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111.
M.A. Abid H. Abu HassanZ. Hassan S.S. NgS.K. Mohd. Bakhori N.H. Abd. Raof 《Physica B: Condensed Matter》2011,406(8):1379-1384
Raman and Fourier transform infrared (FTIR) spectroscopies have been utilized to measure long-wavelength optical lattice vibrations of high-quality quaternary AlxInyGa1−x−yN thin films at room temperature. The AlxInyGa1−x−yN films were grown on c-plane (0 0 0 1) sapphire substrates with AlN as buffer layers using plasma assisted molecular beam epitaxy (PA-MBE) technique with aluminum (Al) mole fraction x ranging from 0.0 to 0.2 and constant indium (In) mole fraction y=0.1. Pseudo unit cell (PUC) model was applied to investigate the phonons frequency, mode number, static dielectric constant, and high frequency dielectric constant of the AlxInyGa1−x−yN mixed crystals. The theoretical results were compared with the experimental results obtained from the quaternary samples by using Raman and FTIR spectroscopies. The experimental results indicated that the AlxInyGa1−x−yN alloy had two-mode behavior, which includes A1(LO), E1(TO), and E2(H). Thus, these results are in agreement with the theoretical results of PUC model, which also revealed a two-mode behavior for the quaternary nitride. We also obtained new values of E1(TO) and E2(H) for the quaternary nitride samples that have not yet been reported in the literature. 相似文献
112.
A.SH. Hussein Z. Hassan S.M. Thahab Abu Hassan M.A. Abid C.W. Chin 《Physica B: Condensed Matter》2011,406(6-7):1267-1271
We have studied the structural properties of undoped and Si-doped AlxGa1?xN/GaN/AlN on Si (1 1 1) substrate prepared by plasma-assisted molecular beam epitaxy (PA-MBE) using high-resolution X-ray diffraction (HR-XRD) and atomic force microscopy (AFM). In comparison with undoped AlGaN, the roughness and dislocation density on the surface of the AlGaN layer decrease with Si doping. Full width half maximum (FWHM) of the undoped and Si-doped samples were equal to 0.69° and 0.52°, respectively. This indicates that the Si doping improves the crystalline quality of the AlxGa1?xN layer compared with the undoped one. Raman scattering measurement reveals that the optical phonon modes of A1(LO) and E2(H) of the AlGaN show a one-mode and two-modes behavior, respectively. The Fourier-transform infrared reflectance (FTIR) investigation confirms the one-mode (two-mode) behavior of the LO (TO) phonon in our samples. This is in good agreement with Raman measurement. Finally, the barrier height (ΦB) of undoped and Si-doped AlxGa1?xN samples was found to be 0.86 and 0.74 eV, respectively. 相似文献
113.
Behnam Bahrami Abasali KhodadadiYadollah Mortazavi Mohamad Esmaieli 《Applied Surface Science》2011,257(23):9710-9716
We report the variation of yield and quality of carbon nanotubes (CNTs) grown by chemical vapor deposition (CVD) of methane on iron oxide-MgO at 900-1000 °C for 1-60 min. The catalyst was prepared by impregnation of MgO powder with iron nitrate, dried, and calcined at 300 °C. As calcined and unreduced catalyst in quartz reactor was brought to the synthesis temperature in helium flow in a few minutes, and then the flow was switched to methane. The iron oxide was reduced to iron nanoparticles in methane, while the CNTs were growing.TEM micrographs, in accordance with Raman RBM peaks, indicate the formation of mostly single wall carbon nanotubes of about 1.0 nm size. High quality CNTs with IG/ID Raman peak ratio of 14.5 are formed in the first minute of CNTs synthesis with the highest rate. Both the rate and quality of CNTs degrades with increasing CNTs synthesis time. Also CNTs quality sharply declines with temperature in the range of 900-1000 °C, while the CNTs yield passes through a maximum at 950 °C. About the same CNTs lengths are formed for the whole range of the synthesis times. A model of continuous emergence of iron nanoparticle seeds for CNTs synthesis may explain the data. The data can also provide information for continuous production of CNTs in a fluidized bed reactor. 相似文献
114.
Mohamad Kamarol Mohd Jamil Shinya Ohtsuka Masayuki Hikita Hitoshi Saitoh Masayuki Sakaki 《Journal of Electrostatics》2011,69(6):611-617
This paper presents the decomposition by-products of trifluro-iodo-methane and their relative proportions in the gas phase under the occurrence of partial discharge. The experiment was performed in the presence of water vapor from 250 to 400 ppm under a non-uniform electric field configuration. The experimental results reveal that the by-products of C2F6, C2F4, C2F5I with the amount of 1300, 200, and 55 (CH3I) ppm, respectively, were produced for a cumulative charge of 161 mC. Other by-products, such as C3F8, CHF3, C3F6 CH3I were obtained at less than 30 ppm C2F6 was the dominant gas by-product of trifluro-iodo-methane suffering partial discharge. 相似文献
115.
Hadey K. Mohamad 《Journal of magnetism and magnetic materials》2011,323(1):61-66
I studied the ferrimagnetic Ising model with nearest neighbour interactions for a square lattice and simple cubic one, using mean field theory. The free energy of a mixed spin Ising ferrimagnetic model was calculated from a mean field approximation of the Hamiltonian. By minimizing the free energy, I obtained the equilibrium magnetizations and the compensation temperatures. Clear indications of the single-ion anisotropies on the compensation points of the mixed spin-3/2 and spin-5/2 ferrimagnetic lattices are found. Some interesting behaviors of these systems are obtained depending not only on the values of magnetic anisotropies for both sublattice sites but also on the lattice structure. The longitudinal magnetic fields dependence of the spin compensation temperature is the main focus of research. The possibility of many compensation temperatures is indicated. 相似文献
116.
Iqbal Mahmud A.J.F. Samed Md. Anamul Haque Md. Abu Bin Hasan Susan 《Journal of Saudi Chemical Society》2011,15(3):203-208
Cyclic voltammetric behavior of anthraquinone in aqueous medium has been studied in presence of a non-ionic surfactant, Triton X-100 (TX-100) using sodium salt of anthraquinone-2-sulphonic acid (AQS) as the electro-active species. When cathodic potential is applied, the anthraquinone (AQ) group of AQS is reduced to its dianion. In the reverse scan, the oxidation of AQ2− gives AQ. The electrochemical behavior shows a profound influence from the dissolved state of TX-100 in aqueous media. Spectrophotometric results indicate interaction between AQ and TX-100. A CEC (chemical–electrochemical–chemical) mechanism with the electrochemical reaction coupled with preceding interaction of AQS with TX-100 and following protonation reaction of reduced AQ has been proposed. 相似文献
117.
A. A. Al-Amiery A. A. Al-Temimi A. A. H. Kadhum Ya. K. Al-Majedy R. I. Al-Bayati H. A. Aday A. B. Mohamad 《Journal of Structural Chemistry》2013,54(3):648-649
A co-crystal is obtained in a methanolic solution from methyl 2-(3-chloro-4-methyl-2-oxo-2H-chromen-7-yloxy)acetate and 2-(2-aminophenyl)benzothiazole. In the crystal these molecules are connected via usual N-H…O and weak C-H…O H-bonds. The co-crystals are very stable. 相似文献
118.
Shaikh A. Ali N. Y. Abu‐Thabit Hasan A. Al‐Muallem 《Journal of polymer science. Part A, Polymer chemistry》2010,48(24):5693-5703
The zwitterionic monomer, ethyl 3‐(N,N‐diallylammonio)propanephosphonate, was cyclopolymerized in aqueous solutions using t‐butylhydroperoxide or ammonium persulfate as initiators to afford a polyphosphonobetaine (PPB). The protonation of P(?O)OEtO– and deprotonation of ? NH+ groups in PPB by HCl and NaOH, gave the corresponding cationic polyphosphononic acid (CPP) and anionic polyphosphonate (APP). The presence of two pH‐responsive functionalities in APP has led to establish the equilibria: APP ? PPB ? CPP, the position of which very much dictates the viscosity behavior of its aqueous solution. The PPB demonstrated “antipolyelectrolyte” viscosity behavior; however, in contrast to many polycarbo‐ and polysulfo‐betaines, it was found to be soluble in salt‐free water as well as in salt‐added solutions. Basicity constant (K1) of the amine group in APP, as determined by potentiometric technique, were found to be “apparent,” and as such followed the modified Henderson‐Hasselbalch equation. The study demonstrated a correlation between the basicity constants and viscosity values. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
119.
Kietics of oxidation of phenylhydrazine and p-bromophenylhydrazine by hexacyanoferrate(III) in acidic medium have been studied. The reactions follow similar kinetics, being first order with respect to both hydrazine and exacyanoferrate(III) and inverse first order with respect to the hydrogen ion. Addition of hexacyanoferrate(II) has no retarding effect on the rate of oxidation. The effects of varying ionic strength, dielectric constant, and temperature on the reaction rates have been investigated. A plausible mechanism has been proposed to account for the experimental results. Benzene and bromobenzene have been identified as the oxidation products. 相似文献
120.