全文获取类型
收费全文 | 1592篇 |
免费 | 69篇 |
国内免费 | 9篇 |
专业分类
化学 | 1009篇 |
晶体学 | 12篇 |
力学 | 54篇 |
数学 | 114篇 |
物理学 | 481篇 |
出版年
2024年 | 2篇 |
2023年 | 6篇 |
2022年 | 8篇 |
2021年 | 26篇 |
2020年 | 23篇 |
2019年 | 30篇 |
2018年 | 20篇 |
2017年 | 24篇 |
2016年 | 50篇 |
2015年 | 45篇 |
2014年 | 55篇 |
2013年 | 110篇 |
2012年 | 122篇 |
2011年 | 105篇 |
2010年 | 88篇 |
2009年 | 64篇 |
2008年 | 118篇 |
2007年 | 114篇 |
2006年 | 106篇 |
2005年 | 100篇 |
2004年 | 62篇 |
2003年 | 69篇 |
2002年 | 70篇 |
2001年 | 35篇 |
2000年 | 43篇 |
1999年 | 16篇 |
1998年 | 19篇 |
1997年 | 11篇 |
1996年 | 27篇 |
1995年 | 26篇 |
1994年 | 13篇 |
1993年 | 15篇 |
1992年 | 5篇 |
1991年 | 7篇 |
1990年 | 6篇 |
1989年 | 3篇 |
1986年 | 2篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 3篇 |
1975年 | 1篇 |
1974年 | 4篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1968年 | 2篇 |
1963年 | 1篇 |
1961年 | 1篇 |
排序方式: 共有1670条查询结果,搜索用时 15 毫秒
101.
102.
103.
An efficient synthesis of 13-epi-7-O-(triethylsilyl)baccatin III from 13-deoxybaccatin III is described. Oxidation of 13-deoxy-7-O-(triethylsilyl)baccatin III with tert-butyl peroxide, followed by reduction with SmI(2), produced 13-epi-7-O-(triethylsilyl)baccatin III in good overall yield. The preparation of 13-oxo-7-O-(triethylsilyl)baccatin III from 13-epi-7-O-(triethylsilyl)baccatin III using tetrapropylammonium perruthenate and N-methylmorpholine N-oxide is also reported. 相似文献
104.
Krokovny P Abe K Abe K Abe T Adachi I Ahn BS Aihara H Akatsu M Asano Y Aso T Aulchenko V Aushev T Bakich AM Ban Y Banas E Bay A Bedny I Behera PK Bizjak I Bondar A Bozek A Bracko M Brodzicka J Browder TE Casey BC Chang P Chao Y Chen KF Cheon BG Chistov R Choi SK Choi Y Danilov M Dong LY Drutskoy A Eidelman S Eiges V Enari Y Everton CW Fang F Fukunaga C Gabyshev N Garmash A Gershon T Golob B Gordon A Guo R Haba J Hanagaki K Handa F Harada Y Hayashii H Hazumi M Heenan EM Higuchi T Hinz L Hojo T 《Physical review letters》2002,89(23):231804
We report the first observation of a B meson decay that is not accessible by a direct spectator process. The channel B(0)-->D(+)(s)K- is found in a sample of 85 x 10(6) BB; events, collected with the Belle detector at KEKB, with a branching fraction B(B(0)-->D(+)(s)K-)=(4.6(+1.2)(-1.1)+/-1.3) x 10(-5). We also obtain evidence for the B0-->D(+)(s)pi(-) decay with branching fraction B(B0-->D(+)(s)pi(-))=(2.4(+1.0)(-0.8)+/-0.7) x 10(-5). This value may be used to extract a model-dependent value of |V(ub)|. 相似文献
105.
106.
Schmidt KS Filippov DV Meeuwenoord NJ van Der Marel GA van Boom JH Lippert B Reedijk J 《Angewandte Chemie (International ed. in English)》2000,39(2):375-377
Cross-linking ability is possible with the oligonucleotide-tethered, monofunctional trans-Pt(II) complex shown. It was synthesized by a novel solid-phase approach comprising conjugation of immobilized tetrathymidylic acid with a trans-a(2)Pt(II) building unit, ammonolysis, and transformation of the resulting complex (R=1-N-cyclohexylmethylthyminate) into the chloro derivative (R=Cl). a=NH(2)CH(3), T=thymine. 相似文献
107.
Tae Oan Ahn Jung Ho Kim Han Mo Jeong Sang Won Lee Lee Soon Park 《Journal of Polymer Science.Polymer Physics》1994,32(1):21-28
The compatibilizing effect of polyarylate-polystyrene (PAR-PS) block copolymer prepared from macroazo initiator was examined in polyarylate/polystyrene blends from the view-points of morphology, density, and thermal, mechanical, and rheological properties. PARPS block copolymer enhanced the mutual dissolution of the homopolymers. Reduced dispersed-domain size and increased density showed the efficiency of the block copolymer as a compatibilizing agent. Results from mechanical and rheological properties could also be explained by the compatibilizing effect of PAR-PS block copolymer in the blends. © 1994 John Wiley & Sons, Inc. 相似文献
108.
The Percus-Yevick equation for the Widom-Rowlinson model is solved exactly in one and three dimensions. In one dimension the direct correlation function is obtained explicitely. In three dimensions only the thermodynamic properties have been obtained so far implicitely in terms of elliptic integrals, and there is a maximum density beyond which the P.Y. equation has no solution and that before that density is ‘critical density’ at which the homogenous state becomes unstable. 相似文献
109.
From Melampyrum silvaticum L. (Scrophulariaceae) the new Iridoid melampyrosid (2) was isolated beside aucubin (1). The structure of 2 is determined by spectral data and chemical reactions. 相似文献
110.
Ahn TK Yoon ZS Hwang IW Lim JK Rhee H Joo T Sim E Kim SK Aratani N Osuka A Kim D 《The journal of physical chemistry. B》2005,109(22):11223-11230
We have investigated the overall excitation energy relaxation dynamics in linear porphyrin arrays as well as the energy transport phenomena by attaching an energy acceptor to one end of a linear porphyrin array by using steady state and time-resolved spectroscopic measurements. We have revealed that the solvation dynamics as well as the conformational dynamics contributes significantly to the energy relaxation processes of linear porphyrin arrays. Consequently, long porphyrin arrays no longer serve as good energy transmission elements in donor-acceptor linked systems due to conformational heterogeneities which provide the non-radiative deactivation channels as energy quenchers. 相似文献