Supersonic radiatively cooled rotating flows and jets in the laboratory

The first laboratory astrophysics experiments to produce a radiatively cooled plasma jet with dynamically significant angular momentum are discussed. A new configuration of wire array z pinch, the twisted conical wire array, is used to produce convergent plasma flows each rotating about the central axis. Collision of the flows produces a standing shock and jet that each have supersonic azimuthal velocities. By varying the twist angle of the array, the rotation velocity of the system can be controlled, with jet rotation velocities reaching approximately 18% of the propagation velocity.     

The mechanism of the addition of tetrachloromethane to alkenes in the presence of [Cr(CO)3(η6-C10H8)]

The title reaction has been examined in detail and is shown to proceed via a non-chain catalysed mechanism involving free radical intermediates.     

The mechanism of the addition of tetrachloromethane to alkenes in the presence of [Cr(CO)3(η-C10H8)]

The title reaction has been examined in detail and is shown to proceed via a non-chain catalysed mechanism involving free radical intermediates.     

57Fe Mössbauer Spectroscopy Studies of Meteorites: Implications for Weathering Rates,Meteorite Flux,and Early Solar System Processes

Ordinary chondrite finds, terrestrial age dated using ¹⁴C analyses, from different meteorite accumulation sites, have been examined by Mössbauer spectroscopy to quantitatively determine terrestrial oxidation. We observe differences in weathering rates between sites, and also between different chondrite groups. A comparison of weathering over time, and its effect in eroding meteorites, together with the number and mass distribution of meteorites in each region, enables us to derive estimates of the number of meteorite falls over a given mass per year. Studies of how the oxygen isotopic composition of samples varies with weathering indicate that incipient alteration may occur without a pronounced isotopic effect, possibly due to weathering of silicates to topotactically oriented smectite confined spaces where the water volume is limited. This finding has profound implications for the use of oxygen isotopes as a tool in understanding water–rock interaction. It also may reconcile previously contradictory data regarding the nebular or asteroidal location of pre-terrestrial aqueous alteration. Finally, Mössbauer spectroscopy is also found to be a useful tool in determining mineral abundance in carbonaceous chondrites, where a fine-grained matrix makes traditional approaches inapplicable. Again, the results have implications for the modification of chondritic materials in the early solar system.     

Pion Interferometry of square root of (s(NN)) =130 GeV Au + Au collisions at RHIC

Two-pion correlation functions in Au+Au collisions at square root of [s(NN)] = 130 GeV have been measured by the STAR (solenoidal tracker at RHIC) detector. The source size extracted by fitting the correlations grows with event multiplicity and decreases with transverse momentum. Anomalously large sizes or emission durations, which have been suggested as signals of quark-gluon plasma formation and rehadronization, are not observed. The Hanbury Brown-Twiss parameters display a weak energy dependence over a broad range in square root of [s(NN)].     

Direct observation of a bulklike spin moment at the Fe/GaAs(100)-4x6 interface

We have used x-ray magnetic circular dichroism, which offers a unique capability to give element specific information at submonolayer sensitivity, to determine the spin and orbital magnetic moments at the Fe/GaAs(100) interface. The wedge samples, grown by molecular beam epitaxy at room temperature, consisted of 0.25-1 monolayer (ML) Fe on GaAs(100)-4x6 capped with 9 ML Co and have shown Fe spin moments of (1.84-1.96)micro(B) and a large orbital enhancement. Our results demonstrate unambiguously that the Fe/GaAs(100)-4x6 interface is ferromagnetic with a bulklike spin moment, which is highly promising for spintronics applications.     

Multistrange baryon production in Au-Au collisions at sqrt[s(NN)]=130 GeV

The transverse mass spectra and midrapidity yields for Xis and Omegas are presented. For the 10% most central collisions, the (-)Xi(+)/h(-) ratio increases from the Super Proton Synchrotron to the Relativistic Heavy Ion Collider energies while the Xi(-)/h(-) stays approximately constant. A hydrodynamically inspired model fit to the Xi spectra, which assumes a thermalized source, seems to indicate that these multistrange particles experience a significant transverse flow effect, but are emitted when the system is hotter and the flow is smaller than values obtained from a combined fit to pi, K, p, and Lambdas.     

Methodology for regioselective synthesis of substituted pyridines via intramolecular oximino malonate hetero Diels-Alder reactions

[structure] Various substituted pyridines can be prepared regioselectively by a sequence involving an intramolecular thermal or high-pressure Diels-Alder cycloaddition of an oximino malonate dienophile tethered to a dienic carboxylic acid, followed by mild aromatization of the resulting cycloadduct with cesium carbonate in DMF at room temperature.     

Effect of core-corona plasma structure on seeding of instabilities in wire array Z pinches

We present the first measurements by x-ray radiography of the development of instabilities during the implosion phase of wire array Z pinches. The seeding of perturbations on the dense core of each wire is provided by nonuniform sweeping of the low-density coronal plasma from the cores by the global JxB force. The spatial scale of these perturbations ( approximately 0.5 mm for Al and approximately 0.25 mm for W) is determined by the size of the wire cores ( approximately 0.25 mm for Al and approximately 0.1 mm for W). A qualitative change in implosion dynamics, with transition to 0D-like trajectory, was observed in Al arrays when the ratio of interwire gap to wire core size was decreased to approximately 3.     

Two different modes of nested wire array Z-pinch implosions

Two different modes of nested wire array implosion driven by a 1-MA, 240-ns current pulse were observed, determined by the fraction of total current induced in the inner array. Penetration by the outer array through the inner with switching of current occurred if current in the inner array was initially suppressed. Simultaneous implosion of arrays with apparent compression of magnetic flux between the arrays was observed if approximately 20% of the current was in the inner array. In both cases the x-ray pulse rise time of approximately 10 ns (for 260-ns implosion time) was considerably smaller than for a single array.