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31.
Iraj Mohammadpoor-Baltork Majid Moghadam Shahram TangestaninejadValiollah Mirkhani Arsalan Mirjafari 《Polyhedron》2008
A wide variety of primary and secondary alcohols were efficiently converted to their corresponding methoxymethyl (MOM) and ethoxymethyl (EOM) ethers in the presence of catalytic amounts of supported H3PW12O40 on silica gel and zirconia at room temperature and under microwave irradiation at solvent-free conditions, whereas, phenols and tertiary alcohols remained intact under the same reaction conditions. Deprotection of these ethers to their parent alcohols was also achieved using these heterogeneous catalysts in ethanol, as a green solvent, under reflux conditions and microwave irradiation. Selective deprotection of primary and secondary MOM- and EOM-ethers in the presence of phenolic and tertiary ones, methyl and benzyl ethers, esters and trimethylsilyl ethers was achieved by these reagent systems. The present methodology offers several advantages such as short reaction times, high yields, simple procedure, heterogeneous reaction conditions, selectivity, non-toxicity and reusability of the catalysts. 相似文献
32.
Basit Muhammad Abdul Tariq Zeeshan Zahid Saira Khan Sheheryar Siddiqui Farrukh Arsalan Khan Muhammad Farooq Ali Gohar Park Tae Joo 《Journal of Cluster Science》2022,33(6):2443-2454
Journal of Cluster Science - Successive ionic layer adsorption and reaction (SILAR) process has been diversely used for deposition of various metal chalcogenides. SnS is one of them. Owing to the... 相似文献
33.
Employing acoustic emission sensors for detection of partial discharge, PD, introduces many advantages. Besides easy installation and replacement, they are non-invasive and immune to electromagnetic noise and interference and their sensitivity does not vary with object capacitance. For PD allocating utilizing AE sensors, distance calculations are based on the arrival time of acoustic waves to the sensors. Considering structure-borne waves of higher speed, the peaks of some of indirect path AE signals with significant contribution are mistakenly considered as peaks of direct path AE signals. Furthermore, the acoustic signals are propagating through certain parts of the transformer, such as the windings, and this complicates the partial discharge detection and allocation. These would imply an incorrect distance between the source and sensor. A method based on a heuristic algorithm has been proposed which considering all possible indirect paths with the relevant propagation times and all the barriers on the travel path of acoustic signal, calculates the more precise arrival times to sensors. A test chamber has been utilized and artificial PD signals are produced at various points. Output results of algorithm have been compared with results of classic method. It has been shown that proposed method significantly reduces the positioning errors. 相似文献
34.
Muhammad Arsalan Ghausi Dr. Jiafang Xie Prof. Qiaohong Li Xueyuan Wang Rui Yang Prof. Maoxiang Wu Prof. Yaobing Wang Prof. Liming Dai 《Angewandte Chemie (International ed. in English)》2018,57(40):13135-13139
Photo/electrochemical CO2 splitting is impeded by the low cost‐effective catalysts for key reactions: CO2 reduction (CDRR) and water oxidation. A porous silicon and nitrogen co‐doped carbon (SiNC) nanomaterial by a facile pyrolyzation was developed as a metal‐free bifunctional electrocatalyst. CO2‐to‐CO and oxygen evolution (OER) partial current density under neutral conditions were enhanced by two orders of magnitude in the Tafel regime on SiNC relative to single‐doped comparisons beyond their specific area gap. The photovoltaic‐driven CO2 splitting device with SiNC electrodes imitating photosynthesis yielded an overall solar‐to‐chemical efficiency of advanced 12.5 % (by multiplying energy efficiency of CO2 splitting cell and photovoltaic device) at only 650 mV overpotential. Mechanism studies suggested the elastic electron structure of ?Si(O)?C?N? unit in SiNC as the highly active site for CDRR and OER simultaneously by lowering the free energy of CDRR and OER intermediates adsorption. 相似文献
35.
Arsalan Wares 《International Journal of Mathematical Education in Science & Technology》2013,44(6):814-819
This note describes two conjectures pertaining to repeated partitioning of an arbitrary triangle. The first conjecture turns out to be true, and hence gives rise to a new, more general, conjecture that is also addressed in this article. Both conjectures can be explored in a dynamic geometry environment. The proofs to the conjectures addressed in this article require knowledge of high school Euclidean geometry. 相似文献
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Arsalan Wares 《International Journal of Mathematical Education in Science & Technology》2018,49(1):153-159
The purpose of this paper is to provide examples of ‘non-traditional’ proof-related activities that can explored in a dynamic geometry environment by university and high school students of mathematics. These propositions were encountered in the dynamic geometry environment. The author believes that teachers can ask their students to construct proofs for these propositions. 相似文献
38.
Svetlana V. Martynovskaya Arsalan B. Budaev Igor A. Ushakov Tatyana N. Borodina Andrey V. Ivanov 《Molecules (Basel, Switzerland)》2022,27(8)
This article shows that two extremely important families of fused heterocyclic assemblies, namely 6-methylbenzo[4,5]imidazo[1,2-a]pyrrolo[2,1-c]pyrazine and 5a-methyl-5a,6-dihydro-5H,12H-benzo[4,5]imidazo[1,2-a]pyrrolo[1,2-d]pyrazine, can be synthesized from only two available building blocks (N-allenylpyrrole-2-carbaldehyde and o-phenylenediamine) by controlling only one reaction parameter (water content of the medium). It should be emphasized that the latter class of compounds (with an a/d arrangement) is previously unknown. If the allene group is introduced not into the starting compound, but during the reaction (in superbase media), a heterocyclic ensemble, 5-methylbenzo[4,5]imidazo[1,2-a]pyrrolo[2,1-c]pyrazines, with a different position of the methyl group is formed. 相似文献
39.
Arsalan Azimian Fereydani Zoha Azizi 《Journal of Thermal Analysis and Calorimetry》2018,133(2):945-950
The droplet flow regime in microchannels can increase the mass transfer and chemical reactions considerably. In this work, the mass transfer of immiscible fluids of water as the solvent and butyl acetate containing 5 vol% of acetic acid as the feed is experimentally studied in a vertical flow inside a microchannel with the inner diameter of 8 mm. Effect of total flow velocity, Re number and volumetric flux ratio of two phases (Qaq/Qor) on the extraction fraction of acetic acid, mass transfer coefficient and droplet size were investigated. Based on the experiments, increasing the flux ratio can shift the flow regime from the plug to the droplet. Compared to the plug flow, the extraction fraction increased by 2–3 times in the droplet regime, depending on the total velocity, while the average diameter of the droplets decreased. Moreover, with the increase in the total velocity, the extraction fraction is reduced by 22%. However, in the case of the plug flow, the extraction fraction does not change appreciably with the increase in the total flow velocity. The mass transfer coefficient was found to increase monotonously with increasing Re number and an enhancement of 133% was achieved in the droplet flow regime. 相似文献
40.
Arsalan Mirjafari Majid Moghadam Shahram Tangestaninejad Valiollah Mirkhani Ahmad Reza Khosropour 《Tetrahedron letters》2010,51(25):3274-728
The Lewis acid room temperature ionic liquid, [bmim][InCl4], was found to be an efficient and green catalyst for the highly chemoselective and one-pot conversion of MOM- or EOM-ethers into their corresponding nitriles, bromides, and iodides under microwave irradiation. The procedures are simple, rapid, and high yielding. The catalyst exhibited a remarkable reactivity and is reusable. 相似文献