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21.
Elena Froner Roberta Adamo Zeno Gaburro Benno Margesin Lorenzo Pavesi Adelio Rigo Marina Scarpa 《Journal of nanoparticle research》2006,8(6):1071-1074
Aqueous solutions of silicon nanocrystals have been obtained, by sonication, from porous Si (p-Si) aged in air for various times. The photoluminescence of these solutions changes with the aging time of p-Si. These changes correlate with nanocrystal core dimensions, i.e. with the oxidation of the nanocrystals. Infrared spectra show that the reaction with water depends on the age of the starting p-Si sample, since the native superficial oxide layer on p-Si inhibits these reactions. 相似文献
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Pascal Cauliez BenoÏT Rigo D. Fasseur D. Couturier 《Journal of heterocyclic chemistry》1996,33(4):1073-1077
Heterocyclizations of trisilylated diacylhydrazines derived from pyroglutamic acid occurs selectively and yields, depending on the conditions, either to 1,3,4-oxadiazoles (basic catalyst: fluoride anion) or to fused 1,2,4-triazines (acidic catalyst: triflic acid). 相似文献
24.
Pascal Cauliez Daniel Couturier Benoît Rigo Dominique Fasseur Patrice Halama 《Journal of heterocyclic chemistry》1993,30(4):921-927
The condensation of pyroglutamic acids with 1,2-phenylenediamine leads to 2-(5-oxo-2-pyrrolidinyl)benzimidazoles and the cyclization of disilylated diacylhydrazines derived from the same acids gives 2-(5-oxo-2-pyrrolidinyl)-1,3,4-oxadiazoles. These compounds show weak antifungal activity. 相似文献
25.
Patrizia Berti Luca Pratelli Pietro Rigo 《Probability Theory and Related Fields》2010,148(1-2):269-283
Let ${(\Omega, \mathcal{F}, P)}$ be a probability space. For each ${\mathcal{G}\subset\mathcal{F}}$ , define ${\overline{\mathcal{G}}}$ as the σ-field generated by ${\mathcal{G}}$ and those sets ${F\in \mathcal{F}}$ satisfying ${P(F)\in\{0,1\}}$ . Conditions for P to be atomic on ${\cap_{i=1}^k\overline{\mathcal{A}_i}}$ , with ${\mathcal{A }_1,\ldots,\mathcal{A}_k\subset\mathcal{F}}$ sub-σ-fields, are given. Conditions for P to be 0-1-valued on ${\cap_{i=1}^k \overline{\mathcal{A}_i}}$ are given as well. These conditions are useful in various fields, including Gibbs sampling, iterated conditional expectations and the intersection property. 相似文献
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A celebrated result of Morse and Hedlund, stated in 1938, asserts that a sequence x over a finite alphabet is ultimately periodic if and only if, for some n, the number of different factors of length n appearing in x is less than n+1. Attempts to extend this fundamental result, for example, to higher dimensions, have been considered during the last fifteen years. Let d≥2. A legitimate extension to a multidimensional setting of the notion of periodicity is to consider sets of Zd definable by a first order formula in the Presburger arithmetic 〈Z;<,+〉. With this latter notion and using a powerful criterion due to Muchnik, we exhibit a complete extension of the Morse–Hedlund theorem to an arbitrary dimension d and characterize sets of Zd definable in 〈Z;<,+〉 in terms of some functions counting recurrent blocks, that is, blocks occurring infinitely often. 相似文献
28.
Gielen E Smisdom N De Clercq B Vandeven M Gijsbers R Debyser Z Rigo JM Hofkens J Engelborghs Y Ameloot M 《Journal of fluorescence》2008,18(5):813-819
Many membrane proteins and lipids are partially confined in substructures ranging from tens of nanometers to micrometers in
size. Evidence for heterogeneities in the membrane of oligodendrocytes, i.e. the myelin-producing cells of the central nervous
system, is almost exclusively based on detergent methods. However, as application of detergents can alter the membrane phase
behaviour, it is important to investigate membrane heterogeneities in living cells. Here, we report on the first investigations
of the diffusion behavior of the myelin-specific protein MOG (myelin oligodendrocyte glycoprotein) in OLN-93 as studied by
the recently developed RICS (raster-scanning image correlation spectroscopy) technique. We implemented RICS on a standard
confocal laser-scanning microscope with one-photon excitation and analog detection. Measurements on FITC-dextran were used
to evaluate the performance of the system and the data analysis procedure.
Ellen Gielen and Nick Smisdom contributed equally to this work. 相似文献
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30.
A. Rigo M. Casas F. Garcias E. Moya de Guerra P. Sarriguren 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,40(1):294-297
We have analyzed the electronic momentum distribution n(k) of sodium clusters using the Kohn-Sham formalism within the Local Density Approximation for the valence electrons. Simple approximations to the Wigner transform have been used to understand the deviation between n(k) in clusters and in the bulk system. Deformation effects have been also analyzed. 相似文献