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81.
A new type of 2-D separation material was synthesized and studied. The material is suitable for 2-D chromatography utilizing both covalent and noncovalent interactions. The first dimension is boronate affinity chromatography, and the second dimension is RP chromatography (or vice versa). The polymeric media were prepared using p-vinylphenylboronic acid as the functional monomer. This monomer was selected due to the presence of the boronic acid group for the cis-diol/boronate interaction in boronate chromatography. Two crosslinkers were evaluated, namely ethylene glycol dimethacrylate and divinylbenzene. The crosslinker content was varied to maximize the polymer strength and the RP performance of the packed column. Several parameters were evaluated to define the optimum for polymer strength and column performance including crosslinker, porogen, initiator, and column-packing parameters. The polymer-based HPLC columns were successful in separating phenol, catechol, dimethylphthalate, and hydroquinone under RP conditions, and thus can be used as an RP HPLC column. The columns were also successful in separating catechol and adenosine under boronate chromatography conditions, and thus can be used as a boronate affinity column. Moreover, the two types of chromatography can be performed consecutively on the same column during one complete chromatographic run, making it a 2-D chromatography. Under these 2-D conditions, the catechol was separated from a mixture of phenol, catechol, dimethylphthalate, and hydroquinone; the adenosine ribonucleoside was separated from a mixture of adenosine ribonucleoside, adenosine deoxyribonucleoside, and uridine deoxyribonucleoside. This type of single-column 2-D HPLC eliminates the requirement of a complex and expensive multidimensional HPLC instrument and provides increased peak capacity for separation. 相似文献
82.
M.-S. Li S.-Y. Huang S.-T. Wu H.-C. Lin A. Y.-G. Fuh 《Applied physics. B, Lasers and optics》2010,101(1-2):245-252
Two-dimensional (2-D) square lattice (SL) photonic crystals (PCs) are fabricated, and their optical/electro-optical properties are studied. The PCs are based on polymer-dispersed liquid crystals (PDLC) that are formed using two-beam interference with double exposures. The PC structure that is observed using a scanning electron microscope matches with the calculated interference pattern. The results of optical/electro-optical studies demonstrate that superprism and negative refraction effects occur at certain incident angles over a range of frequencies and are consistent with the simulated ones. Moreover, the negative refraction efficiency is electrically controllable. 相似文献
83.
The induced optical aberration of laser beam passing through a transparent flowing fluid layer on a metal specimen is experimentally and empirical formula studied. The proposed study presents an experimental investigation of metal surface roughness measurement by combining an optical probe of laser-scattering phenomena and adaptive optics (AO) for aberration correction. In the absence of the AO correction scheme, induced flow velocity of 0.278 m/s can severely degrade the residual wavefront root mean square (RMS) error to 0.58 μm and decrease the scattered laser intensity. Real-time AO correction in closed-loop at a sampling rate of 8Hz can reduce the wavefront RMS error to 0.19 μm and improve the attenuation of scattered laser intensity. The maximum relative error of the estimated roughness (R a) is less than 7.8% compared with the stylus method. The experimental results show satisfactory correction in the presence of a flowing fluid layer using the AO system. 相似文献
84.
85.
Dr. Benjamin A. Chalmers Hui Xing Sevan Houston Dr. Charlotte Clark Dr. Sussan Ghassabian Dr. Andy Kuo Benjamin Cao Andrea Reitsma Cody‐Ellen P. Murray Dr. Jeanette E. Stok Dr. Glen M. Boyle Carly J. Pierce Stuart W. Littler Prof. David A. Winkler Prof. Paul V. Bernhardt Dr. Cielo Pasay Prof. James J. De Voss Prof. James McCarthy Prof. Peter G. Parsons Prof. Gimme H. Walter Prof. Maree T. Smith Prof. Helen M. Cooper Prof. Susan K. Nilsson Dr. John Tsanaktsidis Dr. G. Paul Savage Prof. Craig M. Williams 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2018,130(28):8491-8491
86.
Shuo-En Tsai Wan-Ping Yen Ching-Chun Tseng Jia-Jun Xie Ming Yu Liou Yi-Ting Li Naoto Uramaru Fung Fuh Wong 《Tetrahedron》2018,74(22):2787-2791
The efficient acid catalytic synthesis of pyrazolo [3,4-d]pyrimidine was developed by treating 1H-pyrazol-5-yl-N,N-dimethylformamidine with various aminating agents including N,O-bis(trimethylsilyl)hydroxylamine (NHSiMe3(OSiMe3)), cyanamide (NH2CN), hydroxylamine (NH2OH), methoxyamine (NH2OMe), hydrazine (NH2NH2), and urea (NH2C(O)NH2) in acidic solution at reflux. Based on the experimental result, cyanamide (NH2CN) and methanesulfonic acid were indicated the best aminating agent and acid mediated solvent. On the other hands, the reactivity tendency was involved the activity of original leaving species grafting on the aminating agents, such as –OH, –OMe, –OSiMe3, –NH2, –OSiMe3, –C(O)NH2, and –CN, in acid catalytic heterocyclic reaction. 相似文献
87.
88.
A water-compatible Pd(ii) pincer with a hybrid [SNS]-donor set, [L(1)PdCl]Cl.2H(2)O [L(1) = bis-(2-(i-butylsulfanyl)-ethyl)-amine] has been isolated and crystallographically characterized; its solid lattice at 223 K contains a ladder-like water polymer of tetramers and extensive H-bonding exists among the cation, anion and water cluster, and this water-soluble complex is active in Suzuki-Miyaura coupling of phenylboronic acid and selected aryl bromides in water at 75 degrees C. 相似文献
89.
Cobalt-catalyzed hydrogen desorption from the LiNH2-LiBH4 system 总被引:1,自引:0,他引:1
Tang WS Wu G Liu T Wee AT Yong CK Xiong Z Hor AT Chen P 《Dalton transactions (Cambridge, England : 2003)》2008,(18):2395-2399
A doping of 5 wt% CoCl2 considerably decreases the dehydrogenation temperature of a mixture of LiNH2 and LiBH4. More that 8 wt% of hydrogen can be released at ca. 155 degrees C. X-Ray absorption near edge structure (XANES) spectroscopy indicated the formation of metallic Co after ball milling CoCl2 with LiNH2 and LiBH4. Extended X-ray absorption fine structure (EXAFS) spectroscopy measurements revealed that Co particles have poor crystallinity and are finely dispersed in the sample, which could lead to a high catalytic efficiency. 相似文献
90.
Two heterotrinuclear oligomeric complexes [trans-RuCl(C[triple bond, length as m-dash]Cpy-4)(dppm)(2)](2)[MCl(2)] (M = Pd ; M = Pt ) are prepared from the metalloligand trans-[RuCl(C[triple bond, length as m-dash]Cpy-4)(dppm)(2)] (dppm = Ph(2)PCH(2)PPh(2), ). The resultant linear alignment of the metals [Ru-M-Ru] is imposed by a combinative use of trans-directed spacers and planar metals with trans-juxtaposed donor sites. Ligand exchange of with [Pd(CH(3)CN)(4)][PF(6)](2) gives trans-[Ru(CH(3)CN)(C[triple bond, length as m-dash]Cpy-4)(dppm)(2)][PF(6)] (). All complexes are characterized by single-crystal X-ray crystallography and solution spectroscopy. Acid-base titration on suggested protonation of the pendant pyridyl. Complexes and also undergo protonation at the C[triple bond, length as m-dash]C moiety under acid conditions. The inter-conversion of alkynyl and vinylidene functionality is described. The dual acid and base characters of makes it a potential metalloligand towards basic and acidic fragments in multinuclear heterometallic assemblies. 相似文献