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61.
Chromatographic enantioseparations on the order of a few seconds can be achieved by supercritical fluid chromatography using short columns packed with chiral stationary phases. The evolution of ‘world record’ speeds for the chromatographic separation of enantiomers has steadily dropped from an industry standard of 20–40 min just two decades ago, to a current ability to perform many enantioseparations in well under a minute. Improvements in instrument and column technologies enabled this revolution, but the ability to predict optimal separation time from an initial method development screening assay using the tmin cc predictor greatly simplifies the development and optimization of high‐speed chiral chromatographic separations. In this study, we illustrate how the use of this simple tool in combination with the workhorse technique of supercritical fluid chromatography on customized short chiral columns (1–2 cm length) allows us to achieve ultrafast enantioseparations of pharmaceutically relevant compounds on the 5–20 s scale, bringing the technique of high‐throughput enantiopurity analysis out of the specialist realm and into the laboratories of most researchers. 相似文献
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Kenwright JL Galloway WR Blackwell DT Isidro-Llobet A Hodgkinson J Wortmann L Bowden SD Welch M Spring DR 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(10):2981-2986
Herein, a new copper-catalysed strategy for the synthesis of rare nitrogen-linked seven-, eight- and nine-membered biaryl ring systems is described. It is proposed that the reaction proceeds through a highly activated intramolecularly co-ordinated copper catalyst. The process is technically simple, proceeds under relatively mild conditions, displays a broad substrate scope and forms biologically valuable products that are difficult to synthesise by other methods. We envisage that this methodology will prove useful in a wide synthetic context, with possible applications in both target-oriented and diversity-oriented synthesis. 相似文献
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This paper will describe the application of an interactive queueing network analyzer and an interactive graphics system to the analysis of a multiple processor computer system. The application of these tools greatly increased the productivity of the modelers and resulted in insights which would have otherwise been difficult, if not impossible, to obtain. With this experience as background, we discuss how the increasing availability of computing resources, especially high resolution interactive computer graphics and sophisticated modeling packages, is likely to have a profound influence on the applied stochastic modeler. 相似文献
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Metal-mediated allylations of difluoroacetyltriakylsilanes with various allyl bromides in aqueous media form homoallylic alcohols exclusively. The common Brook rearrangement, carbon to oxygen-silyl migration, is totally suppressed with no detectable formation of silyl enol ether. Influence of solvents on reaction is studied. Reactivity differences between indium and zinc are also described. 相似文献
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M. J. Welch 《Journal of Radioanalytical and Nuclear Chemistry》1993,171(1):269-276
The field Nuclear Medicine has expanded rapidly over the last two decades. Individuals with training in radiochemistry are needed in industry, medical centers and hospitals. Although basic training in organic chemistry, inorganic chemistry, biochemistry or pharmacy are required, radiochemistry knowledge is essential for all of these individuals. Opportunities and training requirements in these areas will be discussed. 相似文献