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31.
Stephan Weinbruch Michael Wentzel Manfred Kluckner Peter Hoffmann Hugo M. Ortner 《Mikrochimica acta》1997,125(1-4):137-141
In this paper procedures for the characterization of individual aerosol particles by element mapping in the electron microprobe are presented. The number, size and qualitative chemical composition of particles is derived from a combination of secondary or backscattered electron images and element distribution maps. Accuracy of the size distribution and reliability of the qualitative analysis procedure were checked with silicate samples. In order to obtain a semi-quantitative estimate of the chemical composition of individual particles the count rates taken from element distribution maps are corrected for matrix and geometric effects using particle ZAF procedures.Dedicated to Professor Dr. rer. nat. Dr. h.c. Hubertus Nickel on the occasion of his 65th birthday 相似文献
32.
Hugo M. Ortner 《Fresenius' Journal of Analytical Chemistry》1992,343(11):825-826
Conclusion Analytical Chemistry, as we have seen, is quite an established science but also a very vivid and young one. Its boundaries have always been and will be at the very frontiers of natural science: we are approaching the detection of single atoms as well as the analysis of matter at the very fringes of our universe. Analytical Chemistry is essential for the development of taylor-made high-tech materials and equally for the evolution of our knowledge about the toxicity of elements and compounds. It needs specialists with a profound insight in certain fields, for methods development or the handling of very complex instrumentation as e.g. a high resolution secondary ion mass spectrometer. But it also needs allrounders with a broad view not only of the capability of Analytical Chemistry as a whole but with an understanding for the complexity of modern social and economic structures. Frequently new ideas, new concepts and progress are forming on the seams between disciplines, on the grain boundaries of scientific fields too often kept strictly separated from each other. Analytical Chemistry is certainly a discipline which is predestinated for scientific communication collaborating with practically all fields of natural science as well as politics and economics.As a branch of natural science it is neutral in its moral value and therefore needs responsible and courageous analysts to use it for the benefit of mankind. 相似文献
33.
The defect rock-salt type materials Zr1?xS, Sc1?xS, and Lu1?xS have been shown to exhibit a complex variety of ordered superstructures. These superstructures are reviewed within the context of Landau's theory of symmetry and phase transitions, and it is concluded that there is a significant similarity in the transitions when they are considered from the point of view of reciprocal space. 相似文献
34.
Summary A model of the mechanism for recognition of the D1 receptor has been developed. Conformational analysis for 10 agonists from diverse chemical families was carried out as a first step toward the characterization of the bioactive form. First, maximum structural overlap of the features common to all ligands allowed a simple identification of the candidate bioactive form for each ligand. At a second level of characterization, steric and electronic properties were computed for all accessible structures to analyze those properties that may modulate receptor recognition. 相似文献
35.
A number of polyfunctionalized cis-bicycio ¦3.3.0¦octanes have been synthesized starting from the tricyclic key intermediate which was obtained by the intramolecular cyclopropanation reaction of the diazo keto ester . Selected stereocontrolled transformations of using nucleophiles and electrophiles have been studied for the preparation of the title compounds. 相似文献
36.
Hugo F. Franzen Mirtha X. Umaña J.R. McCreary R.J. Thorn 《Journal of solid state chemistry》1976,18(4):363-368
The first-row transition-metal monosulfides and alkaline-earth chalcogenides were studied by means of X-ray photoelectron spectroscopy. It is shown that the bonding in the alkaline earth compounds is relatively ionic with XPS evidence for significant charge separation. On the other hand, transition metal sulfides, with the exception of MnS, appear to be principally metallic with little or no charge separation. Values for the inner orbital binding energy shifts are reported for a large number of monochalcogenides. 相似文献
37.
38.
Raymond Zelnik Ema Rabenhorst Akhtar Haider Jürgen Lauterwein Hugo Wyler 《Helvetica chimica acta》1983,66(3):780-788
Dehydration of abiet-8-ene-7β, 13β-diol (ibozol, 1 ) leads to abieta-7,9(11)-dien-13β-ol ( 2 ) which aromatizes slowly to the known abieta-8,11,13-triene ( 3 ). Photosensitized oxygenation of the heteroannular diene 2 yields a mixture from which three compounds were identified; abiet-7-ene-9α, 11α, 13β-triol ( 4 ), abieta-8,11,13-trien-7-one ( 5 ), and abieta-8,11,13-trien-7α-ol ( 6 ). 相似文献
39.
The high sensitivity that can be attained using an enzymatic system and mediated by 4-tert-butylcatechol (4-TBC) has been verified by on-line interfacing of a rotating biosensor and continuous flow/stopped-flow/continuous-flow processing. Horseradish peroxidase, HRP, [EC 1.11.1.7], immobilized on a rotating disk, in presence of hydrogen peroxide catalyzed the oxidation of 4-TBC, whose back electrochemical reduction was detected on glassy carbon electrode surface at −150 mV. Thus, when penicillamine (PA) was added to the solution, these thiol-containing compounds participate in Michael type addition reactions with 4-TBC to form the corresponding thioquinone derivatives, decreasing the peak current obtained proportionally to the increase of its concentration. The highest response for PA was obtained around pH 7. This method could be used to determine PA concentration in the range 0.02-80 μM (r = 0.998). The determination of PA was possible with a limit of detection of 7 nM, in the processing of as many as 50 samples per hour. The HRP-rotating biosensor was successfully applied to the determination of PA in pharmaceutical formulations. 相似文献
40.
Ethylene tetramerization: a new route to produce 1-octene in exceptionally high selectivities 总被引:11,自引:0,他引:11
Bollmann A Blann K Dixon JT Hess FM Killian E Maumela H McGuinness DS Morgan DH Neveling A Otto S Overett M Slawin AM Wasserscheid P Kuhlmann S 《Journal of the American Chemical Society》2004,126(45):14712-14713
Linear alpha-olefins, such as 1-hexene and 1-octene, are important comonomers in the production of linear low-density polyethylene (LLDPE). The conventional method of producing 1-hexene and 1-octene is by oligomerization of ethylene, which yields a wide spectrum of linear alpha-olefins (LAOs). While there exists several processes for producing 1-hexene via ethylene trimerization, a similar route for the selective production of 1-octene has so far been elusive. We now, for the first time, report an unprecedented ethylene tetramerization reaction that produces 1-octene in selectivities exceeding 70%, using an aluminoxane-activated chromium/((R2)2P)2NR1 catalyst system. 相似文献