全文获取类型
收费全文 | 11358篇 |
免费 | 566篇 |
国内免费 | 139篇 |
专业分类
化学 | 7931篇 |
晶体学 | 99篇 |
力学 | 576篇 |
综合类 | 7篇 |
数学 | 1482篇 |
物理学 | 1968篇 |
出版年
2024年 | 24篇 |
2023年 | 92篇 |
2022年 | 241篇 |
2021年 | 479篇 |
2020年 | 390篇 |
2019年 | 479篇 |
2018年 | 498篇 |
2017年 | 404篇 |
2016年 | 674篇 |
2015年 | 480篇 |
2014年 | 621篇 |
2013年 | 1198篇 |
2012年 | 890篇 |
2011年 | 866篇 |
2010年 | 642篇 |
2009年 | 522篇 |
2008年 | 565篇 |
2007年 | 502篇 |
2006年 | 350篇 |
2005年 | 358篇 |
2004年 | 230篇 |
2003年 | 213篇 |
2002年 | 178篇 |
2001年 | 93篇 |
2000年 | 64篇 |
1999年 | 68篇 |
1998年 | 53篇 |
1997年 | 53篇 |
1996年 | 60篇 |
1995年 | 39篇 |
1994年 | 42篇 |
1993年 | 25篇 |
1992年 | 41篇 |
1991年 | 37篇 |
1990年 | 40篇 |
1989年 | 38篇 |
1988年 | 36篇 |
1987年 | 39篇 |
1986年 | 36篇 |
1985年 | 43篇 |
1984年 | 42篇 |
1982年 | 31篇 |
1981年 | 23篇 |
1980年 | 26篇 |
1979年 | 27篇 |
1978年 | 23篇 |
1977年 | 19篇 |
1976年 | 26篇 |
1975年 | 19篇 |
1974年 | 20篇 |
排序方式: 共有10000条查询结果,搜索用时 175 毫秒
991.
Ismail M. Ali 《Journal of Radioanalytical and Nuclear Chemistry》2010,285(2):263-270
A series of rare-earth-doped sodium titanates with the chemical formula R
x
H
y
Na4 − (x+y)TiO4·nH2O (where R = Ce3+, Nd3+ and Sm3+) were grown employing solid-state fusion reaction technique. The physico-chemical investigations indicated that the new materials
were self engineered into large particles enough to be used in sorption process and having crystalline structures containing
localized Na+ ions. Equilibrium studies revealed that an enhancement in sorption efficiency of sodium titanate after rare-earth doping.
The neodymium-rich sodium titanate exhibited a better exchange affinity for Cs+ compared to the other studied series. Data on the kinetics of cesium exchange fit well to pseudo-second order and intra-particle
diffusion models. In a separate experiment, it was reported that the R-HNaTi series showed responsible sorption affinity toward
Ce, Nd and Sm ions in their solution mixture with insignificant selectivity trend which reflects the high stability of titanate
matrices. 相似文献
992.
Fariborz Momenbeik Mostafa Roosta Ali Akbar Nikoukar 《Journal of chromatography. A》2010,1217(24):3770-3773
An environmentally benign and simple method has been proposed for separation and determination of fat-soluble vitamins using isocratic microemulsion liquid chromatography. Optimization of parameters affecting the separation selectivity and efficiency including surfactant concentration, percent of cosurfactant (1-butanol), and percent of organic oily solvent (diethyl ether), temperature and pH were performed simultaneously using genetic algorithm method. A new software package, MLR-GA, was developed for this purpose. The results indicated that 73.6 mM sodium dodecyl sulfate, 13.64% (v/v) 1-butanol, 0.48% (v/v) diethyl ether, column temperature of 32.5 °C and 0.02 M phosphate buffer of pH 6.99 are the best conditions for separation of fat-soluble vitamins. At the optimized conditions, the calibration plots for the vitamins were obtained and detection limits (1.06–3.69 μg mL−1), accuracy (recoveries > 94.3), precision (RSD < 3.96) and linearity (0.01–10 mg mL−1) were estimated. Finally, the amount of vitamins in multivitamin syrup and a sample of fish oil capsule were determined. The results showed a good agreement with those reported by manufactures. 相似文献
993.
994.
Ali Asghar Rastegari Abdol-Khalegh Bordbar Vajihe Mehnati-Najafabadi 《Cellulose (London, England)》2010,17(6):1213-1225
The present study evaluates the binding of cetylpyridinium chloride (CPC) with cellulase in various experimental conditions
using potentiometric, fluorescence spectroscopy and turbidimetric techniques. The analysis of binding curves revealed the
existence of two sets of binding sets for CPC. The binding parameters were estimated and interpreted in terms of structural
viewpoints of cellulase. The observation of turbidity suggests that CPC molecules individually nucleate around cellulase/CMC
complex to form micelle-like structures. Fluorescence spectroscopy analysis of cellulase/CMC-surfactant system showed that
these complexes could be compact to elucidate the mechanism of binding cellulase/CMC complex to CPC. The differential response
of the enzyme/CMC to surfactant, indicates that the interaction on the complex surface is strongly ionic and hydrophobic(cooperative)
in nature. A sequencing analysis was also conducted on β-1, 4-endoglucanase from A. niger (EglA) and others from family 12 in order to examine the nature of interaction involved in binding process and structure
of carbohydrate-protein complexes. The results suggest that the conserved residues are located in a more hydrophobic microenvironment
and apolar area energy is more than polar within enzyme structure. 相似文献
995.
Ijaz A. Bhatti Shahid Adeel M. Asghar Jamal Muhammad Safdar Muhammad Abbas 《Radiation Physics and Chemistry》2010,79(5):622-625
The effect of gamma radiation on the dyeing of cotton with extract of turmeric (Curcuma longa L.) powder has been investigated. Cotton fabric and turmeric powder were irradiated to absorbed doses of 1, 2, 3, 4 and 6 kGy using Co-60 gamma irradiator. Dyeing parameters such as temperature, pH and mordant concentration were optimized. Dyeing was performed using un-irradiated and irradiated cotton with the extracts of un-irradiated and irradiated turmeric powder in order to investigate the effect of radiation treatment on the colour strength of dyed fabric. The reported data of un-irradiated and irradiated fabrics dyed with un-irradiated and irradiated dyes were obtained using the spectraflash SF-650. The colourfastness to light, rubbing- and washing-fastness properties showed that gamma irradiation has improved the dyeing characteristics from fair to good. 相似文献
996.
ElShazali Ahmed Mohamed Nahid Abdelraheem Ali Salma Hashim Ahmed Isam A. Mohamed Ahmed Elfadil E. Babiker 《Radiation Physics and Chemistry》2010,79(7):791-796
Whole and dehulled flours of millet cultivars Ashana and Dembi were stored for 30 and 60 days before and after radiation and/or cooking. Phytic acid and polyphenols contents were assayed for all treatments. The results revealed that the storage period was found to have no effect on phytate and polyphenols contents. Moreover, dehulling of the grains reduced more than 50% of phytate and polyphenols of both cultivars. Cooking of the raw whole and dehulled flour significantly (P≤0.05) reduced phytate and polyphenols contents for both cultivars. Radiation process alone had no effect on phytate and polyphenols contents but when followed by cooking significantly (P≤0.05) reduced the level of such antinutrients for the whole and dehulled flour of both cultivars. Dehulling alone significantly (P≤0.05) decreased Ca and P content but slightly decreased Fe content. Radiation alone or in combination with cooking was found to have slight effect on minerals content of the whole and dehulled raw flour for both cultivars. Cooking alone or in combination with radiation of whole or dehulled raw flour significantly (P≤0.05) improved the extractable Ca but had no significant (P≤0.05) effect on extractable P and Fe for both cultivars. 相似文献
997.
S. Abbas Mousavi Susan Dadbin Masoud Frounchi David C. Venerus Teresita Guadarrama Medina 《Radiation Physics and Chemistry》2010,79(10):1088-1094
Chemical and electron beam irradiation methods were used to introduce a branched structure into polypropylene and propylene–ethylene copolymer. The chemical method was carried out in an internal mixer using initiator and TMPTMA monomer. In irradiation method, the polymer was irradiated by electron beam under air and nitrogen atmosphere. The branched structure in the modified polymer was confirmed by rheological measurements. While degradation was significant in chemical method, branching occurred efficiently by irradiation under air. Small amount of ethylene in the propylene copolymer promoted branching over degradation. 相似文献
998.
Carbon nanotubes are a kind of new carbon-based nanomaterials, which have drawn great attention in many application fields. The potential of single-walled carbon nanotubes (SWCNTs) as solid-phase microextraction (SPME) adsorbent for the preconcentration of environmental pollutants has been investigated in recent years. In the present study, the feasibility of SWCNTs as SPME adsorbent for the determination of monobutyltin, dibutyltin and tributyltin in seawater samples was studied. To achieve this aim, the potential factors affecting the SPME efficiency, including extraction time, extraction temperature, desorption time, desorption temperature, and salinity were optimized. The developed method showed good performance according to the ICH (International Conference on Harmonization of Technical Requirements for Analytical Methods) criteria. The acquired calibration curves were linear (r ≥ 0.992) over the concentration range from ≤12 to 2000 ng L−1. For all of the analytes, the limit of detection at signal-to-noise ratio of 3 was below 5 ng L−1. Furthermore, in comparison with the commercial carboxen/polydimethylsiloxane fiber, the developed SWCNT fiber showed better thermal stability (over 350 °C) and longer life span (over 150 times). The application of the proposed method in environmental analyses was shown by analyzing seawater samples from the harbors on the Persian Gulf for butyltin residues. Some of the butyltins were detected in the analyzed samples. Results of the present study demonstrate the feasibility of the SWCNTs as SPME adsorbent for the determination of butyltins in seawater samples. 相似文献
999.
Ali Haider Zareen Akhter Humaira Masood Siddiqi Edward R. T. Tiekink 《Journal of chemical crystallography》2010,40(5):397-401
Abstract
The molecule of 4-aminobenzohydrazide is essentially planar and geometric parameters conform to literature precedents. Supramolecular N–H···O and N–H···N interactions combine to link molecules of 4-aminobenzohydrazide into a three-dimensional network. Weaker N–H···N and N–H···π interactions consolidate the structure. The compound crystallizes in the monoclinic space group P21/n with a = 5.411(2) ?, b = 14.000(6) ?, c = 9.894(4) ?, β = 103.917(7)o, and Z = 4. 相似文献1000.
采用初湿浸渍和溶胶凝胶法分别制备了Li/MgO催化剂和Li/MgO纳米催化剂. 比较两种Li/MgO催化剂对于甲烷氧化偶联反应的催化性能. 采用X射线衍射、BET吸附和透射电镜进行了表征.在973-1073 K和总压力为101 kPa下对催化剂进行了测试. 实验结果表明,Li/MgO纳米催化剂比普通催化剂对于甲烷氧化偶联反应表现为更高的甲烷转换率,较高选择性和较高的的主要产品(乙烷和乙烯)的产率. 相似文献