全文获取类型
收费全文 | 2161篇 |
免费 | 52篇 |
国内免费 | 12篇 |
专业分类
化学 | 1289篇 |
晶体学 | 12篇 |
力学 | 71篇 |
数学 | 291篇 |
物理学 | 562篇 |
出版年
2021年 | 19篇 |
2020年 | 29篇 |
2019年 | 23篇 |
2016年 | 45篇 |
2015年 | 40篇 |
2014年 | 43篇 |
2013年 | 100篇 |
2012年 | 96篇 |
2011年 | 106篇 |
2010年 | 68篇 |
2009年 | 63篇 |
2008年 | 87篇 |
2007年 | 78篇 |
2006年 | 86篇 |
2005年 | 73篇 |
2004年 | 68篇 |
2003年 | 52篇 |
2002年 | 72篇 |
2001年 | 34篇 |
2000年 | 40篇 |
1999年 | 30篇 |
1998年 | 23篇 |
1997年 | 25篇 |
1996年 | 26篇 |
1995年 | 28篇 |
1994年 | 17篇 |
1993年 | 43篇 |
1992年 | 25篇 |
1991年 | 28篇 |
1990年 | 28篇 |
1989年 | 29篇 |
1987年 | 25篇 |
1986年 | 20篇 |
1985年 | 23篇 |
1984年 | 27篇 |
1983年 | 18篇 |
1982年 | 23篇 |
1981年 | 27篇 |
1980年 | 25篇 |
1979年 | 16篇 |
1978年 | 25篇 |
1977年 | 37篇 |
1976年 | 22篇 |
1975年 | 18篇 |
1974年 | 19篇 |
1973年 | 21篇 |
1971年 | 22篇 |
1968年 | 18篇 |
1967年 | 16篇 |
1966年 | 16篇 |
排序方式: 共有2225条查询结果,搜索用时 171 毫秒
11.
12.
Rat pancreatic secretory proteins were separated by an automated liquid chromatography system utilizing a Mono S cation-exchange column. Optimal resolution was obtained with a multistep salt and pH gradient (0.01-2 M LiCl, pH 5.3-63). A total of fourteen well-separated peaks, as well as several minor peaks, were detected by UV absorption. The main pancreatic enzymes were resolved (two amylases, two chymotrypsinogens, two trypsinogens, proelastase, lipase, prophospholipase A2, procarboxypeptidase A, procarboxypeptidase B, and ribonuclease). In addition, proteins without enzymic activity, such as lithostathine and pancreatitis-associated protein, were identified. Activation of proenzymes did not occur during the separation. At a flow-rate of 0.5 ml/min, ca. 250 micrograms to 5 mg of protein could be applied with equal resolution. The reproducibility of retention volumes and peak areas was high (less than 1% or 5% variation, respectively). When radiolabeled proteins were separated, a comparable pattern of peaks was obtained. The technique described is, therefore, not only useful for analytical and preparative separation of pancreatic proteins but can additionally serve for quantitative determination of the pancreatic isoenzyme pattern. 相似文献
13.
D. T. Le C. P. Morath H. E. Norton D. A. Cardimona S. Raghavan P. Rotella S. A. Stintz B. Fuchs S. Krishna 《Infrared Physics & Technology》2003,44(5-6):517-526
In this paper we report studies on normal incidence, InAs/In0.15Ga0.85As quantum dot infrared photodetectors (QDIPs) in the dots-in-a-well (DWELL) configuration. Three QDIP structures with similar dot and well dimensions were grown and devices were fabricated from each wafer. Of the three devices studied, the first served as the control, the second was grown with an additional 400 Å AlGaAs blocking layer, and the third was grown on a GaAs n+ substrate with the intention of testing a single pass geometry. Spectral measurements on all three devices show one main peak in the long-wave IR (≈8 μm). The absorption was attributed to the bound-to-bound transition between the ground state of the InAs quantum dot and the ground state of the In0.15Ga0.85As well. Calibrated peak responsivity and peak detectivity measurements were performed on each device at 40, 60, and 80 K. For the same temperatures, frequency response measurements from 20 Hz to 4 kHz at a bias of Vb=−1 V were also performed. The addition of the blocking layer was shown to slightly enhance responsivity, which peaked at 2.4 A/W at 77 K, Vb=−1 V and responsivity was observed to be significantly reduced in the single pass (n+ substrate) sample. The rolloff of the frequency response was observed to be heavily dependent on temperature, bias, and irradiance. The results from the characterization of each sample are reported and discussed. 相似文献
14.
Jakob Oren Michaela Vardi Rossana Viskin Sarah Abramson Benzion Fuchs 《Helvetica chimica acta》1993,76(3):1182-1193
The title molecules were shown to photorearrange with remarkable selectivity. Wavelength variation steers the rearrangement modes, of which the [1,2]-acyl shift was found to be largely regioselective, diastereoselective, and enantiospecific. Chemical intercorrelation of products and mechanistic studies were carried out all along. The potential significance of these photochemical processes in selective synthetic schemes is discussed. 相似文献
15.
16.
S. Descotes N.H. Fuchs L. Girlanda J. Stern 《The European Physical Journal C - Particles and Fields》2002,24(3):469-483
The recently published E865 data on charged decays and phases are reanalyzed to extract values of the two S-wave scattering lengths, of the subthreshold parameters and , of the low-energy constants and as well as of the main two-flavour order parameters: and in the limit taken at the physical value of the strange quark mass. Our analysis is exclusively based on direct experimental information
on phases below 800 MeV and on the new solutions of the Roy equations by Ananthanarayan et al. The result is compared with the
theoretical prediction relating 2a
0
0-5a
0
2 and the scalar radius of the pion, which was obtained in two-loop Chiral Perturbation Theory. A discrepancy at the 1- level is found and commented upon.
Received: 11 December 2001 / Revised version: 28 March 2002 / Published online: 7 June 2002 相似文献
17.
R. Rehm M. Walther J. Schmitz J. Fleißner F. Fuchs J. Ziegler W. Cabanski 《Opto-Electronics Review》2006,14(1):19-24
The first fully operational mid-IR (3–5 μm) 256×256 IR-FPA camera system based on a type-II InAs/GaSb short-period superlattice
showing an excellent noise equivalent temperature difference below 10 mK and a very uniform performance has been realized.
We report on the development and fabrication of the detecor chip, i.e., epitaxy, processing technology and electro-optical
characterization of fully integrated InAs/GaSb superlattice focal plane arrays. While the superlattice design employed for
the first demonstrator camera yielded a quantum efficiency around 30%, a superlattice structure grown with a thicker active
layer and an optimized V/III BEP ratio during growth of the InAs layers exhibits a significant increase in quantum efficiency.
Quantitative responsivity measurements reveal a quantum efficiency of about 60% for InAs/GaSb superlattice focal plane arrays
after implementing this design improvement.
The paper presented there appears in Infrared Photoelectronics, edited by Antoni Rogalski, Eustace L. Dereniak, Fiodor F. Sizov, Proc. SPIE Vol. 5957, 595707 (2005). 相似文献
18.
Colloid and Polymer Science - Nach einer Aufzählung der verschiedenen Arten von zwischenmolekularen Kräften und dem Hinweis auf die Gültigkeitsgrenze der bestehenden Vorstellungen... 相似文献
19.
Gerhard Laus Johannes Schütz Herwig Schottenberger Max Andre Klaus Wurst Mariana Spetea Karl‐Hans Ongania AdrianG. Müller Helmut Schmidhammer 《Helvetica chimica acta》2003,86(10):3274-3280
The two diastereoisomeric ferrocenyl‐substituted orvinols 2 and 3 were prepared. The modified alkaloids are still able to interact with opioid receptors (see Table). The ferrocene moiety allows highly selective and sensitive electrochemical detection. The X‐ray crystal structure of the major isomer 2 was determined. The combination of a metallocene and a morphinan alkaloid holds promise for useful antitumor activity. 相似文献
20.
Martin Fuchs 《manuscripta mathematica》1987,58(3):377-380
Considering discrete groups G only, we present an elementary proof of the familiar equivalence of the category of G-spaces (with maps equivariant up to homotopy) and the category of Borel fibrations over BG. 相似文献