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11.
Trituration and capillary solid-state spot-tests for 25 anions with a number of organic and inorganic reagents have been examined. A comparative study of the corresponding reactions in solution has also been made. Incorporation of a glass-wool plug in the capillary improves the selectivity. Schemes are presented for possible use of the technique. 相似文献
12.
The heavy mesons of the charmonium and upsilon family are described in an alternative static potential model chosen in a combination of Hulthen and linear potential. We find that the quark-confining potential in the form of an equal admixture of vector and scalar parts successfully explains the fine-hyperfine structures of \(c\bar c\) and \(b\bar b\) systems in a flavour-independent manner. The leptonic decay widths of the vector mesons ofψ and γ families are calculated taking into account the Poggio-Schnitzer correction. We obtain some of the bound states of the yet-to-be observed \(t\bar t\) system for thet-quark mass ranging from 50 to 200 GeV. 相似文献
13.
J. S. Shukla R. K. Tiwari 《Journal of polymer science. Part A, Polymer chemistry》1981,19(6):1517-1524
The aqueous polymerization of methacrylamide (I) initiated by KBrO3–thioglycolic acid (TGA) has been studied at 30 ± 0.2°C in nitrogen. The rate is given by K[M]1.19 [thioglycolic acid]1 [KBrO3]0.53 for 10–15% conversion. Activation energy was found to be 53.96 kJ/mole (12.92 kcal/mole) in the investigated range of temperature 30–45°C. The role of addition of a series of aliphatic alcohols and some salts was also determined. The kinetics of polymerization was followed iodometrically. 相似文献
14.
Low molecular weight poly(dimethylsiloxane) and poly(methylphenylsiloxane) were synthesized and blended with polyimide (PI) at its precursor poly(amic acid) stage. FTIR analysis has proven the retention of polysiloxanes in polyimide after the ultimate curing of blends. Differential scanning calorimetric analysis was performed on polysiloxanes to elucidate the structures present in polymers while thermogravimetric analysis (TGA) was performed on polysiloxanes, polyimide as well as their blends to evaluate the thermal stability and to analyze the effect of polysiloxane incorporation in blends. Blends have shown synergistic improvement as compared to neat polyimide. 相似文献
15.
Summary Copper(II) forms a stable colourless complex with thiourea. This property has been utilized to develop a Spectrophotometric method for the determination ofg quantities of thiourea. The complex absorbs in ultraviolet region and the determinations are carried out at 250 nm. The method permits the determination of thiourea from 10–60g with error not exceeding ± 1.0%.
Zusammenfassung Kupfer(II) bildet mit Thioharnstoff eine farblosa Komplexverbindung, die sich auf Grund ihrer Absorption bei 250 nm zur spektrophotometrischen Bestimmung von Mikrogrammengen Thioharnstoff eignet. 10 bis 60g Thioharnstoff lassen sieh mit einem Fehler von höchstens ± 1,0% bestimmen.相似文献
16.
Vinod K. Tiwari Archana Singh Hakkim A. Hussain Bhuwan B. Mishra Vyasji Tripathi 《Monatshefte für Chemie / Chemical Monthly》2007,138(7):653-658
Summary. A convenient and high yielding method for the synthesis of diverse dithiocarbamates having various substituents including
alkyl, aryl, heteroaryl, and alkylaryl at the thiol chain or at the amine chain or at both thiol and amine chains were developed
by the one-pot reaction of mercaptans, amines, and bis(benzotriazolyl)methanethione in presence of amidine base under mild
reaction conditions. 相似文献
17.
A. K. Rastogi S. Mishra A. K. Tiwari 《International Journal of Infrared and Millimeter Waves》1995,16(3):601-614
Dispersion characteristics and wave impedance for the even and odd modes of the broad side coupled dielectric image guides are computed by using mode matching techniques. Dispersion curves for broadside image guide are plotted for various dielectric materials and dimensional parameters as a function of frequency. Normalized electric field for dominant electric field component E of TM even and odd modes for various half spacings between two dielectric slabs of broadside coupled image guide have been plotted. Polysterene ( r=2.56) and Stycast ( r=3.4) have been used as dielectric materials in fabricating broadside coupled image guide. This broadside coupled dielectric guide is very convenient as compared to the other dielectric guides. Since in case of broadside coupled image guide the dielectric slab can be bonded to the side metallic walls using some low loss adhesive material, while in other coupled dielectric guides the dielectric slab have to be supported by some low dielectric constant material (Eccofoam with r=1.02) to maintain the proper distance of side metallic walls from the dielectric slab. Since this structure is symmetrical, this configuration can be analysed in terms of even and odd mode phase velocities. The difference in these even and off mode phase velocities can be used to determine the coupling between coupled dielectric slab. Various couplers in this configuration can be realised. 相似文献
18.
Vaishali Tiwari 《Thermochimica Acta》2006,443(2):206-211
Densities ρ and viscosities η of two hydroxamic acids, N-phenyl-2-chlorobenzo- and N-o-tolyl-4-chlorobenzo-, have been determined as a function of their concentration in aqueous acetone solution at temperatures 303.15 and 313.15 K. Apparent molar volumes, standard-state partial molar volumes and relative viscosities have been calculated. The viscosity data have been analyzed using Jones-Dole equation. The activation thermodynamic parameters of viscous flow have been evaluated using Feakins equation. These were obtained to throw light on the mechanism of viscous flow. Thermodynamic interactions in solutions have been studied in terms of a number of excess functions calculated from the experimental data. The effect of hydroxamic acid concentration and temperature on these parameters has been discussed. The results were interpreted in the light of solute-solvent interactions in aquo-organic media. 相似文献
19.
S. P. Mushran A. K. Bose J. N. Tiwari 《Monatshefte für Chemie / Chemical Monthly》1976,107(4):1021-1027
N-bromosuccinimide oxidation of cyclopentanone in acidic media in presence of mercuric acetate has been made. A zero order dependance to N-bromosuccinimide and a first order dependence to cyclopentanone and hydrogen ion concentration has been observed. Ionic strength, mercuric acetate and succinimide has negligible effect while methanol addition has a positive effect. Various rate parameters have been computed and 1,2-cyclopentanedione identified as the end product. A suitable mechanism in confirmity with the above observations has been proposed.With 2 Figures 相似文献
20.
Summary The halogen oxidation and nitrosylation of cis-[(SB)M-(CO)4] [M = Cr or Mo, SB = N,N-ethylenebis(p-tolualideneimine), N,N-ethylenebis(p-N,N-dimethylaminobenzalideneimine) or N,N-ethylenebis(methyl-p-methoxyphenylketimine); M = Mo, SB = N,N-ethylenebis-(cinnamylideneimine) or N,N-ethylenebis(methyl-p-methylphenylketimine)] have been studied. Halogenation of [(SB)Cr(CO)4] yielded [(SB)CrX2] (X = Cl, Br or I) where-as [(SB)Mo(CO)4] gave [(SB)Mo(CO)3X2] (X = Br or I) and [(SB)MoX
x
] (X = I, n = 2; X = Cl or Br, n = 4). NOCl produced [(SB)Cr(NO)2Cl2] and [(SB)Mo(CO)2(NO)Cl] when reacted with the corresponding [(SB)M(CO)4]. The complexes were characterized by physico-chemical and spectroscopic measurements. 相似文献