全文获取类型
收费全文 | 147篇 |
免费 | 6篇 |
专业分类
化学 | 106篇 |
力学 | 2篇 |
数学 | 8篇 |
物理学 | 37篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 1篇 |
2019年 | 3篇 |
2018年 | 3篇 |
2017年 | 2篇 |
2016年 | 1篇 |
2015年 | 5篇 |
2014年 | 5篇 |
2013年 | 8篇 |
2012年 | 5篇 |
2011年 | 6篇 |
2010年 | 4篇 |
2009年 | 6篇 |
2008年 | 7篇 |
2007年 | 5篇 |
2006年 | 13篇 |
2005年 | 15篇 |
2004年 | 13篇 |
2003年 | 3篇 |
2002年 | 5篇 |
2001年 | 1篇 |
1999年 | 2篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1993年 | 4篇 |
1992年 | 5篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 6篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有153条查询结果,搜索用时 15 毫秒
91.
The symmetric marching technique developed in [1,2] has been extended to the elliptic equations with variable coefficients involving mixed partial derivatives. The restricted class of such equations of the form uxx+2B(x, y)uxy+c(x,y)uyy=0 have been considered. Numerical results of model problems solved are presented. 相似文献
92.
Adams J Adler C Aggarwal MM Ahammed Z Amonett J Anderson BD Arkhipkin D Averichev GS Bai Y Balewski J Barannikova O Barnby LS Baudot J Bekele S Belaga VV Bellwied R Berger J Bezverkhny BI Bharadwaj S Bhatia VS Bichsel H Bland LC Blyth CO Bonner BE Botje M Boucham A Brandin A Bravar A Cadman RV Cai XZ Caines H Calderón de la Barca Sánchez M Carroll J Castillo J Cebra D Chaloupka P Chattopdhyay S Chen HF Chen Y Cheng J Cherney M Chikanian A Christie W Coffin JP Cormier TM Cramer JG Crawford HJ 《Physical review letters》2004,92(18):182301
The transverse mass spectra and midrapidity yields for Xis and Omegas are presented. For the 10% most central collisions, the (-)Xi(+)/h(-) ratio increases from the Super Proton Synchrotron to the Relativistic Heavy Ion Collider energies while the Xi(-)/h(-) stays approximately constant. A hydrodynamically inspired model fit to the Xi spectra, which assumes a thermalized source, seems to indicate that these multistrange particles experience a significant transverse flow effect, but are emitted when the system is hotter and the flow is smaller than values obtained from a combined fit to pi, K, p, and Lambdas. 相似文献
93.
Ce(NO3)3.6H2O or Pr(NO3)3.6H2O and pyridine-2,6-dicarboxylic acid form a linear coordination polymeric structure under hydrothermal conditions. Hexameric water clusters join these linear chains through bonding to the metal ions. Other coordinated water and the carboxylate oxygen form an intricate array of hydrogen bonding resulting in a 3D network where each metal ion shows 9-coordination with an approximate D3 symmetry. Dimeric water clusters are also located in the void spaces. In the structure containing Pr(III), the water dimers are hydrogen-bonded to the hexamers, whereas in the Ce(III) structure, the dimers and the hexamers are far apart. 相似文献
94.
Field amplified sample stacking (FASS) is used to increase sample concentrations in electrokinetic flows. The technique uses
conductivity gradients to establish a non-uniform electric field that accumulates ions within a conductivity gradient, and
can be readily integrated with capillary electrophoresis. Conductivity gradients also cause gradients in near-wall electroosmotic
flow velocities. These velocity gradients generate internal pressure gradients that drive secondary, dispersive flows. This
dispersion leads to a significant reduction in the efficiency of sample stacking. This paper presents an experimental investigation
of internally generated pressure gradients in FASS using micron-resolution particle image velocimetry (μPIV). We measure velocity
fields of particles seeded into an electrokinetic FASS flow field in a glass microchannel with a single buffer–buffer interface. μPIV
allows for the direct quantification of local, instantaneous pressure gradients by analyzing the curvature of velocity profiles.
Measurements show internally generated pressure-driven velocities on the order of 1mm/s for a typical applied electric field
of 100 V/cm and a conductivity ratio of 10. A one-dimensional (1D) analytical model for the temporal development of the internal
pressure gradient generation is proposed which is useful in estimating general trends in flow dynamics.
相似文献
Juan G. SantiagoEmail: |
95.
Vivek S. Bharadwaj Nathaniel M. Eagan Nicholas M. Wang Prof. Matthew W. Liberatore Prof. C. Mark Maupin 《Chemphyschem》2015,16(13):2810-2817
Despite the importance of fatty‐acid methyl esters (FAMEs) as key components of various green solvents, detergents, plasticizers, and biodiesels, our understanding of these systems at the molecular level is limited. An enhanced molecular‐level perspective of FAMEs will enable a detailed analysis of the polymorph and crystallization phenomena that adversely impact flow properties at low temperatures. Presented here, is the parameterization and validation of a charge‐modified generalized amber force field (GAFF) for eight common FAMEs and two representative biodiesel mixtures. Our simulations accurately reproduce available experimental data (e.g. densities and self‐diffusivity coefficients) and their trends, with respect to temperature and degree of unsaturation. Structural analyses from our simulations provide a more detailed picture of liquid‐phase molecular ordering in FAMEs and confirm recent experimental hypotheses. This study provides a firm foundation to initiate further studies into the mechanisms that drive crystallization phenomena at the molecular level. 相似文献
96.
Crystal structure of the compound L·4H2O (L = aza cryptand) and its supramolecular assembly via H-bonding through water molecules are described here. The compound crystallizes in the cubic space group Pa3 (no. 205) with the following lattice parameters: a=b=c=19.023(2) Å, V=6883.9(4) Å3, Z=8, R 1=0.0592, wR 2 = 0.1572, S=0.964. 相似文献
97.
Adams J Aggarwal MM Ahammed Z Amonett J Anderson BD Arkhipkin D Averichev GS Badyal SK Bai Y Balewski J Barannikova O Barnby LS Baudot J Bekele S Belaga VV Bellwied R Berger J Bezverkhny BI Bharadwaj S Bhasin A Bhati AK Bhatia VS Bichsel H Billmeier A Bland LC Blyth CO Bonner BE Botje M Boucham A Brandin AV Bravar A Bystersky M Cadman RV Cai XZ Caines H Calderón de la Barca Sánchez M Castillo J Cebra D Chajecki Z Chaloupka P Chattopadhyay S Chen HF Chen Y Cheng J Cherney M Chikanian A 《Physical review letters》2005,94(6):062301
Midrapidity open charm spectra from direct reconstruction of D0(D0)-->K-/+pi+/- in d+Au collisions and indirect electron-positron measurements via charm semileptonic decays in p+p and d+Au collisions at squareroot[sNN]=200 GeV are reported. The D0(D0) spectrum covers a transverse momentum (pT) range of 0.1相似文献
98.
Ultraparamagnetic Cells Formed through Intracellular Oxidation and Chelation of Paramagnetic Iron 下载免费PDF全文
Pradeep Ramesh Dr. Son‐Jong Hwang Hunter C. Davis Audrey Lee‐Gosselin Vivek Bharadwaj Max A. English Jenny Sheng Vasant Iyer Prof. Mikhail G. Shapiro 《Angewandte Chemie (International ed. in English)》2018,57(38):12385-12389
Making cells magnetic is a long‐standing goal of chemical biology, aiming to enable the separation of cells from complex biological samples and their visualization in vivo using magnetic resonance imaging (MRI). Previous efforts towards this goal, focused on engineering cells to biomineralize superparamagnetic or ferromagnetic iron oxides, have been largely unsuccessful due to the stringent required chemical conditions. Here, we introduce an alternative approach to making cells magnetic, focused on biochemically maximizing cellular paramagnetism. We show that a novel genetic construct combining the functions of ferroxidation and iron chelation enables engineered bacterial cells to accumulate iron in “ultraparamagnetic” macromolecular complexes, allowing these cells to be trapped with magnetic fields and imaged with MRI in vitro and in vivo. We characterize the properties of these cells and complexes using magnetometry, nuclear magnetic resonance, biochemical assays, and computational modeling to elucidate the unique mechanisms and capabilities of this paramagnetic concept. 相似文献
99.
A pH-induced differential derivative spectrophotometric procedure has been developed for the simultaneous determination of Phenobarbitone (PBT) and Phenytoin sodium (DPH Na) in tablet preparations. The method comprized of measurement of difference absorptivities derivatized in second order (DeltaD(2)) of a tablet extract in 0.01 N NaOH relative to that of an equimolar solution in 0.01 N HCl at wavelengths of 244.8 and 252.8 nm respectively. The presence of identical zero-crossing points for pure drug and tablet extract solutions established the non-interference of the excipients in the absorption at these wavelengths. The compliance of Beer's law was adhered over a concentration range of 7.5-25 mug ml(-1) for both PBT and DPH. 相似文献
100.
Bhadra S Appel JA Bartlett DF Denby BH Biel J Bintinger D Bharadwaj VK Blodgett DE Bracker SB Bronstein J Daum C Duncan AL Eisner AM Elliott JR Estabrooks P Hartner GF Kalbfleisch GR Kennett RG Kumar BR Losty MJ Lu A Luste GJ Mantsch PM Martin JF Morrison RJ Nash T Nauenberg U Pinfold J Robertson M Schmidke W Shahbazian KK Sheperd RA Sliwa K Sokoloff MD Spalding WJ Stacey J Stanfield KC Streetman M Summers DJ Willis SE Witherell MS Yellin SJ Zorn CJ 《Physical review letters》1985,55(25):2749-2751