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91.
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94.
Velislava A Ignatova Sven Van Den Berghe Steven Van Dyck Vladimir N Popok 《Microscopy and microanalysis》2006,12(5):432-437
The oxide scales of AISI 304 formed in boric acid solutions at 300 degrees C and pH = 4.5 have been studied using X-ray photoelectron spectroscopy (XPS) depth profiling. The present focus is depth profile quantification both in depth and chemical composition on a molecular level. The roughness of the samples is studied by atomic force microscopy before and after sputtering, and the erosion rate is determined by measuring the crater depth with a surface profilometer and vertical scanning interferometry. The resulting roughness (20-30 nm), being an order of magnitude lower than the crater depth (0.2-0.5 microm), allows layer-by-layer profiling, although the ion-induced effects result in an uncertainty of the depth calibration of a factor of 2. The XPS spectrum deconvolution and data evaluation applying target factor analysis allows chemical speciation on a molecular level. The elemental distribution as a function of the sputtering time is obtained, and the formation of two layers is observed-one hydroxide (mainly iron-nickel based) on top and a second one deeper, mainly consisting of iron-chromium oxides. 相似文献
95.
A. Ferreira da Silva I. Pepe S.A. Tomás W.M. de Azevedo R. Ahuja 《Applied Surface Science》2006,252(15):5365-5367
In this paper we present spectroscopic properties of doped and undoped titanium dioxide (TiO2) as nanofilms prepared by the sol-gel process with rhodamine 6G doping and studied by photoacoustic absorption, excitation and emission spectroscopy. The absorption spectra of TiO2 thin films doped with rhodamine 6G at very low concentration during their preparation show two absorption bands, one at 2.3 eV attributed to molecular dimmer formation, which is responsible for the fluorescence quenching of the sample and the other at 3.0 eV attributed to TiO2 absorption, which subsequently yields a strong emission band at 600 nm. The electronic band structure and optical properties of the rutile phase of TiO2 are calculated employing a fully relativistic, full-potential, linearized, augmented plane-wave (FPLAPW) method within the local density approximation (LDA). Comparison of this calculation with experimental data for TiO2 films prepared for undoped sol-gels and by sputtering is performed. 相似文献
96.
Summary High-purity indium was analysed by spark source mass spectrometry, using electrical and photoplate detection. For the calibration of the differences in elemental sensitivity, a standard sample was prepared in which 10 impurities were determined by graphite furnace atomic absorption spectrometry. In this way accuracies of less than 40% were obtained for relatively homogeneous elements at ppm and sub-ppm level. About 40 elements could be determined with detection limits of 10 to 30 ppb. Two pattern recognition methods, principal component analysis and clustering analysis, were applied to obtain information on trace element distribution, which indicated that a number of elements were strongly spatially correlated in the analysed sample.
On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China 相似文献
Chemische Analyse und Verteilungsbestimmung von Spurenelementen in Indium-Matrix durch Funkenquellen-Massenspektrometrie
On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China 相似文献
97.
Eliza P. de Jager 《Topology and its Applications》2007,154(10):2117-2126
We show that the infimum of any family of proximally symmetric quasi-uniformities is proximally symmetric, while the supremum of two proximally symmetric quasi-uniformities need not be proximally symmetric. On the other hand, the supremum of any family of transitive quasi-uniformities is transitive, while there are transitive quasi-uniformities whose infimum with their conjugate quasi-uniformity is not transitive. Moreover we present two examples that show that neither the supremum topology nor the infimum topology of two transitive topologies need be transitive. Finally, we prove that several operations one can perform on and between quasi-uniformities preserve the property of having a complement. 相似文献
98.
G.M. Ingo P. Plescia E. Angelini C. Riccucci T. de Caro 《Applied Physics A: Materials Science & Processing》2006,83(4):611-615
The surface microchemical structure of high tin leaded bronze Roman mirrors has been studied by means of scanning electron microscopy combined with energy dispersive spectrometry (SEM-EDS), X-ray diffraction (XRD) and optical microscopy (OM) techniques. The results allowed understanding of the origin of their high chemical stability and silvery-lustrous appearance. Indeed, some areas of the selected Roman mirrors are still characterised by a highly reflective and silver coloured surface even though they have been buried in the soil for about 2000 years. The micro-chemical results obtained from these areas have revealed that the mirror surface was tin enriched via inverse-segregation phenomenon by tailoring the cooling parameters. Furthermore, the presence of tin could be likely enhanced via cycles of oxidation and selective copper corrosion processes, thus resulting in a tin surface enrichment as a semi-transparent amorphous-like tin oxide (SnO2) film, as well as a copper depletion at the outer surfaces. 相似文献
99.
A. Craig W. H. Jacobson A. Meyer N. Welwart A. Seuthe H. N. Marr B. S. Evans G. E. F. Lundell J. A. Scherrer E. Stelling F. J. Mück A. Kling A. Lassieur L. Bertiaux C. C. Bissett P. de Pauw J. Heslinga A. Bartsch R. E. Lee W. H. Fegeley F. H. Reichel und E. Saz 《Fresenius' Journal of Analytical Chemistry》1927,71(1-2):83-90
Ohne Zusammenfassung 相似文献
100.
We study a class of shape optimization problems for semi-linear elliptic equations with Dirichlet boundary conditions in smooth
domains in ℝ2. A part of the boundary of the domain is variable as the graph of a smooth function. The problem is equivalently reformulated
on a fixed domain. Continuity of the solution to the state equation with respect to domain variations is shown. This is used
to obtain differentiability in the general case, and moreover a useful formula for the gradient of the cost functional in
the case where the principal part of the differential operator is the Laplacian.
Online publication 23 January 2004. 相似文献