全文获取类型
收费全文 | 1208篇 |
免费 | 50篇 |
国内免费 | 4篇 |
专业分类
化学 | 915篇 |
晶体学 | 2篇 |
力学 | 21篇 |
数学 | 202篇 |
物理学 | 122篇 |
出版年
2024年 | 1篇 |
2023年 | 12篇 |
2022年 | 8篇 |
2021年 | 75篇 |
2020年 | 38篇 |
2019年 | 32篇 |
2018年 | 26篇 |
2017年 | 14篇 |
2016年 | 41篇 |
2015年 | 40篇 |
2014年 | 43篇 |
2013年 | 69篇 |
2012年 | 81篇 |
2011年 | 93篇 |
2010年 | 50篇 |
2009年 | 37篇 |
2008年 | 82篇 |
2007年 | 96篇 |
2006年 | 64篇 |
2005年 | 73篇 |
2004年 | 63篇 |
2003年 | 55篇 |
2002年 | 41篇 |
2001年 | 26篇 |
2000年 | 5篇 |
1999年 | 13篇 |
1998年 | 9篇 |
1997年 | 9篇 |
1996年 | 8篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有1262条查询结果,搜索用时 171 毫秒
91.
Loss S Magistrato A Cataldo L Hoffmann S Geoffroy M Röthlisberger U Grützmacher H 《Angewandte Chemie (International ed. in English)》2001,40(7):1143
The cover picture shows the metalloporphyrin heterodimer [(tpp)Mo$\rm{\mathop{-}^{4}}$Re(oep)](+) with the novel [Mo$\rm{\mathop{-}^{4}}$Re](5+) core. The core represents the first example of a quadruple bond between elements of different triads, thus proving that heterometallic quadruple bonds are not limited to the Group 6 metals. From the space-filling model it is clear that there is no interaction between the stabilizing porphyrin ligands. The ORTEP plot in a projection along the Re-Mo axis emphasizes the perfectly eclipsed geometry of the porphyrins, which is unambiguous proof of the existence of the quadruple bond in the solid state. The diamagnetism and large magnetic anisotropy of the cation, as determined by (1)H NMR spectroscopy, indicate that the quadruple bond is retained in solution. A logical and well-defined synthetic route was used to synthesize the dimer, and can be extended to other metalloporphyrins to generate further novel quadruple bonds (the picture was generated by Marina Boulan, St. Petersburg, Russia), full details are reported by J. P. Collman et al. on p. 1271 ff. 相似文献
92.
93.
94.
95.
Alessandra Bernardi 《Journal of Pure and Applied Algebra》2008,212(6):1542-1559
The ideal of a Segre variety Pn1×?×Pnt?P(n1+1)?(nt+1)−1 is generated by the 2-minors of a generic hypermatrix of indeterminates (see [H.T. Hà, Box-shaped matrices and the defining ideal of certain blowup surface, J. Pure Appl. Algebra 167 (2-3) (2002) 203-224. MR1874542 (2002h:13020)] and [R. Grone, Decomposable tensors as a quadratic variety, Proc. Amer. Math. 43 (2) (1977) 227-230. MR0472853 (57 #12542)]). We extend this result to the case of Segre-Veronese varieties. The main tool is the concept of “weak generic hypermatrix” which allows us to treat also the case of projection of Veronese surfaces from a set of general points and of Veronese varieties from a Cohen-Macaulay subvariety of codimension 2. 相似文献
96.
97.
98.
Maria Alessandra Ragusa 《Journal of Global Optimization》2008,40(1-3):361-368
In this note we prove a sufficient condition for commutators of fractional integral operators to belong to Vanishing Morrey
spaces VL
p,λ. In doing this we use an extension on Morrey spaces of an inequality by Fefferman and Stein concerning the sharp maximal
function and the fractional maximal function and related Morrey inequalities.
相似文献
99.
de Souza Cabrini F. da Cunha Alessandra L. M. C. Auclio Ricardo Queiroz 《Chromatographia》2009,70(9-10):1461-1466
Micellar electrokinetic capillary chromatography was used for the determination of picoxystrobin and pyraclostrobin. The background electrolyte consisted of borate buffer (40 mmol L−1 pH 8.5), SDS (30 mmol L−1) and acetonitrile (15% in volume). Runs were made at 25 °C with 25 kV applied potential. The developed method was applied to analyte fortified urine samples. On-line analyte concentration, combined with a capillary of a longer optical path length, allowed limits of quantification of 8.6 × 10−8 mol L−1 for picoxystrobin and 1.8 × 10−7 mol L−1 for pyraclostrobin.
相似文献100.
Alam Gustavo Trov Silene Alessandra Santos Melo Raquel Fernandes Pupo Nogueira 《Journal of photochemistry and photobiology. A, Chemistry》2008,198(2-3):215-220
Photodegradation of the pharmaceuticals amoxicillin (AMX), bezafibrate (BZF) and paracetamol (PCT) in aqueous solutions via the photo-Fenton process was investigated under black-light and solar irradiation. The influences of iron source, initial H2O2 concentration and matrix (distilled water and sewage treatment plant effluent) on degradation efficiency were discussed in detail. The results showed that (i) the degradation of the drugs was favored in the presence of potassium ferrioxalate (FeOx) in comparison to Fe(NO3)3; (ii) the increase of the H2O2 concentration improved the efficiency of AMX and BZF oxidation; however, the same was not observed for PCT; (iii) the influence of the matrix was observed for the degradation of BZF and PCT; (iv) under solar irradiation, the oxidation of the BZF and PCT is faster than under black-light irradiation. All these pharmaceuticals can be efficiently degraded employing the process evaluated. 相似文献