乌鲁木齐市安宁渠区蔬菜中重金属的分布特征研究

对乌鲁木齐市郊安宁渠区在土壤调查的基础上，又进行了蔬菜中的重金属调查．并对蔬菜进行了污染评价．结果标明：土壤的环境元素组合与蔬菜的不同．土壤和蔬菜的重金属聚类分析结果也不同．按食品卫生标准进行评价，蔬菜中Cd、Pb的超标率最高，大白菜的超标率比四季豆和长豇豆更高．长豇豆对重金属的富集系数相对较小．     

POSITRON ANNIHILATION WITH VACANCIES IN THIN SURFACE LAYER OF As HEAVILY DOPED Si

The lifetime spectroscopy of slow positron accelerated with linear accelerator and pulse punch system was first used to analyze the vacancies in the thin surface layer of silicon heavily doped with arsenic. The results demonstrated that no mono-vacancy was detected to support the arsenic-vacancy complex models for explaining the electrical deactivation mechanism of arsenic-heavily-doped silicon.     

心脏内部血流实时动态径迹的非侵入性显示方法——超声微泡血流图

前言人体心内血液流动是生命存在的象征.显示人体心内血液流场对研究心脏力学及其病理改变有着重要意义.虽然流体力学中显示流场动态的方法有多种形式,但要显示人体心内血液流场,又要做到...     

MULTIPLE SOLUTIONS TO SINGULAR BVPS WITH VARIABLE COEFFICIENT ON THE HALF-LINE

This paper is concerned with a singular second-order nonlinear boundary value problem with a time depending on derivative operator and posed on the positive half-line. The nonlinearity is derivative-dependent, which has singularities at t=0 and/or x=0, and may change sign. The method of the upper and lower solutions on unbounded domains combined with the topological degree theory are employed to prove the existence and multiplicity of solutions.     

Xe对NO(X)微分截面和非弹性散射中的碰撞诱导旋转准直

本文对NO(X)-Xe碰撞系统在碰撞能量为519 cm^-1，测量了完全?-双峰分解的微分截面和碰撞引起的旋转准直力矩. 同时结合初始量子态选择，使用六极杆的非均质电场，借助量子态分辨的测量，利用(1+1'')共振增强的多光子电离和速度离子成像. 结果显示，微分截面以及偏振相关的微分截面均显示与从头算势能面上进行的量子力学散射计算[J. K?os etal. J. Chem. Phys. 137, 014312 (2012)]一致. 通过与准经典轨迹、硬壳势能的量子力学散射以及运动近端模型的比较，评估了势能对所测微分截面和碰撞引起的旋转准直力矩的影响.     

F−(H2O)+CH3I配体交换反应动力学

本文介绍F^?(H₂O)+CH₃I→[FCH₃I]^?+H₂O在交叉分子束碰撞能量0.3∽2.6 eV的配体交换动力学成像结果. 产物的动能受到弱键结合配合物的稳定性的影响，大量水分子的内部激发不利于中间物有效的能量重新分配，随着碰撞增加，低动能受到抑制. 在0.3 eV时，内部亲核取代非常重要，为形成I^?和I^?(H₂O)的竞争性亲核取代途径提供了依据.     

Understanding Chemical Reactivity in Extended Systems:Exploring Models of Chemical Softness in Carbon Nanotubes

Chemical reactivity towards electron transfer is captured by the Fukui function.However,this is not well defined when the system or its ions have degenerate or pseudo-degenerate ground states.In such a case,the first-order chemical response is not independent of the perturbation and the correct response has to be computed using the mathematical formalism of perturbation theory for degenerate states.Spatialpseudo-degeneracy is ubiquitous in nanostructures with high symmetry and totally extended systems.Given the size of these systems,using degenerate-state perturbation theory is impractical because it requires the calculation of many excited states.Here we present an alternative to compute the chemical response of extended systems using models of local softness in terms of the local density of states.The local softness is approximately equal to the density of states at the Fermi level.However,such approximation leaves out the contribution of inner states.In order to include and weight the contribution of the states around the Fermi level,a model inspired by the long-range behavior of the local softness is presented.Single wall capped carbon nanotubes(SWCCNT) illustrate the limitation of the frontier orbital theory in extended systems.Thus,we have used a C360 SWCCNT to test the proposed model and how it compares with available models based on the local density of states.Interestingly,a simple Hü ckel approximation captures the main features of chemical response of these systems.Our results suggest that density-of-states models of the softness along simple tight binding Hamiltonians could be used to explore the chemical reactivity of more complex system,such a surfaces and nanoparticles.     

Tween80/BmimPF6/醇/甲苯体系的相行为

以环境友好型的Tween80为表面活性剂, 以醇(乙醇、正丁醇、正己醇、正辛醇、正癸醇和异戊醇)为助表面活性剂, 对离子液体1-丁基-3-甲基咪唑六氟磷酸盐(bmimPF6)和甲苯进行了微乳化实验, 绘制了不同条件下Tween80离子液体的微乳体系的拟三元相图, 考察了醇的种类、含量对单相微乳区的影响, 并用电导法研究了在乙醇为助表面活性剂情况下, 单相微乳区的结构转变. 结果表明, 当醇(异戊醇)固定时, 随着表面活性剂/醇的质量比增加, 单相微乳区的面积逐渐增大; 不同链长的直链醇对单相微乳区的面积影响与该醇在离子液体中的溶解情况有关, 单相微乳区的面积随着直链醇链长的增加而越小; 当乙醇作助表面活性剂时, 所得到的单相微乳区的面积最大, 且单相微乳区存在着O/IL(oil-in-ionic liquid)、双连续相和IL/O(ionic liquid-in-oil)三种微结构. 尤其对离子液体微乳体系的电导随油的含量的增加而最初增大的现象进行了解释, 这一现象是由于油主要起到减少离子液体中离子对或离子的积聚, 提高带电离子淌度的作用.     

GSI 对最重的靶元素254Es 的首次轰击

在10月10—18日之间,在GSI,人们利用尤尼拉克(UNILAC)的束流对99号元素锒的同位素~(254)Es(半寿命T_(1/2)=276天)进行了首次轰击,这是迄今使用的最重的靶元素;该实验用了2μg 的Es 同位素,这几乎是世界上仅有的库存。实验是由劳伦斯利弗莫尔实验室和GSI 合作完成的,其目的是想用~(16)O,~(18)O和~(22)Ne 作炮弹对~(254)Es 进行轰击,找到生成丰中子重锕系元素和超锕系同位素的最佳反应条件。去年在利弗莫尔的离线化学实验表明,这个方法将被认为是这次实验的唯一有效的。