Probing individual localization centers in an InGaN/GaN quantum well

Photoluminescence (PL) spectroscopy with subwavelength lateral resolution has been employed to probe individual localization centers in a thin InGaN/GaN quantum well. Spectrally narrow emission lines with a linewidth as small as 0.8 meV can be resolved, originating from the recombination of an electron-hole pair occupying a single localized state. Surprisingly, the individual emission lines show a pronounced blueshift when raising the temperature, while virtually no energy shift occurs for increasing excitation density. These findings are in remarkable contrast to the behavior usually found in macro-PL measurements and give a fundamental new insight into the recombination process in semiconductor nanostructures in the presence of localization and strong internal electric fields. We find clear indications for a biexciton state with a negative binding energy of about -5+/-0.7 meV.     

STEM-study of 1.3 μm InAs/InGaAs quantum dot structures

We investigated InAs-Dots-in-a-well structures emitting near 1.3 μm by bright field and Z-contrast mode in a scanning transmission electron microscope. The chemically sensitive Z-contrast mode is found to give direct information on the actual position of the InAs-Dots inside the embedding well, while the bright field mode monitors the strain fields. Comparing a series of structures, we found that the most symmetric design is realized by an nominally asymmetric growth. These symmetric structures exhibit the best performance with respect to photoluminescence spectra and laser threshold current density.     

On the reaction mechanism of adduct formation in LOV domains of the plant blue-light receptor phototropin

The blue-light sensitive photoreceptor, phototropin, is a flavoprotein which regulates the phototropism response of higher plants. The photoinduced triplet state and the photoreactivity of the flavin-mononucleotide (FMN) cofactor in two LOV domains of Avena sativa, Adiantum capillus-veneris, and Chlamydomonas reinhardtii phototropin have been studied by time-resolved electron paramagnetic resonance (EPR) and UV-vis spectroscopy at low temperatures (T < or = 80 K). Differences in the electronic structure of the FMN as reflected by altered zero-field splitting parameters of the triplet state could be correlated with changes in the amino acid composition of the binding pocket in wild-type LOV1 and LOV2 as well as in mutant LOV domains. Even at cryogenic temperatures, time-resolved EPR experiments indicate photoreactivity of the wild-type LOV domains, which was further characterized by UV-vis spectroscopy. Wild-type LOV1 and LOV2 were found to form an adduct between the FMN cofactor and the functional cysteine with a yield of 22% and 68%, respectively. The absorption maximum of the low-temperature photoproduct of wild-type LOV2 is red-shifted by about 15 nm as compared with the FMN C(4a)-cysteinyl adduct formed at room temperature. In light of these observations, we discuss a radical-pair reaction mechanism for the primary photoreaction in LOV domains.     

AKD-Modification of bacterial cellulose aerogels in supercritical CO2

Different approaches towards hydrophobic modification of bacterial cellulose aerogels with the alkyl ketene dimer (AKD) reagent are presented. If AKD modification was performed in supercritical CO₂, an unexpectedly high degree of loading was observed. About 15 % of the AKD was bound covalently to the cellulose matrix, while the other part consisted of re-extractable AKD-carbonate oligomers, which are novel chemical structures described for the first time. These oligomers contain up to six AKD and CO₂ moieties linked by enolcarbonate structures. The humidity uptake from environments with different relative humidity by samples equipped with up to 30 % AKD is strongly reduced, as expected due to the hydrophobization effect. Samples above 30 % AKD, and especially at very high loading between 100 and 250 %, showed the peculiar effect of increased humidity uptake which even exceeded the value of unmodified bacterial cellulose aerogels.     

Separation of polychlorodibenzo-p-dioxins and-dibenzofurans on the new polar stationary phase DB DIOXIN

Summary A complete assignment of the polychlorodibenz-p-dioxins (CL_xDD) and polychlorodibenzofurans (Cl_xDF) (x=4–8) separated on the new polar polysiloxane phase which contains 44% methyl, 28% phenyl, 20% cyanopropyl and 8% polyoxyethylene (Carbowax) groups (DB DIOXIN) is presented.     

Excitation of high-spin unnatural parity states in 208Pb from the (p,p′) reaction at 135 MeV

Differential cross sections for the excitation of states at 6.42, 6.73 and 7.04 MeV in ²⁰⁸Pb by 135 MeV protons are reported. Both the excitation energies and the backward peaked angular distributions observed in this experiment and in a recent (e, e′) experiment strongly suggest that these states are predominantly one-particle-one-hole excitations with J^π = 12^?, 14^? and 12^?, respectively. The present (p, p′) data are interpreted using a distorted wave impluse approximation and the effect of configuration mixing between the two 12^? states is investigated.     

Chromophores from hexeneuronic acids (HexA): synthesis of model compounds and primary degradation intermediates

Hexeneuronic acid (HexA) is formed under pulping conditions from 4-O-methyl-glucuronic acid residues in xylans by methanol elimination. It is usually removed by an acidic washing treatment (A-stage) within the pulp bleaching sequence. Hexeneuronic acid has long been recognized as a source of color generation in pulps, but the chemical structure of the actual chromophoric compounds remained elusive. We report the synthesis of isotopically (¹³C) labeled HexA model units carrying a label at any of the six carbon atoms. Confirming pertinent literature accounts, it is shown that HexA forms three primary degradation intermediates, 2-furancarboxylic acid, 5-formyl-2-furancarboxylic acid, and formic acid, under mildly acidic conditions, and their formation mechanism is discussed. 2-Furancarboxylic acid is demonstrated to be deformylation product of 5-formyl-2-furancarboxylic acid. The three primary intermediates are colorless and do not represent chromophores themselves. Their mixture, upon thermal or acidic treatment, gives rise to the same chromophores that are also directly formed from HexA.