the unit disk. Criteria for when such operators are bounded or compact are given. In particular, we find the precise range of orders of fractional derivatives for which all composition operators are bounded on such spaces. Sharp results about boundedness and compactness of a composition operator are also given when the inducing map is polygonal.