Ca掺杂的Ba2Al2Si10N14O4:Eu2+荧光粉发光性能

通过固相反应制备了系列Ca掺杂的Ba2Al2Si10M14O4:Eu2+色荧光粉,发现当半径较大的Ba被Ca取代后导致了晶格的收缩,通过X射线衍射(XRD)测量和Unitcell软件计算发现Ca的最大掺杂量在20％.Ca掺人Eu0.4Ba1.6Al2Si10N14O4荧光粉后,可有效地提高光转换性能,并使激发光谱发生一定程度的红移和宽化,从而被近紫外宽波段光有效激发,与近紫外LED的发射光谱匹配.同时Ca的掺杂也使发射光谱发生了可控的红移,可以由520 nm的绿光红移至548 nm的黄光区域.进一步发现Eu2+的淬灭浓度随着20％ Ca的掺入而降低,这是由于Ca掺入导致的晶格收缩使Eu2+离子间距离减小.最后在CIE色度图中对不同Ca,Eu浓度的荧光粉的色坐标位置进行比较,发现可通过Ca,Eu浓度的变化在很大范围内调制荧光粉的发光性能.     

Simulating the resonance-mediated (1+2)-three-photon absorption enhancement in Pr3+ ions by a rectangle phase modulation

Enhancing the upconversion luminescence of rare earth ions is crucial for their applications in the laser sources, fiber optic communications, color displays, biolabeling, and biomedical sensors. In this paper, we theoretically study the resonance-mediated (1+2)-three-photon absorption in Pr³⁺ ions by a rectangle phase modulation. The results show that the resonance-mediated (1+2)-three-photon absorption can be effectively enhanced by properly designing the depth and width of the rectangle phase modulation, which can be attributed to the constructive interference between on-resonant and near-resonant three-photon excitation pathways. Further, the enhancement efficiency of resonance-mediated (1+2)-three-photon absorption can be affected by the pulse width (or spectral bandwidth) of femtosecond laser field, final state transition frequency, and absorption bandwidths. This research can provide a clear physical picture for understanding and controlling the multi-photon absorption in rare-earth ions, and also can provide theoretical guidance for improving the up-conversion luminescence.     

碳纳米管纤维及薄膜的热导率和热扩散率研究

宏观碳纳米管(Carbon nanotube,CNT)薄膜的成功制备是发展有机热电材料的一个重要方向。由于CNT薄膜厚度仅为200 nm且多孔、粗糙度大,对其热学特性表征极为困难。本文提出应用3ω技术测量由单壁(Single-walled,SW)CNT薄膜卷曲成的宏观纤维的热导率和热扩散率,讨论了卷曲层数对结果的影响及估算薄膜面向热导率和热扩散率的思路。所研究的两个SWCNT薄膜的面向热导率为3.4 W/(m·K)和2.0 W/(m·K),热扩散率为24 mm~2/s和21mm~2/s。结果表明SWCNT薄膜将为发展低成本有机热电材料领域做出贡献。     

Painlevé Analysis,Soliton Collision and B?cklund Transformation for the (3+1)-Dimensional Variable-Coefficient Kadomtsev–Petviashvili Equation in Fluids or Plasmas

In this paper, we investigate a(3+1)-dimensional generalized variable-coefficient Kadomtsev–Petviashvili equation, which can describe the nonlinear phenomena in fluids or plasmas. Painlev′e analysis is performed for us to study the integrability, and we find that the equation is not completely integrable. By virtue of the binary Bell polynomials,bilinear form and soliton solutions are obtained, and B¨acklund transformation in the binary-Bell-polynomial form and bilinear form are derived. Soliton collisions are graphically discussed: the solitons keep their original shapes unchanged after the collision except for the phase shifts. Variable coefficients are seen to affect the motion of solitons: when the variable coefficients are chosen as the constants, solitons keep their directions unchanged during the collision; with the variable coefficients as the functions of the temporal coordinate, the one soliton changes its direction.     

线性随机时滞微分方程裂步Milstein方法的收敛性(英文)

给出一个新的求解线性随机时滞微分方程的显式分裂步长Milstein格式.运用ItoTaylor展开式证明该格式相对于已有的求解随机时滞微分方程的分裂步长方法而言具有更好的收敛性.数值实验验证了理论分析的正确性.     

多足化合物的分子内激基缔合物形成及pH对其荧光的影响

研究了含萘脲基多足化合物溶液的稳态和瞬态光物理行为.由于分子内不同足间脲基的相互作用干扰了萘基的π-π叠合,使分子内萘基的激基缔合物生成受到影响.实验表明:由于三足化合物存在着给电子叔胺基团,因此当萘基被激发时、可因分子内的光诱导电子转移而导致荧光猝灭.正因如此,在三足化合物归一化后的稳态光谱中激基缔合物的发光强度很弱.用皮秒级单光子记数技术测得该化合物的瞬态荧光为三指数衰变过程.其中最长寿命的物种,即属于生成激基缔合物后再分解为萘激发态的部分仅占总量的4%,与稳态的结果相一致.工作表明对这类可用作荧光化学敏感器的三足化合物,如利用其激基缔合物的强度变化为其识别外来物种的敏感部位并不适合.相反,如引入的外来物种能影响化合物的分子内光诱导电子转移,进而影响萘基的发光强度,则是一较好的判别外来物种是否已进入主体的标志.     

杨振宁物理教学思想浅探

20 0 1年是诺贝尔物理学奖设立 10 0周年 ,全世界物理学界都将以各种各样的形式庆贺这一盛事 .自 1957年杨振宁、李政道获得诺贝尔物理学奖以来 ,全世界的华人视他们为英雄 .他们大大提高了华人在物理学界的地位 ,乃至世界上的地位 .这一点正如杨振宁所说 :“我一生最重要的贡献是帮助中国人改变了自己觉得不如人的心理作用 .”杨振宁先生的贡献是巨大的 ,也是多方面的 .除了他和李政道一起提出弱相互作用下宇称不守恒理论而获得科学界的最高荣誉外 ,他和米尔斯创立的规范场理论被看作 2 0世纪与相对论、量子力学齐名的三大里程碑之一 .此外…     

Interaction of multi-podal open-chained compounds with anions

Six kinds of naphthyl urea and thiourea podands were designed and synthesized. The interaction between these compounds and various guest anions are studied in molecular level via absorption, fluorescence and 1H NMR spectra. The experiments show that tri-podal urea or thiourea host can bind H2PO4-or HSO4-selectively and form a host-guest complex thus inducing a change in photophysical properties of host molecule. Through comparison between urea and thiourea compounds used as host molecules, the stability constants and stoichiometry of the complexes have been determined. The binding manner and possible structures of them have been proposed.     

核裂变材料核素成份的γ特征谱分析

研究对裂变核材料及有关核装置进行无损探测与识别的物理可行性。其要点是由测量得到的γ特征能谱出发,通过对γ射线输运过程的物理分析并引入相应的参量描述,以推论有关核材料的特征信息。数值计算模拟实验的结果表明。据此方法可以在有效的精度范围内由所测量到的裂变核材料的出射γ特征谱推算出其同位素成份等重要信息。研究结果还表明,考虑源区核材料的自吸收修正(称几何自屏蔽修正)是提高计算分析精度的关键因素之一。通过对大量计算结果的分析与综合,还给出了某些简单几何形状的自吸收修正的简要公式。该研究对有关核材料的监控、核查及衡算等安全保障技术方面有重要的应用价值。