Anomeric configuration-directed diastereoselective C-C bond formation in vinyl sulfone-modified carbohydrates: a general route to branched-chain sugars

[structure: see text] This is the first report on the diastereoselective addition of carbon nucleophiles to vinyl sulfone-modified hex-2-enopyranosides and pent-2-enofuranosides. Nucleophiles add to the C-2 position from a direction opposite to that of the disposition of the anomeric methoxy group. This novel concept of anomeric configuration-directed stereocontrolled carbon-carbon bond formation in vinyl sulfone-modified carbohydrates is general in nature and has been implemented in the synthesis of new hexopyranosyl and pentofuranosyl branched-chain sugars and densely functionalized carbohydrates.     

Dynamics of (H(-), H(2)) collisions: a time-dependent quantum mechanical investigation on a new ab initio potential energy surface

A global analytical potential energy surface for the ground state of H(3)(-) has been constructed by fitting an analytic function to the ab initio potential energy values computed using coupled cluster singles and doubles with perturbative triples [CCSD(T)] method and Dunning's augmented correlation consistent polarized valence triple zeta basis set. Using this potential energy surface, time-dependent quantum mechanical wave packet calculations were carried out to calculate the reaction probabilities (P(R)) for the exchange reaction H(-)+H(2)(v, j)-->H(2)+H(-), for different initial vibrational (v) and rotational (j) states of H(2), for total angular momentum equal to zero. With increase in v, the number of oscillations in the P(R)(E) plot increases and the oscillations become more pronounced. While P(R) increases with increase in rotational excitation from j=0 to 1, it decreases with further increase in j to 2 over a wide range of energies. In addition, rotational excitation quenches the oscillations in P(R)(E) plots.     

PMD effect on pulse shapes and power penalty in optical communication systems

We present an analytical expression relating the output state of polarization and the first-order polarization mode dispersion (PMD) vector in terms of the angle of precession of the output state of polarization around the PMD vector. We derive, incorporating for the first time this angle of precession, a general relation to study the effect of first-order PMD on pulses of arbitrary shapes, and expressions for pulse shape, pulse broadening and power penalty taking into account both PMD and chromatic dispersion. Measured experiment results are presented for NRZ, RZ, NRZ-DPSK, and RZ-DPSK modulation formats.     

Effects of positron density and temperature on ion acoustic dressed solitons in an electron–positron–ion plasma

Ion acoustic dressed solitons in a three component plasma consisting of cold ions, hot electrons and positrons are studied. Using reductive perturbation method, Korteweg–de Vries (KdV) equation and a linear inhomogeneous equation, governing respectively the evolution of first and second order potentials are derived for the system. Renormalization procedure of Kodama and Taniuti is used to obtain nonsecular solutions of these coupled equations. It is found that electron–positron–ion plasma system supports only compressive solitons. For a given amplitude of soliton on increasing the positron concentration, velocity of the KdV as well as dressed soliton increases. For any arbitrary values of soliton's amplitude and positron concentration, velocity of the dressed soliton is found to be larger than that of the KdV soliton. For small amplitude of solitons, the width of KdV as well as dressed soliton decreases as positron concentration increases and width of dressed soliton is found to be larger than that of the KdV soliton. However, for a large value of soliton's amplitude as concentration of positrons increases, instead of decreasing width of dressed soliton starts to increase.     

Superconducting State Parameters of CucZr100-c Binary Amorphous Alloys by Pseudopotential Approach

We present the screening dependence theoretical investigations of the superconducting state parameters, i.e. electron-phonon coupling strength A, Coulomb pseudopotential μ＊, transition temperature To, isotope effect exponent α, and effective interaction strength NoV of some CucZr100-c （C = 25, 30, 33, 35, 40, 45, 50, 55, 57, 60 at.%） binary amorphous alloys by employing the well-known empty core model potential of Ashcroft. Five screening functions proposed by Hartree, Taylor, Ichimaru-Utsumi, Farid et al. and Sarkar et al. are used to study the screening influence on the aforesaid superconducting properties. The transition temperature Tc obtained from the Ichimaru-Utsumi screening function is found to be in excellent agreement with available theoretical or experimental data. Also, the present results are found in qualitative agreement with the other earlier reported data, which confirms the superconducting phase in the amorphous alloys.     

Study of superconducting state parameters of amorphous metals by a pseudopotential theory

The theoretical computation of the superconducting state parameters (SSP) viz; electron-phonon coupling strength λ, Coulomb pseudopotential μ ^*, transition temperature T _c , isotope effect exponent α and effective interaction strength N _O V of some monovalent (Cu and Au), divalent (Ca, Sr, Ba, αHg, βHg and Ra) and polyvalent (Lu, Rh, Sc, Y, La, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Ac, Th, Hf, Ru, Os, Ir, V, Ta, Pa, Cr, Mo, U, Re, Np and Pu) amorphous metals based on the different groups of the periodic table have been carried out for the first time using the well known Ashcroft’s empty core (EMC) model pseudopotential. Herein, we have employed five different types of local field correction functions proposed by Hartree (H), Taylor (T), Ichimaru-Utsumi (IU), Farid et al. (F) and Sarkar et al. (S) to study the exchange and correlation effects on the present investigations. A very strong influence of all the exchange and correlation functions have been observed in the present study. Our results are in fair agreement with documented theoretical as well as experimental data. A strong dependency of the SSP of amorphous metals on the valency Z was found.      

Concomitant dimorphs of tri-O-[p-halobenzoyl]-myo-inositol 1,3,5-orthoformates with different halogen bonding contacts: first order crystal-to-crystal thermal phase transition of kinetic form to the thermodynamic form

Crystallization of tri-O-[p-halobenzoyl]-myo-inositol 1,3,5-orthoformates from ethyl acetate-petroleum ether solution produced concomitant dimorphs that have different halogen bonding contacts; the kinetic form with C-Br...O-C contacts upon heating to 185 degrees C, converts completely to the thermodynamic form with C-Br...O=C contacts via crystal-to-crystal first order phase transition.     

Functional group dependent site specific fragmentation of molecules by low energy electrons

Functional group dependence is observed in the dissociative electron attachment (DEA) to various organic molecules in which the DEA features seen in the precursor molecules of the groups are retained in the bigger molecules. This functional group dependence is seen to lead to site-selective fragmentation of these molecules at the hydrogen sites. The results are explained in terms of the formation of core-excited Feshbach resonances. The results point to a simple way of controlling chemical reactions as well as interpreting the DEA data from bigger biological molecules.     

Rigidity spectrum of cosmic ray helium nuclei

An experiment has been carried out using an oriented stack of nuclear emulsions to determine the rigidity spectrum of cosmic ray helium nuclei between 12 and 40 GV, by taking advantage of the variation of the geomagnetic cut-off rigidity in the east-west plane over Hyderabad, India. Altotal of 2433 identified helium nuclei recorded in the stack, has been divided into 8 angular intervals in the east-west plane corresponding to 8 different cut-off rigidities. From this the integral fluxes of helium nuclei at the top of the atmosphere have been obtained for all the 8 rigidity intervals. The vertical flux above an effective threshold rigidity of 16·73 GV has been determined with high statistical accuracy and has a value of 15·0±0·5 helium nuclei (m².sr.sec.)^?1. The rigidity spectrum of these nuclei between 12 and 40 GV can be well represented by a power law of the type N (>R) =1990 R^?1.74±0.11 (m².sr.sec.)^?1 and is the first direct determination so far made in this rigidity region. The differential rigidity spectra of protons, helium nuclei and S-nuclei of the cosmic radiation in the vicinity of the earth at solar minimum (1965) have been constructed with the existing world data and it is found that for rigidities ? 10 GV, the three spectra have, within experimental errors, the same slope of 2·6. The ratio P/He and He/S of the differential fluxes have been studied as a function of rigidity. It is found that for R>2 GV, the ratio P/He has, within experimental errors, a constant value of 6·3; as for the ratio He/S, it seems that the experimental data above a GV is not inconsistent with a constant value of 14 over the entire rigidity interval considered here.     

An Approach to Linear Scalable DH-PHEMT Model for Millimeterwave Application

This paper describes a scalable small-signal equivalent circuit for 0.25 m gatelength Double Heterojunction delta-doped PHEMTs. The scaling rules for all elements except the pad capacitances and bondwire inductances have been determined. Good agreement is obtained between simulation results and measured results for 2 times 20 m , 2 times 40 m, 2 times 60 m, 2 times 100 m gate width (number of gate fingers times unit gate width) DH PHEMT.