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21.
Murat Ates Nesimi Uludag Tolga Karazehir Fatih Arican 《Journal of Solid State Electrochemistry》2013,17(9):2417-2427
In this work, (3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-(4-vinylbenzyl)-9H-carbazole) (EDOTVBCz) comonomer was chemically synthesized and characterized by Fourier transform infrared (FTIR), proton nuclear magnetic resonance, and carbon nuclear magnetic resonance spectroscopy. EDOTVBCz was electrocoated on glassy carbon electrode (GCE) in various initial molar concentrations ([EDOTVBCz]0?=?1.0, 1.5, 2.0, and 3.0) in 0.1 M lithium perchlorate (LiClO4)/acetonitrile (CH3CN). P(EDOTVBCz)/GCE was characterized by cyclic voltammetry, FTIR reflectance-attenuated total reflection spectroscopy, scanning electron microscopy–energy dispersive X-ray analysis, atomic force microscopy, and electrochemical impedance spectroscopy (EIS). EIS was used to determine the capacitive behaviors of modified GCE via Nyquist, Bode magnitude, Bode phase, and admittance plots. The highest low-frequency capacitance value was obtained as C LF?=?~2.35 mF cm?2 for [EDOTVBCz]0?=?3.0 mM. Double-layer capacitance of the polymer/electrolyte system was calculated as C dl?=?~2.78 mF cm?2 for [EDOTVBCz]0?=?1.0 and 3.0 mM. The maximum phase angle was obtained as θ?=?~76.7o for [EDOTVBCz]0?=?1.0, 1.5, 2.0, and 3.0 mM at the frequency of 20.6 Hz. AC impedance spectra of P(EDOTVBCz)/LiClO4/CH3CN was obtained by performing electrical equivalent circuit model of R(Q(R(CR))) with linear Kramers–Kronig test. Figure
SEM-EDX analysis of P(EDOTVBCz)/CFME EDX point analysis inset: SEM point analysis, [EDOTVBCz]0?=?3 mM. Chronoamperometric method of constant potential at 1.6 V, 300 s in 0.1 M LiClO4/CH3CN 相似文献
22.
The inhibition efficiency of 2-Pyrrolidin-1-yl-1,3-thiazole-5-carboxylic acid (PTCA) against mild steel (MS) corrosion was investigated in acidic solution by using quantum chemical calculations based on Density Functional Theory (DFT) method and electrochemical measurements. The electrochemical impedance spectroscopy (EIS), potentiodynamic, potential zero charge (pzc) analysis and electrochemical noise (EN) measurements at various concentrations (from 0.1 to 10 mM) and immersion times were utilized in experimental part. The surface analysis was achieved scanning electron microscope (SEM) and contact angle measurements in the absence and presence of 10 mM PTCA. According to DFT results, PTCA exhibited 3.737 eV band gap and 8.130 Debye dipole moment which were a signal of potentially convenient corrosion inhibitor properties. PTCA has a remarkable corrosion inhibition capability to mild steel, which inhibited both anodic and cathodic corrosion rates, relying on it's physically adsorption on the metal solution interface and protection ability was increased with increasing PTCA concentration. The obtained adsorption equilibrium constant was 11.11 × 103 M-1 and calculated standard free energy of adsorption was ?33.03 kJ mol?1. The determined activation energy values were 55.58 kJ mol?1 and 96.86 kJ mol?1 in 0.5 M HCl in the absence and presence of 10 mM PTCA, respectively. PTCA demonstrated a strong inhibition efficiency of 98.3%, after 168 h immersion, according to the EIS results. As a consequently, we recommend that PTCA is a convenient inhibitor in 0.1 M HCl for mild steel protection against corrosion. 相似文献
23.
24.
S. R. Garaeva Ahmet Alper Aydin Adnan Aydin Bahattin Yalçin P. A. Fatullaeva A. A. Medzhidov 《Russian Journal of Applied Chemistry》2010,83(1):97-101
Structure of products formed in polyethylene oxidation by nitric acid was studied by NMR, IR, and electronic absorption spectroscopies
and derivatography. 相似文献
25.
Alper PB Meyers C Lerchner A Siegel DR Carreira EM 《Angewandte Chemie (International ed. in English)》1999,38(21):3186-3189
The role of the bifunctional catalyst is decisive: The magnesium ion as Lewis acid and its nucleophilic iodide counterion contribute in synergy to the successful ring expansion of the cyclopropane 1 by aldimine 2 [Eq. (1)]. This reaction offers a novel route to spiro[pyrrolidin-3,3'-oxindoles] 3. 相似文献
26.
Amines were obtained in excellent yields by treatment of nitro compounds, at room temperature and atmospheric pressure, with carbon monoxide, ruthenium carbonyl as the metal catalyst, and benzyltriethylammonium chloride as the phase transfer catalyst in an aqueous base-organic solvent system. 相似文献
27.
28.
[reaction: see text] The [Rh(COD)Cl]2- and KI-catalyzed carbonylation of functionalized N-alkylisothiazolidines in toluene gives the corresponding tetrahydro-2H-1,3-thiazin-2-ones in good yield. The carbonylation reaction occurred site-selectively at the S-N bond of the isothiazolidine ring. The reaction is believed to proceed via oxidative addition, followed by CO insertion and reductive elimination to form the tetrahydro-2H-1,3-thiazin-2-one derivatives. 相似文献
29.
Sharapov SE Alper B Fessey J Hawkes NC Young NP Nazikian R Kramer GJ Borba DN Hacquin S De La Luna E Pinches SD Rapp J Testa D;JET-EFDA contributors 《Physical review letters》2004,93(16):165001
A microwave interferometry technique is applied for the first time for detecting a discrete spectrum of Alfvén cascade (AC) eigenmodes excited with fast ions in reversed magnetic shear plasmas of the Joint European Torus. The interferometry measurements of plasma density perturbations associated with ACs show an unprecedented frequency and time resolution superior to that obtained with external magnetic coils. The measurements of ACs are used for monitoring the evolution of the safety factor and density of rational magnetic surfaces in the region of maximum plasma current. 相似文献
30.
A synthesis of a previously unknown indole derivative is presented. The route reported herein allows for the preparation of multihundred gram quantities of material without any chromatographic purification. Conditions are presented for the Pd-catalyzed elaboration of one of the "diversity generating elements" of this important pharmacophore. 相似文献